An experimental study on Fischer‐Tropsch catalysis: Implications for impact phenomena and nebular chemistry

Abstract— Fischer‐Tropsch catalysis, by which CO and H₂ are converted to CH₄ on the surface of transition metals, has been considered to be one of the most important chemical reactions in many planetary processes, such as the formation of the solar and circumplanetary nebulae, the expansion of vapor clouds induced by cometary impacts, and the atmospheric re‐entry of vapor condensate due to asteroidal impacts. However, few quantitative experimental studies have been conducted for the catalytic reaction under conditions relevant to these planetary processes. In this study, we conduct Fischer‐Tropsch catalytic experiments at low pressures (1.3 times 10^?4 bar ≤ P ≤ 5.3 times 10^?1 bar) over a wide range of H₂/CO ratios (0.25–1000) using pure iron, pure nickel, and iron‐nickel alloys. We analyze what gas species are produced and measure the CH₄ formation rate. Our results indicate that the CH₄ formation rate for iron catalysts strongly depends on both pressure and the H₂/CO ratio, and that nickel is a more efficient catalyst at lower pressures and lower H₂/CO ratios. This difference in catalytic properties between iron and nickel may come from the reaction steps concerning disproportionation of CO, hydrogenation of surface carbon, and the poisoning of the catalyst. These results suggest that nickel is important in the atmospheric re‐entry of impact condensate, while iron is efficient in circumplanetary subnebulae. Our results also indicate that previous numerical models of iron catalysis based on experimental data at 1 bar considerably overestimate CH₄ formation efficiency at lower pressures, such as the solar nebula and the atmospheric re‐entry of impact condensate.     

Decision-theoretic sensitivity analysis for reservoir development under uncertainty using multilevel quasi-Monte Carlo methods

At various stages of petroleum reservoir development, we encounter a large degree of geological uncertainty under which a rational decision has to be made. In order to identify which parameter or group of parameters significantly affects the output of a decision model, we investigate decision-theoretic sensitivity analysis and its computational issues in this paper. In particular, we employ the so-called expected value of partial perfect information (EVPPI) as a sensitivity index and apply multilevel Monte Carlo (MLMC) methods to efficient estimation of EVPPI. In a recent paper by Giles and Goda, an antithetic MLMC estimator for EVPPI is proposed and its variance analysis is conducted under some assumptions on a decision model. In this paper, for an improvement on the performance of the MLMC estimator, we incorporate randomized quasi-Monte Carlo methods within the inner sampling, which results in an multilevel quasi-Monte Carlo (MLQMC) estimator. We apply both the antithetic MLMC and MLQMC estimators to a simple waterflooding decision problem under uncertainty on absolute permeability and relative permeability curves. Through numerical experiments, we compare the performances of the MLMC and MLQMC estimators and confirm a significant advantage of the MLQMC estimator.     

AKARI—Infrared Satellite Mission—Present Status and Early Results

AKARI, formerly known as ASTRO-F, is a satellite mission dedicated to infrared astronomy for the first time in Japan. It has a 685-mm aperture telescope with two focal-plane instruments cooled by liquid helium (LHe) and mechanical coolers on board for observations in the 2–180 μm infrared spectral range. AKARI was launched on 2006 February 21 (UT) into a sun-synchronous polar orbit and started observations in May, 2006. It carried 179 liter LHe that lasted for 550 days and observations with LHe were carried out for more than 15 months. During the LHe holding period, AKARI made all-sky survey observations with six bands from 9 to 160 μm, which surpass the IRAS all-sky survey data in the sensitivity, spatial resolution, and spectral coverage. Together with the all-sky observation, AKARI also made pointing observations for about 10 min at a given position of the sky to execute deep imaging and spectroscopy from near- to far-infrared. Both focal-plane instruments work successfully on orbit and more than 90% of the sky was observed in the all-sky survey. After LHe exhaustion, near-infrared observations are planned to continue. This paper reports the in-orbit performance of AKARI and its early observational results so far obtained.