Polymetallic and Au-Ag Mineralizations at the Mutnovskoe Deposit in South Kamchatka, Russia

Abstract. The Mutnovskoe deposit located in the Porozhisto‐Asachinskaya metallogenic province of South Kamchatka, Russia, is a polymetallic vein and Au‐Ag quartz vein associated type of hydrothermal deposit. The Mutnovskoe deposit is located inside a paleo‐caldera structure at the center of the Mutnovsko‐Asachinskaya geothermal field of Pliocene ‐ Quaternary age, where active gold deposition is identified in hot spring precipitate. The Mutnovskoe deposit is subdivided into the north flank, the central flank and the south flank based on the vein distributions and mineral parageneses. The mineralized vein system is oriented N‐S hosted in diorite ‐ gabbroic diorite stock, volcanic rocks and sedimentary rocks of Miocene ‐ Pleistocene age. The mineralization stage I (polymetallic vein) mainly in the central and the south flanks is Zn‐Pb‐Cu‐Au‐Ag contained in sphalerite, galena and tetrahedrite‐tennantite group mineral. The stage II (Au‐Ag quartz vein) occurs in the north and the central flanks. The stage III (Mn‐sulfide and Mn‐Ca‐carbonate vein) occurs in the whole deposit area. Stage II is the typical Au‐Ag quartz‐adularia vein of low‐sulfidation type. Stage III is alabandite‐rhodochrosite‐quartz‐calcite vein. The K‐Ar ages are 1.3±0.1 Ma for stage I sericite in alteration zone, and 0.7±0.1 Ma for the stage II adularia in mineralized vein. Based on the fluid inclusion study, range of ore forming temperature of the Mutnovskoe deposit is 200 to 260d?C (av. 230d?C). Salinities of fluid inclusions indicate 2.2 to 5.7 wt% NaCl in sphalerite and 0.8 to 3.3 wt% NaCl in quartz for the stage I. Mineral paragenesis of the polymetallic vein (stage I) is characterized by a district zoning of tennantite and Cd‐rich sphalerite in the south flank and tetrahedrite and Mn‐rich sphalerite in the central flank, which is due to the fractional crystallizations of ore‐forming fluid. Depositional condition of the low sulfidation state is inferred for the Mutnovskoe deposit, where the polymetallic vein of the south flank is in relatively higher sulfidation state than the central flank.     

Occurrence and seasonal variations of algal toxins in water, phytoplankton and shellfish from North Stradbroke Island, Queensland, Australia

A number of marine microalgae are known to produce toxins that can accumulate in shellfish and when eaten, lead to toxic and potentially fatal reactions in humans. This paper reports on the occurrence and seasonal variations of algal toxins in the waters, phytoplankton and shellfish of Southeast Queensland, Australia. These algal toxins include okadaic acid (OA), domoic acid (DA), gymnodimine (GD), pectenotoxin-2 (PTX-2) and pectenotoxin-2-seco acid (PTX-2-SA), which were detected in the sampled shellfish and phytoplankton, via HPLC-MS/MS. Dissolved OA, PTX-2 and GD were also detected in the samples collected from the water column. This was the first occasion that DA and GD have been reported in shellfish, phytoplankton and the water column in Queensland waters. Phytoplankton tows contained both the toxic Dinophysis and Pseudo-nitzschia algae species, and are suspected of being the most likely producers of the OA, PTX-2s and DA found in shellfish of this area. The number of cells, however, did not correlate with the amount of toxins present in either shellfish or phytoplankton. This indicates that toxin production by algae varies with time and the species present and that number of cells alone cannot be used as an indicator for the presence of toxins. The presence of OA and PTX-2s were more frequently seen in the summer, while DA and GD were detected throughout the year and without any obvious seasonal patterns.     

X-ray observations of PSR B1259−63 near the 2007 periastron passage

PSR B1259−63 is a 48-ms radio pulsar in a highly eccentric 3.4-yr orbit with a Be star SS 2883. Unpulsed γ-ray, X-ray and radio emission components are observed from the binary system. It is likely that the collision of the pulsar wind with the anisotropic wind of the Be star plays a crucial role in the generation of the observed non-thermal emission. The 2007 periastron passage was observed in unprecedented details with Suzaku , Swift , XMM–Newton and Chandra missions. We present here the results of this campaign and compare them with previous observations. With these data we are able, for the first time, to study the details of the spectral evolution of the source over a 2-month period of the passage of the pulsar close to the Be star. New data confirm the pre-periastron spectral hardening, with the photon index reaching a value smaller than 1.5, observed during a local flux minimum. If the observed X-ray emission is due to the inverse Compton (IC) losses of the 10-MeV electrons, then such a hard spectrum can be a result of Coulomb losses, or can be related to the existence of the low-energy cut-off in the electron spectrum. Alternatively, if the X-ray emission is a synchrotron emission of very high-energy electrons, the observed hard spectrum can be explained if the high-energy electrons are cooled by IC emission in Klein–Nishina regime. Unfortunately, the lack of simultaneous data in the TeV energy band prevents us from making a definite conclusion on the nature of the observed spectral hardening and, therefore, on the origin of the X-ray emission.     

Melting of iron–silicon alloy up to the core–mantle boundary pressure: implications to the thermal structure of the Earth’s core

The melting temperature of Fe–18 wt% Si alloy was determined up to 119 GPa based on a change of laser heating efficiency and the texture of the recovered samples in the laser-heated diamond anvil cell experiments. We have also investigated the subsolidus phase relations of Fe–18 wt% Si alloy by the in-situ X-ray diffraction method and confirmed that the bcc phase is stable at least up to 57 GPa and high temperature. The melting curve of the alloy was fitted by the Simon’s equation, P(GPa)/a = (T _m(K)/T ₀) ^c , with parameters, T ₀ = 1,473 K, a = 3.5 ± 1.1 GPa, and c = 4.5 ± 0.4. The melting temperature of bcc Fe–18 wt% Si alloy is comparable with that of pure iron in the pressure range of this work. The melting temperature of Fe–18 wt% Si alloy is estimated to be 3,300–3,500 K at 135 GPa, and 4,000–4,200 K at around 330 GPa, which may provide the lower bound of the temperatures at the core–mantle boundary and the inner core–outer core boundary if the light element in the core is silicon.     

Determination of the oxidation state of radiogenic Pb in natural zircon using X-ray absorption near-edge structure

We examined the L_III-edge Pb X-ray absorption near-edge structure (XANES) of three natural zircon samples with different amounts of radiation doses (1.9 × 10¹⁵ to 6.8 × 10¹⁵ α-decay events/mg). The results suggest that the oxidation state of radiogenic Pb in the zircon sample with the highest radiation dose is divalent. The XANES spectra of the two other samples with lower radiation doses suggest that radiogenic Pb(II) is present, and further that some Pb may be tetravalent. This is the first work on the determination of the oxidation state of radiogenic Pb in natural zircon using XANES.     

Field Survey of the 1996 Irian Jaya Earthquake Tsunami in Biak Island

Runup data in Biak Island and itsnearby islets are described with discussions oftsunami magnitude and a few characteristics such aswitnessed arrival times, wave periods and wavenumbers. From an engineering viewpoint, a relationbetween inundation depth and current velocity on landis also described with relations between inundationdepth and degree of damage to houses and between sanderosion depth and current velocity in backshoreregion, based on data collected from the present andpast tsunamis.     

Numerical simulation of the 1992 Flores tsunami: Interpretation of tsunami phenomena in northeastern Flores Island and damage at Babi Island

Numerical analysis of the 1992 Flores Island, Indonesia earthquake tsunami is carried out with the composite fault model consisting of two different slip values. Computed results show good agreement with the measured runup heights in the northeastern part of Flores Island, except for those in the southern shore of Hading Bay and at Riangkroko. The landslides in the southern part of Hading Bay could generate local tsunamis of more than 10 m. The circular-arc slip model proposed in this study for wave generation due to landslides shows better results than the subsidence model, It is, however, difficult to reproduce the tsunami runup height of 26.2 m at Riangkroko, which was extraordinarily high compared to other places. The wave propagation process on a sea bottom with a steep slope, as well as landslides, may be the cause of the amplification of tsunami at Riangkroko. The simulation model demonstrates that the reflected wave along the northeastern shore of Flores Island, accompanying a high hydraulic pressure, could be the main cause of severe damage in the southern coast of Babi Island.