Low-Temperature, Low-Pressure Metamorphism of Mn-rich Rocks in the Lienne Syncline, Venn--Stavelot Massif (Belgian Ardennes), and the Role of Carpholite

Low-grade Mn-rich metamorphic rocks of the Lienne syncline (westernpart of the Venn–Stavelot Massif, Belgian Ardennes) havebeen re-examined to evaluate the petrological significance ofcarpholite proper, Mn^2$ Al₂[Si₂O₆](OH)₄. Metamorphic P–Tconditions of these rocks are estimated to be {small tilde}300C1–2 kbar, which is in accordance with the exclusive occurrenceof carpholite in low-P rocks such as hydrothermal environmentselsewhere. Carpholite of the Lienne syncline exclusively occursin quartz-rich segregations. Its composition is close to end-member.Thermodynamic calculations confirm that carpholite is a stablephase at low-pressure–low-temperature conditions, in contrastto ferro- and magnesiocarpholite, which are high-pressure minerals.No information is available on the high-P behaviour of carpholite.The occurrence of carpholite is partly closely associated withspessartine-bearing country rocks, or carpholite is alteredto assemblages with spessartine, sudoite, chlorite, muscoviteand paragonite. Spessartine in these rocks contains minor amountsof hydrogarnet component {(H/4)/[Si$(H/4)] = 0.03–0.06}.The presence of carpholite-spessartine assemblages in theselow-P rocks is in contrast to high-pressure metamorphic rocksfrom other areas, where parageneses such as fem/magnesiocarpholite–chloritoidor magnesiocarpholite–chlorite–kyanite occur. Theappearance of carpholite–garnet assemblages in low-P Mn-richrocks can be explained by contrasting phase relations becauseof a high Mn–Mg partition coefficient between the mineralsunder consideration. In rhodo-chrosite-bearing veins in theLienne syncline, nearly complete replacement of carpholite byspessartine and chlorite is due to the continuous reaction carpholite$ rhodochrosite $ quartz = spessartine $ chlorite $ H₂O $ CO₂,which defines a very low X_co, in the temperature range underconsideration. It is suggested that spessartine (possibly containingsome hydrogarnet component), during prograde metamorphism atlow pressure, becomes stable at a temperature of {small tilde}300C KEY WORDS: carpholite; spessartine; sudoite; Venn–Stavelot Massif; Ardemes ^*Corresponding author. Fax: x49/531/3918131. e-mail: t.theye{at}tu.bs.de     

Origin of the Charnockites of the Louis Lake Batholith, Wind River Range, Wyoming

The 2·63 Ga Louis Lake batholith, a calc-alkalic plutonexposed in Wind River Range of western Wyoming, consists ofminor diorite, quartz diorite, granodiorite, and granite. Atshallow structural levels the batholith is pyroxene free, butat deeper levels, all units of the batholith contain pyroxenes.On its northern margin the batholith was emplaced at P = 5–6kbar, T = 775–800°C, fO₂ at FMQ (fayalite–magnetite–quartz)+ 1·5 to FMQ + 1·8, and aH₂O     

Evidence for Pleistocene wet aeolian dune and interdune accumulation,S. Pedro da Maceda,north‐west Portugal

Outcrops and cored/counter‐flushed boreholes in the coastal area between Espinho and Aveiro (north‐west Portugal) were investigated to reconstruct the changing patterns of sedimentation during the Late Pleistocene–Holocene. To obtain a common comparison basis, the grain‐size data from outcrop and borehole samples were analysed. The outcrops and the cored parts of the boreholes were dated by radiocarbon and optically stimulated luminescence. The results show that, on top of pebble‐rich beds of fluvial origin, a wet aeolian dune and interdune environment was active during the later part of the Pleistocene, turning to dry aeolian at the transition to the Holocene. The data indicate also that aeolian accumulation was controlled by vegetation changes (climate) and groundwater table fluctuations. During the Holocene, a podzol formed on the Pleistocene dunes and extensive vegetation precluded major aeolian accumulations. Remobilization of sand started again because of human deforestation and – last but not least – the Little Ice Age.     

Molecular identification of the extinct mountain goat, Oreamnos harringtoni (Bovidae)

Campos, P. F., Willerslev, E., Mead, J. I., Hofreiter, M. & Gilbert, M. T. P. 2009: Molecular identification of the extinct mountain goat, Oreamnos harringtoni (Bovidae). Boreas , 10.1111/j.1502-3885.2009.00111.x. ISSN 0300-9483.
Harrington's mountain goat ( Oreamnos harringtoni ), an extinct North American herbivore, is one of the least known mammals of the Pleistocene. Fossil specimens are predominantly known from dry cave localities throughout the arid American west – the Grand Canyon, Colorado Plateau, Nevada and Mexico. Morphological analysis of the recovered fossils suggests a close phylogenetic relationship between Harrington's mountain goat and the extant mountain goats from the American northwest ( Oreamnos americanus ). However, the degree of genetic similarity between the two species, and their overall placement within the Caprinae, is not clear. In this study, we recovered and sequenced the first DNA fragments from O. harringtoni in order to investigate these relationships. Genetic analysis further supports the morphological hypothesis that O. harringtoni and O. americanus are two distinct species.     

A recent build-up of atmospheric CO2 over Europe. Part 1: observed signals and possible explanations

We analysed interannual and decadal changes in the atmospheric CO₂ concentration gradient (ΔCO₂) between Europe and the Atlantic Ocean over the period 1995–2007. Fourteen measurement stations are used, with Mace-Head being used to define background conditions. The variability of ΔCO₂ reflects fossil fuel emissions and natural sinks activity over Europe, as well as atmospheric transport variability. The mean ΔCO₂ increased by 1–2 ppm at Eastern European stations (∼30% growth), between 1990–1995 and 2000–2005. This built up of CO₂ over the continent is predominantly a winter signal. If the observed increase of ΔCO₂ is explained by changes in ecosystem fluxes, a loss of about 0.46 Pg C per year would be required during 2000–2005. Even if severe droughts have impacted Western Europe in 2003 and 2005, a sustained CO₂ loss of that magnitude is unlikely to be true. We sought alternative explanations for the observed CO₂ build-up into transport changes and into regional redistribution of fossil fuel CO₂ emissions. Boundary layer heights becoming shallower can only explain 32% of the variance of the signal. Regional changes of emissions may explain up to 27% of the build-up. More insights are given in the Aulagnier et al. companion paper.     

Vegetation and climate history in the Westeifel Volcanic Field (Germany) during the past 11 000 years based on annually laminated lacustrine maar sediments

Lakes Holzmaar and Meerfelder Maar are located in the Westeifel Volcanic Field less than 10 km apart. Both maar lakes are well known for their annually laminated (varved) sediments covering the past 15 000 years. Here, we focus on reconstructing the history of Holocene vegetation, human impact and climate using high-resolution pollen data. Detailed correlation between the two records using palynologically defined tie-points provides for the first time a test of the precision of the individual varve chronologies. The high-resolution pollen records of both Holzmaar and Meerfelder Maar show continuous natural successions of vegetation during the early and mid-Holocene controlled by the development of soil, climate, immigration and competitive expansion of thermophilous tree species. From 6500 varve yr BP onwards, human impact became an increasingly more important factor. Given the high chronological precision of both records, regional similarities, but also local differences of anthropogenically influenced vegetation changes, can be recognized. The reconstructed July temperature between 8500 and 5000 varve yr BP is around 1 °C higher than today, most likely in response to higher summer insolation related to orbital forcing. High variability of reconstructed July and January temperatures as well as annual precipitation around 5000 varve yr BP is a prominent climatic signal. This is consistent with other records in several areas of Europe which also identify this period as climatically highly variable.     

Improved fitting of the Bartlett-Lewis Rectangular Pulse Model for hourly rainfall

Abstract

This paper examines the applicability of the Bartlett-Lewis Rectangular Pulse Model to rainfall taken from a site in Elmdon, Birmingham, UK. The approach used is to assess the performance of the model in terms of characteristics of the precipitation process, incorporating monthly seasonality. Analytical expressions are derived to complement those presented in Rodriguez-Iturbe et al. (1987). As in that paper, the shortcomings of the simple Poisson process are reduced by the use of a Bartlett-Lewis process. Different methods of parameter estimation are examined. The characteristic features of the time distribution of rainfall events, however, can be well approximated only by optimization and this enables an improved identification of the model parameters.     

Vertically resolved dust optical properties during SAMUM: Tinfou compared to Ouarzazate

Vertical profiles of dust key optical properties are presented from measurements during the Saharan Mineral Dust Experiment (SAMUM) by Raman and depolarization lidar at two ground-based sites and by airborne high spectral resolution lidar. One of the sites, Tinfou, is located close to the border of the Sahara in Southern Morocco and was the main in situ site during SAMUM. The other site was Ouarzazate airport, the main lidar site. From the lidar measurements the spatial distribution of the dust between Tinfou and Ouarzazate was derived for 1 d. The retrieved profiles of backscatter and extinction coefficients and particle depolarization ratios show comparable dust optical properties, a similar vertical structure of the dust layer, and a height of about 4 km asl at both sites. The airborne cross-section of the extinction coefficient at the two sites confirms the low variability in dust properties. Although the general picture of the dust layer was similar, the lidar measurements reveal a higher dust load closer to the dust source. Nevertheless, the observed intensive optical properties were the same. These results indicate that the lidar measurements at two sites close to the dust source are both representative for the SAMUM dust conditions.