Thoughts on ‘MgSO4 ion association in seawater’ by Fisher,Gieskes and Hsu

The correct values of the association constants of MgSO₄ and the adequacy of using the Debye—Hückel equation are considered.     

Transversal ejection-collision orbits in Hill's problem forC≫1

In a recent paper [3], Lacomba and Llibre showed numerically the existence of two transversal ejection-collision orbits in Hill's problem for a valueC=5 of the Jacobian constant. This result can be used to prove the non-existence ofC ¹-extendable regular integrals for Hill's problem. Here we give an analytic proof of the existence of four ejection-collision orbits which are transversal for large enough values ofC.     

Embryotoxicity of the antifouling biocide zinc pyrithione to sea urchin (Paracentrotus lividus) and mussel (Mytilus edulis)

The effects of the new antifouling compound zinc pyrithione (Zpt) on the embryonic development of sea urchin (Paracentrotus lividus) and mussel (Mytilus edulis) were investigated in laboratory toxicity tests. The median effective concentrations (EC50) were 7.7 nM for sea urchin embryos and 8 nM for mussel embryos. Toxic effects of Zpt on the larval growth of the sea urchin were detected at 0.5 nM. Predicted environmental concentrations of Zpt in pleasure craft harbours are higher than the predicted no effect concentrations for sea urchin and mussel embryos, indicating that Zpt may pose a threat to those species from exposure in the field.     

Water quality and presence of pesticides in a tropical coastal wetland in southern Mexico

The water quality of the Pozuelos-Murillo lagoon system in southern Mexico was evaluated during three periods between March and October 2002, with particular emphasis on the detection of organochlorine and organophosphorous pesticide residues in water and sediments. Physicochemical and microbiological parameters of water were also measured and integrated in a water quality index (WQI). Multivariate analysis was used to regionalise the lagoon system as a function of the behaviour of all measured parameters. Solid phase micro-extraction followed by gas chromatography (SPME-GC) was used for pesticide analysis. The concentration of phosphorous was found to be higher than that of nitrogenous compounds. This, besides a deficiency in dissolved oxygen and a high organic matter concentration (as COD), reflects eutrophication processes in some areas of the system. Measured levels of faecal coliforms and oils and greases were above the limits established by Mexican law and comparable to the concentrations reported for other highly polluted systems in Mexico. Residues of DDD (2.0 microg L(-1)) in water and DDE (247 ng g(-1)) and endosulfan I (814 ng g(-1)) sediments were detected by SPME-GC. The spatial distribution of these contaminants implies major potential risks because the most polluted sites were found to be those with the highest fishing activity. Although in general the WQI is on acceptable levels (65-80%), some contamination problems are evident.     

Biomarkers of exposure and effect in the Brazilian flounder Paralichthys orbignyanus (Teleostei: Paralichthyidae) from the Patos Lagoon estuary (Southern Brazil)

Biomarkers of exposure (liver metallothionein-like proteins content and catalase and glutathione S-transferase activities) and effect (liver lipoperoxidation and blood cell DNA damage) of contaminants were analyzed in the Brazilian flounder Paralichthys orbignyanus from the Patos Lagoon estuary (Southern Brazil). Flounders were collected for a year in two sites: "Coroa do Boi" (polluted site) and "Saco do Justino" (non-polluted site). Results indicated that micronucleated cells frequency was the best biomarker to distinguish flounders from the two sites. Taken together, data from DNA damage analyses (micronucleus test and comet assay) indicated that flounders from the non-polluted site efficiently repaired the DNA breaks, contrary to those from the polluted site, which probably had their DNA repair system inhibited or exhausted. Furthermore, data from enzyme activities (catalase and GST) and lipid peroxidation indicated that flounders from the polluted site were under oxidative stress in summer and autumn.     

Starbursts at space ultraviolet wavelengths

Starbursts are systems with very high star formation rate per unit area. They are the preferred place where massive stars form; the main source of thermal and mechanical heating in the interstellar medium, and the factory where the heavy elements form. Thus, starbursts play an important role in the origin and evolution of galaxies. The similarities between the physical properties of local starbursts and high-z star-forming galaxies, highlight the cosmological relevance of starbursts. On the other hand, nearby starbursts are laboratories where to study violent star formation processes and their interaction with the interstellar and intergalactic media, in detail and deeply. Starbursts are bright at ultraviolet (UV) wavelengths, as they are in the far-infrared, due to the ‘picket-fence’ interstellar dust distribution. After the pioneering IUE program, high spatial and spectral resolution UV observations of local starburst galaxies, mainly taken with HST and FUSE, have made relevant contributions to the following issues:

The determination of the initial mass function (IMF) in violent star forming systems in low and high metallicity environments, and in dense (e.g. in stellar clusters) and diffuse environments: A Salpeter IMF with high-mass stars constrains well the UV properties.

The modes of star formation: Starburst clusters are an important mode of star formation. Super-stellar clusters have properties similar to globular clusters.

The role of starbursts in AGN: Nuclear starbursts can dominate the UV light in Seyfert 2 galaxies, having bolometric luminosities similar to the estimated bolometric luminosities of the obscured AGN.

The interaction between massive stars and the interstellar and intergalactic media: Outflows in cold, warm and coronal phases leave their imprints on the UV interstellar lines. Outflows of a few hundred km s^?1 are ubiquitous phenomena in starbursts. These metal-rich outflows and the ionizing radiation can travel to the halo of galaxies and reach the intergalactic medium.

The contribution of starbursts to the reionization of the universe: In the local universe, the fraction of ionizing photons that escape from galaxies and reach the intergalactic medium is of a few percent. However, in high-z star-forming galaxies, the results are more controversial.

Despite the very significant progress over the past two decades in our understanding of the starburst phenomenon through the study of the physical processes revealed at satellite UV wavelengths, there are important problems that still need to be solved. High-spatial resolution UV observations of nearby starbursts are crucial to further progress in understanding the violent star formation processes in galaxies, the interaction between the stellar clusters and the interstellar medium, and the variation of the IMF. High-spatial resolution spectra are also needed to isolate the light from the center to the disk in UV luminous galaxies at z = 0.1–0.3 found by GALEX. Thus, a new UV mission furnished with an intermediate spectral resolution long-slit spectrograph with high spatial resolution and high UV sensitivity is required to further progress in the study of starburst galaxies and their impact on the evolution of galaxies.     

On final evolutions in the restricted planar parabolic three-body problem

In this paper, we prove the existence of special type of motions in the restricted planar parabolic three-body problem, of the type exchange, emission–capture, and emission–escape with close passages to collinear and equilateral triangle configuration, among others. The proof is based on a gradient-like property of the Jacobian function when equations of motion are written in a rotating–pulsating reference frame, and the extended phase space is compactified in the time direction. Thus a phase space diffeomorphic to -coordinates (θ, ζ, ζ′) is obtained with the boundary manifolds θ = ± π/2 corresponding to escapes of the binaries when time tends to ± ∞. It is shown there exists exactly five critical points on each boundary, corresponding to classic homographic solutions. The connections of the invariant manifolds associated to the collinear configurations, and stable/unstable sets associated to binary collision on the boundary manifolds, are obtained for arbitrary masses of the primaries. For equal masses extra connections are obtained, which include equilateral configurations. Based on the gradient-like property, a geometric criterion for capture is proposed and is compared with a criterion introduced by Merman (1953b) in the fifties, and an example studied numerically by Kocina (1954).     

An exotic Cretaceous kimberlite linked to metasomatized lithospheric mantle beneath the southwestern margin of the Francisco Craton,Brazil

We present major and trace element compositions of mineral concentrates comprising garnet xenocrysts,ilmenite,phlogopite,spinel,zircon,and uncommon minerals (ti...