Analysis of the spatial variation of heavy metals in the Guadiana Estuary sediments (SW Iberian Peninsula) based on GIS-mapping techniques

This work reveals the usefulness of the GIS (Geographic Information Systems) mapping techniques to show the distribution of pollutants along an estuarine environment, as the final stage of a thorough study. In the case of study, the environmental quality of the sediments in the Guadiana river estuary was determined by means of a complete geochemical characterization consisting on the calculation of enrichment factors for the most important metals and metalloids (compared with the local background of non-contaminated sediments). The obtained results were depicted in “enrichment distribution maps” which evidenced a distribution of the elements in two groups: Group-I, elements with natural origin (Al, Fe, Mn, Co, and Cr) distributed homogeneously along the basin, and Group-II, elements associated to anthropic origin (As, Cd, Cu, Pb, Ni and Zn) with clear punctual sources besides a high concentration all over the estuary. The enrichment factors for the elements of Group-II are indicative of the existence of a noticeable diffuse historical mining pollution associated with the acid mine drainage generated in the internal zones of the basin, which could overlap minor pollution inputs from other human activities. The obtained results lead us to a reconsideration of the traditionally thought “unpolluted” environment when it was compared to nearby estuaries.     

Inorganic arsenic speciation in the waters of the Penzé estuary (NW France): Seasonal variations and fluxes to the coastal area

Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux.     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.     

Multispectral remote sensing of biomass burning in West Africa

Remote sensing measurements provide a vauable means of determining the extent of burning areas and of estimating the overall distribution of pollutant sources (identified from experimental studies) in time and space. This distribution has to be taken into account in the boundary conditions of chemistry atmospheric models.Recent methods developed for the remote sensing of active fires in tropical or temperated forest zones, have been found to be completely inadequate for fire detection on West African savannas. In order to accurately estimate the active fire distribution in the function of different sorts of West African savannas (Sahelian, Sudanian and Guinean) and forests, a multispectral methodology has been developed based on NOAA/11-AVHRR satellite data, with the purpose of eliminating as much as possible the problems related to large surface heterogeneity, confusion and bias, produced by clouds, smoke, haze, background emissivities, etc.Unlike other methods, the results show that the multispectral method, in spite of its selectivity, provides realistic results, and does not under- or over-estimate the number of fires that can be sensed by the satellite. Consequently, this methodology is more appropriate than the simplest ones for a systematic sensing of this phenomenon.     

Seismic analysis of multiply supported secondary systems with dynamic interaction effects

For a proper response spectrum analysis of a secondary system with multiple supports, the seismic inputs are required to be defined in terms of the auto and cross floor response spectra. If no feed-back or interaction effect from the secondary system to its supporting primary structure is suspected, these inputs can be developed by a direct analysis of the supporting structure alone. However, sometimes the effect of the interaction on the secondary system response can be quite significant. Herein, a method is developed to incorporate the feed-back effect, through proper modification of the interaction-free floor spectrum inputs. The interaction coefficients are used to effect such modifications in different floor spectral quantities. A procedure for the calculation of the interaction coefficients is proposed. The modified floor spectra when used as inputs to the secondary system do introduce the interaction effect in the secondary system response. A successful application of this method is demonstrated by numerical examples of secondary systems with three different secondary-to-primary system mass ratios.     

Morphology of the Itapeva to Tramandai transgressive dunefield barrier system and mid‐ to late Holocene sea level change

The surface morphology of the transgressive dunefield barrier extending from Itapeva to Tramandai along the northern littoral of Rio Grande do Sul, is examined and an attempt is presented to link morphological changes across the barrier to Holocene sea level changes. The 4·5 km wide Holocene barrier displays two typical morphologies: an inner part dominated by large‐scale, continuous alongshore, overlapping dunefield phases comprising sand sheets, dunes, deflation plains and precipitation ridges; and an outer part dominated by discontinuous, medium‐ to small‐scale, triangular to lobate transgressive dunefield phases, cut by both active and relict (palaeo‐) creeks or washouts. Holocene sea level in the region rose to c. +1 to +3 m above present reaching a maximum around 5100 years bp and then progressively fell to the present level. We argue that the effect on barrier development was to suppress the development of a drainage system during the rising and maximum stages, and encourage the development of an organized drainage system in the form of regularly spaced washouts during the falling period, and that this change in sea level from rising to falling therefore produced the large‐scale differences in barrier morphology. Copyright © 2006 John Wiley & Sons, Ltd.     

Acceleration response modification factors for nonstructural components attached to inelastic moment‐resisting frame structures

A statistical analysis of the peak acceleration demands for nonstructural components (NSCs) supported on a variety of stiff and flexible inelastic regular moment‐resisting frame structures with periods from 0.3 to 3.0 s exposed to 40 far‐field ground motions is presented. Peak component acceleration (PCA) demands were quantified based on the floor response spectrum (FRS) method without considering dynamic interaction effects. This study evaluated the main factors that influence the amplification or decrease of FRS values caused by inelasticity in the primary structure in three distinct spectral regions namely long‐period, fundamental‐period, and short‐period region. The amplification or decrease of peak elastic acceleration demands depends on the location of the NSC in the supporting structure, periods of the component and building, damping ratio of the component, and level of inelasticity of the supporting structure. While FRS values at the initial modal periods of the supporting structure are reduced due to inelastic action in the primary structure, the region between the modal periods experiences an increase in PCA demands. A parameter denoted as acceleration response modification factor (R_acc) was proposed to quantify this reduction/increase in PCA demands. Copyright © 2007 John Wiley & Sons, Ltd.