A frequency criterion for optimal node selection in smoothing with cubic splines

When smoothing a function with high‐frequency noise by means of optimal cubic splines, it is often not clear how to choose the number of nodes. The more nodes are used, the closer the smoothed function will follow the noisy one. In this work, we show that more nodes mean a better approximation of Fourier coefficients for higher frequencies. Thus, the number of nodes can be determined by specifying a frequency up to which all Fourier coefficients must be preserved and increasing the number of nodes until this criterion is met. A comparison of the corresponding smoothing results with those obtained by filtering using moving average and moving median filters of corresponding length and a low pass with corresponding high‐cut frequency shows that optimal cubic splines yield better results as they preserve not only the desired low‐frequency band but also important high‐frequency characteristics.     

Effects of the 'Prestige' oil spill on macroalgal assemblages: large-scale comparison

An assessment of the effects of the 'Prestige' oil spill on intertidal, macroalgal assemblages was carried out comparing abundance data obtained before and after the spill. Four zones in the North and Northwest coast of Spain were sampled, one of them located at the immediate vicinity of the spill, the zone most heavily oiled. Macroalgal assemblages had similar structure between years. Neither critical decrease in abundance of the dominant macroalgae, nor increase in opportunistic species were found. Some differences in abundance were observed, but they did not show any pattern, being more likely the result of the natural variability of the assemblage. Extensive, but not intense fuel deposition on the shores and a limited use of aggressive cleanup methods are suggested as possible causes for the lack of the effects in these assemblages after the 'Prestige' oil spill.     

Rare earth elements in sediments of the Vigo Ria,NW Iberian Peninsula

The abundance and distribution of rare earth elements (REE) and their signatures in the Vigo Ria were studied from 50 samples of surface sediments and related to the geological formation in its watershed. The total amount of REE in the Ria is heterogeneous. It ranges from 220 mg kg⁻¹ in the southern middle Ria margin in the vicinity of the Galiñeiro geological shore complex, which contains REE-enriched minerals, to 2 mg kg⁻¹ near the Ria mouth due to dilution with high levels of carbonated biogenic particles (31% of Ca). Rare earth elements of the Ria sediments are considerably enriched in light-REE relative to heavy-REE (a LREE/HREE ratio of 9.7±1.6) and also show a slightly negative Eu-anomaly. Low European shale normalised REE patterns were distinguished in the innermost sediments of Vigo Ria, but were not correlated with Al. This suggests a minor contribution of REE from upstream freshwater inputs to the sediments in the middle Vigo Ria zone. Normalised REE ratios in the middle Ria imply that fine particles enriched in REE may be exported from the Ria to shelf mud patches and REE can be useful as sediment tracers of Ria input on the shelf.     

Shear effects on hollow section piers under seismic actions: experimental and numerical analysis

Shear effects are often a very important issue on the seismic behaviour of piers, particularly for hollow section bridge piers. In fact, for this type of piers the cyclic response is similar to that of a structural wall in which both the transverse reinforcement ratio and the detailing can play an important role on its performance, even likely to be determinant in terms of the failure mechanism. On the other hand, codes and design guidelines are usually very conservative concerning shear capacity in order to avoid any shear failure mechanism likely to trigger well known catastrophic consequences. Therefore, research studies on this topic are still needed for a better understanding of pier cyclic shear response and also for improvement of the performance under seismic actions. Pursuing this general objective, this paper partially reports on an experimental/numerical campaign carried out on 1:4 reduced scale bridge piers in order to highlight and investigate shear-type problems. Within the scope of this paper, two specimens types were selected having equal rectangular hollow section (900 × 450 mm², 75 mm thick) but different transverse reinforcement detailing, namely one with a single stirrup per wall (representative of typical bridge construction without seismic design requirements) and another with multiple stirrups, according to Eurocode 8 provisions. Numerical simulations of the experimental results were also conducted aiming at contributing for complete and consistent interpretations of experimental results. Detailed modelling was performed allowing for realistic simulations of the non linear behaviour, particularly suitable when a significant shear component is involved. Therefore, the numerical strategy was based on a detailed 3D FEM discretization using a two-scalar variable damage model for the concrete constitutive law and a suitable cyclic behaviour law for steel bars represented by truss elements. Results have shown that shear deformation and failure modes are well simulated, while providing detailed insight concerning concrete damage pattern and distribution of yielding on the transverse and longitudinal reinforcement.     

Study of Metal Distribution in Raw and Screened Swine Manure

The growth of industrial swine production over the last few years has led to a growth in concern over effluents generated by the activity. Several elements, mainly toxic metals, can be present in swine wastewater and can have a serious environmental impact. It is important, therefore, to know the metal concentration before the discharge of wastewater. In this work the temporal metal distribution in swine manure and its potential reduction using coarse (2 mm) and fine (<0.45 μm) liquid‐solid separation techniques were investigated. In order to do this, different swine manure sample preparation methods for Al, Ba, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr and Zn determination by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were tested. The acid mixtures used to digest the manure sample significantly affected the metal recovery. Good analyte recoveries were observed with nitric acid/hydrogen peroxide mixtures or nitric acid/perchloric acid mixtures. Sulfuric acid/hydrogen peroxide mixtures produced inconsistent results and poor recoveries, mainly for Ba and Pb. It was observed that metal concentrations in swine manure varied greatly with time, up to one order of magnitude, due to changes in swine production such as feed and animal numbers. Metals concentrations observed in the raw wastewater exceeded Brazilian limits for discharge into water bodies and recommendations for agricultural use. Results obtained from the liquid‐solid separation study showed that metals in the raw swine manure were not removed with coarse screening. However, the major fraction of metals were removed by filtration (0.45 μm), with the exception of Na, K and Sr. Thus, the use of liquid‐solid separation techniques that capture the fine solid fractions (and associated metals) from raw manure can have a favorable impact on the environment and contribute to swine production wastewater treatment.     

Quantifying Multipath Using MNR Ratios

The global positioning system (GPS) is used increasingly to control horizontal and vertical displacement of large civil constructions. The displacements can occur over varius time scales. For example, in case of the loading test of a bridge, the time span between measurements is on the order of 30 min. The achievable precision in the vertical component and its relation to residual multiplath effects become critically important in such aaplications. A multipath-to-noise ratio (MNR) on individual satellites is introduced to quantify the multipath effects. ? 2000 John Wiley & Sons, Inc.     

Magnitude-Intensity Relationships in the Ibero-Magrebhian Region

In this paper we present magnitude (Ms) – magnitude(mb) and magnitude-intensity relationships which areconsidered the most adequate in the Ibero-Maghrebianregion. This work is based on selected samples ofrecently revised events with magnitude mb assigned bythe Instituto Geográfico Nacional (I.G.N.) and Msassigned by I.S.C and N.E.I.C., and isoseismal mapsfrom 142 events. Using these data, we have obtainedone magnitude (Ms) – magnitude (mb) relationship, twomagnitude (mb and Ms) assignment relationships viaepicentral intensity (I₀), and ten magnitude (mb andMs) assignments relationships via macroseismicinformation: four using Ambraseys' methodology (1985)and six using the isoseismal area of degree III, IV and VI.According to the obtained results it could be concluded that historical magnitude assignment with lesser uncertainties are those obtained via macroseismic information using magnitude-intensity relationships with Ambraseys' methodology (1985). The magnitude-isoseismal area assignment relationships have, in most cases, great differences depending on the degree of the isoseismal area used. Magnitude assignments via epicentral intensity have the highest uncertainties. Geographic regionalization of the relationshipshas been studied but the highest correlations and statistical significance are obtained when we fit all the Ibero-Maghrebian region data.Finally we have used the results obtained in this workto assign magnitude to some important historicalearthquakes in the Ibero-Maghrebian region: the 1755Lisbon earthquake, the 1680 Málaga earthquake, the1829 Torrevieja earthquake and the 1884 Arenas del Reyearthquake. According to our relationships andmethodology we have assigned an Ms value of 9.3 ±0.6 to the 1755 Lisbon earthquake (its mb magnitudecannot be estimated due to the saturation of the mbscale), an mb value of 6.3 ±0.4 and an Ms valueof 6.9 ± 0.6 to the 1829 Torrevieja earthquake, anmb value of 6.2 ± 0.4 and an Ms value of 6.4 ±0.6 to the 1680 Málaga earthquake and an mb valueof 6.1 ± 0.4 and an Ms value of 6.5 ± 0.6 tothe 1884 Arenas del Rey earthquake.     

Upper Ocean Temperatures Hit Record High in 2020

The long-term warming of the ocean is a critical indicator of both the past and present state of the climate system. It also provides insights about the changes to come, owing to the persistence of both decadal variations and secular trends,which the ocean records extremely well(Hansen et al., 2011;IPCC, 2013;Rhein et al., 2013;Trenberth et al., 2016;Abram et al., 2019).     

Pyrite formation driven by MSW landfill leachate in the Madrid Basin, Spain

The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H₂S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ³⁴S values for sulfates were consistent with previously reported data; however, the measured δ¹⁸O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ³⁴S values (≈−8‰) than gypsum-coating pyrite crystals (δ³⁴S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H₂S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as