A possible Caledonide arm through the Barents Sea imaged by OBS data

The assembly of the crystalline basement of the western Barents Sea is related to the Caledonian orogeny during the Silurian. However, the development southeast of Svalbard is not well understood, as conventional seismic reflection data does not provide reliable mapping below the Permian sequence. A wide-angle seismic survey from 1998, conducted with ocean bottom seismometers in the northwestern Barents Sea, provides data that enables the identification and mapping of the depths to crystalline basement and Moho by ray tracing and inversion. The four profiles modeled show pre-Permian basins and highs with a configuration distinct from later Mesozoic structural elements. Several strong reflections from within the crystalline crust indicate an inhomogeneous basement terrain. Refractions from the top of the basement together with reflections from the Moho constrain the basement velocity to increase from 6.3 km s⁻¹ at the top to 6.6 km s⁻¹ at the base of the crust. On two profiles, the Moho deepens locally into root structures, which are associated with high top mantle velocities of 8.5 km s⁻¹. Combined P- and S-wave data indicate a mixed sand/clay/carbonate lithology for the sedimentary section, and a predominantly felsic to intermediate crystalline crust. In general, the top basement and Moho surfaces exhibit poor correlation with the observed gravity field, and the gravity models required high-density bodies in the basement and upper mantle to account for the positive gravity anomalies in the area. Comparisons with the Ural suture zone suggest that the Barents Sea data may be interpreted in terms of a proto-Caledonian subduction zone dipping to the southeast, with a crustal root representing remnant of the continental collision, and high mantle velocities and densities representing eclogitized oceanic crust. High-density bodies within the crystalline crust may be accreted island arc or oceanic terrain. The mapped trend of the suture resembles a previously published model of the Caledonian orogeny. This model postulates a separate branch extending into central parts of the Barents Sea coupled with the northerly trending Svalbard Caledonides, and a microcontinent consisting of Svalbard and northern parts of the Barents Sea independent of Laurentia and Baltica at the time. Later, compressional faulting within the suture zone apparently formed the Sentralbanken High.     

Interaction between runoff – bedrock groundwater in a steep headwater catchment underlain by sedimentary bedrock fractured by gravitational deformation

Recent studies have suggested the importance of the bedrock groundwater (BG) contribution in storm runoff in headwater catchments. However, few such studies have been conducted, and the study of different types of bedrock conditions is still ongoing. The role of BG in storm runoff is still poorly understood, particularly in headwater catchments underlain by relatively deep fractured bedrock. This study aims to clarify this role using hydrometric and hydrochemical observations of BG via boreholes and catchment discharge. The responses of the BG to rainfall are demonstrated to be fast and independent of the sediment cover. The BG exhibits different responses and flow paths that are largely controlled by the bedrock fracture system. The storm runoff in the studied catchment is characterized by rapid discharge response generally followed by a delayed discharge response. The peak of the delayed discharge is much faster than that observed in previous studies, and it is well correlated with the BG levels. A hydrograph separation was performed for two storm events using three end members: rainfall, shallow BG and deep BG. The results demonstrate that the delayed discharge is primarily composed of deep BG. Moreover, a significant contribution of shallow BG is observed during large precipitation events. Although we observed no physical evidence of direct contributions of BG in the catchment, the calculations presented in this study demonstrate that the BG controls the hydrological and hydrogeological response of the catchment to rainfall events. Copyright © 2015 John Wiley & Sons, Ltd.     

Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.