ON THE CHARACTERISTICS OF NON-LINEAR SOIL RESPONSE AND DYNAMIC SOIL PROPERTIES USING VERTICAL ARRAY DATA IN JAPAN

Non-linear response of the soil is investigated by comparing the spectral ratios (uphole/downhole) using weak and strong motions. Data from seven vertical arrays in Japan are analysed in this study. The frequency-dependent transfer function of soil is calculated as a ratio of the spectrum at uphole to the spectrum at downhole, considering the horizontal component of shear wave. In spectral ratio analysis auto- and cross-spectra are employed. The reduction in the predominant frequency of the transfer function with increases in excitation level reflects the non-linear response of the soil. Results of analysis demonstrate a significant non-linear ground response at six sites with surface PGA exceeding 90 gal. However, the results of one site show the linear response up to 130 gal surface PGA. Furthermore, the in situ strain-dependent soil behaviour is examined through the shear modulus – shear strain relationship. When compared, the actual and laboratory results of the shear strain – shear modulus relationship are in agreement. Additionally, a good consistency between the tendency of reduction in shear modulus ratio with shear strain increases, and reduction of predominant frequency with ground motion increases, confirms the significance of non-linearity in site effects study.     

A comment on determining the induced magnetic field in bodies of arbitrary shape

Summary The authors prove that the solution of Laplace's equation under Neumann's boundary conditions can be transformed to an advantage into determining the field which is generated by charges, induced by the external field at surfaces of discontinuity.     

Experimental study of igneous and sedimentary apatite dissolution: Control of pH, distance from equilibrium, and temperature on dissolution rates

Apatite dissolution experiments were conducted using both a fluidized bed and stirred tank reactor over a range of pH, temperature, solution saturation state, and on non-carbonated and carbonated apatite compositions: igneous fluorapatite (FAP) and sedimentary carbonate fluorapatite (CFA), respectively. From 2 <pH <6, the rate of release from dissolution of all apatite components [calcium (Ca), phosphorus (P), and fluoride (F)] increased with decreasing pH for FAP. From 6 < pH < 8.5, the FAP dissolution rate is pH independent. Measuring apatite dissolution rates at pH > 8.5 were not possible due to detection limits of the analytical techniques used in this study and the high insolubility of FAP. For the CFA compositions studied, the dissolution rate decreased with increasing pH from 4 < pH < 7. During early stages of the dissolution reaction for both FAP and CFA, mineral components were released in non-stoichiometric ratios with reacted solution ratios of dissolved Ca:P and Ca:F being greater than mineral stoichiometric ratios, suggesting that Ca was preferentially released compared to P and F from the mineral structure during the early stages of dissolution. An increase in reacted solution pH accompanies this early elevated release of Ca. As the dissolution reaction proceeded to steady state, dissolution became congruent. When normalized to BET measured surface area, FAP dissolved faster from 4 < pH < 7 compared to CFA. The apparent Arrhenius activation energy (E_a) of FAP dissolution over the temperature range of 25-55°C at pH = 3.0, I = 0.1, and pCO₂ = 0 is 8.3 ± 0.2 kcal mol⁻¹. Both the apparent exchange of solution H⁺ for solid-bound Ca at low pH in the early stage of dissolution and the E_a of dissolution suggest a surface and not a diffusion controlled dissolution reaction for FAP and CFA. The degree of undersaturation of the solution, ΔG_R, with respect to FAP was important in determining the dissolution rate. At pH = 3.0, I = 0.1, and pCO₂ = 0, the dissolution rate of FAP was ∼ 5× greater in the far-from-equilibrium region compared to the near-equilibrium slope region.A simple apatite weathering model incorporating the experimental results from this study was constructed, and numerical calculations suggest that during the Phanerozoic both the surface area of igneous rock available for weathering and the average global temperature were important factors in determining the P weathering flux from apatite dissolution. It is possible that elevated global temperatures coupled with relatively high surface area of igneous rock during the early- to mid-Paleozoic resulted in elevated P weathering fluxes, which along with climatic evolutionary pressures of the Neoproterozoic, facilitated the radiation of multicellular organisms, large-scale phosphorite deposition, and abundance of calcium phosphate shelled organisms during the early Cambrian.     

The assemblage quartz — Sillimanite — Garnet — Cordierite as an indicator of metamorphic conditions in the Daly Bay Complex,N.W.T.

If cordierite is treated as an anhydrous mineral, the composition of garnet and cordierite, coexisting with quartz and silliminate, depends on total pressure and temperature. Phase relations may be deduced by combining some available experimental work with several approximations. Assuming ideal ionic solution in garnet and cordierite, analyses of coexisting garnet and cordierite permit the determination of total pressure and temperature. Five rocks from the Daly Bay Complex, N. W. T., collected from locations up to 35 miles apart, indicate a range of 610–760 and 5.3–6.6 kb.     

Holocene changes in seasonal precipitation highlighted by fire incidence in eastern Canada

Postglacial fire history has been reconstructed for eastern Canada from charcoal-influx anomalies from 30 sites taken from a lacustrine charcoal database. The reconstruction exhibits coherent patterns of fire occurrence in space and time. The early Holocene is characterised by high fire incidence. There is a major change to much lower occurrence slightly after 8 ka BP. A return to more fire appears after 3 ka BP. This sequence does not fit with the hydro-climatic reconstruction deduced from lake level reconstructions for northeastern North America, which indicates a dry early and mid-Holocene, and a wet late-Holocene. Fire occurrence however closely matches summer relative humidity inferred from δ¹⁸O. The differences between fire frequency and lake level history, are due to changes in the seasonality of precipitation and drought frequency. Lake levels are essentially controlled by winter precipitation while summer precipitation controls fire occurrence. The early Holocene before 8–7.5 ka BP experienced dry summers due to higher solar radiation and dry adiabatic winds from the residual Laurentide Ice Sheet. The middle Holocene was dominated by wet summers due to stability of the Atlantic air mass over eastern Canada. After 2.5 ka BP, summers became drier, albeit not as fire-conducive as during the early Holocene. Late-Holocene summers conducive to fire are explained by more frequent incursions of dry Cool Pacific or Cold Arctic air masses over eastern Canada. Received: 25 January 1999 / Accepted: 14 December 1999     

Abrupt changes (Heinrich events) in late Quaternary North Atlantic marine environments: a history and review of data and concepts

In the last several years evidence has mounted that a series of abrupt changes in sediment delivery and palaeoceanography effected the North Atlantic; they are recorded in a variety of proxy records but most dramatically in changes of grain-size and mineralogy associated with postulated iceberg rafting events, specifically Heinrich (H) events. This review paper examines the evidence for such evidence prior to the development of the ‘Heinrich event’ concept (1988–1992), and then examines the explosion of data and correlations that stemmed from the acceptance and use of this paradigm. Specific attention is focused on ideas pertaining to the cause(s) of glaciological mechanisms, sediment delivery, and sediment source, and major gaps in our understanding of the underlying glaciological, glacial geological, and glacial marine processes are stressed. Abrupt changes across boundaries associated with H-2 in the Labrador Sea are illustrated from core HU87033-009LCF. The case is made that correlations between records need to be more rigorous, especially within the range of radiocarbon dating, but it appears that abrupt changes in the delivery of iceberg rafted debris, which characterize these intervals, are multisourced. It is unclear how global ‘climate’ can simultaneously influence the abrupt behaviour of ice margins in different parts of the world—for marine-based margins, changes in relative sea-level are one possibility. A qualitative model is presented for triggering H events, which includes global changes in mass balance, changes in relative sea-level at ice margins due to glacial isostasy, and changes in the basal thermal regime of tidewater ice-streams. © 1998 John Wiley & Sons, Ltd.     

Analogue study of particle segregation in pyroclastic density currents, with implications for the emplacement mechanisms of large ignimbrites

Abstract Analogue flume experiments were conducted to investigate the transport and sedimentation behaviour of turbulent pyroclastic density currents. The experimental currents were scaled approximately to the natural environment in three ways: (1) they were fully turbulent; (2) they had a very wide range of particle sizes and associated Rouse numbers (the ratio of particle settling velocity to effective turbulent eddy velocity in the current); and (3) they contained particles of two different densities. Two sets of surge‐type experiments were conducted in a 5 m long, water‐filled lock‐exchange flume at five different volumetric particle concentrations from 0·6% to 23%. In one set (one‐component experiments), the currents contained just dense particles; in the other set (two‐component experiments), they contained both light and dense particles in equal volume proportions. In both sets of experiments, the population of each component had a log‐normal size distribution. In the two‐component experiments, the size range of the light particle population was selected in order to be in hydrodynamic equivalence with that of the dense particles. Dense particles were normally graded, both vertically and downstream, in the deposits from both sets of experiments. The mass loading (normalized to the initial mass of the suspension) and grain size of the dense component in the deposits decreased with distance from the reservoir and were insensitive to initial total particle concentration in the currents. On the other hand, in the two‐component experiments, the light particles were extremely sensitive to concentration. They were deposited in hydrodynamic equivalence with the dense particles from dilute currents, but were segregated efficiently at concentrations higher than a few per cent. With increasing particle concentration, the large, light particles were carried progressively further down the flume because of buoyancy effects. Deposits from the high‐concentration currents exhibited reverse vertical grading of the large, light particles. Efficient segregation of the light component was observed even if the bulk density of the current was less than that of the light particles. In both sets of experiments, marked inflexions in the rate of downstream decline in mass loading and maximum grain size of the dense component can be attributed to the presence of two different particle settling regimes in the flow: (1) particles with Rouse numbers >2·5, which did not respond to the turbulence and settled rapidly; and (2) particles with Rouse numbers <2·5, which followed the turbulent eddies and settled slowly. The results are applied to the transport and sedimentation dynamics of pyroclastic density currents that generate large, widespread ignimbrites. Field data fail to reveal significant departures from aerodynamic equivalence between pumice and lithic clasts in three such ignimbrites: the particulate loads of some large ignimbrites are transported principally in turbulent suspensions of low concentration. In some ignimbrites, the well‐developed inflexions in curves of maximum lithic (ML) size vs. distance can be attributed to the existence of distinct high and low Rouse number particle settling regimes that mark the transition from an overcharged state to one in which the residual particulate load is transported more effectively by turbulence.     

Discovery of Pyrrhotite-Chalcopyrite-Bearing Amphibole Megacrysts in Tongling Area, Anhui Province

Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts, belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts.amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well.