Urban heat island diagnosis using ASTER satellite images and ‘in situ’ air temperature

This study demonstrates that thermal satellite images combined with ‘in situ’ ground data can be used to examine models of heat island genesis and thus identify the main causes of urban heat islands (UHIs). The models, although proposed over 30 years ago, have not been thoroughly evaluated due to a combination of inadequate ground data and the low resolution of thermal satellite data. Also there has been limited understanding of the relevance of satellite-derived surface temperatures to local and regional scale air temperatures. A cloud-free ASTER thermal image of urban and rural areas of Hong Kong was obtained on a winter night with a well-developed heat island, accompanied by a 148 km vehicle traverse of air temperatures. Over the whole traverse a high R² of 0.80 was observed between surface and air temperatures, with the two datasets showing a similar amplitude and general trend, but with the surface exhibiting much higher local variability than air temperature. Gradients in both surface and air temperature could be related to differences in land cover, with little evidence of large scale advection, thus supporting the population/physical structure model of UHI causation, rather than the advection model. However, the much higher surface and air temperatures observed over the largest urban area, Kowloon, than over any smaller urban centre with similar physical structure in the New Territories, would seem more indicative of the advection model. The image and ground data suggest that Kowloon's urban canopy layer climate is mainly influenced by local city structure, but it is also modified by a strongly developed, regional scale urban boundary layer which has developed over the largest urban centre of Kowloon, and reinforces heating from both above and below.     

A coupled poroplastic damage model accounting for cracking effects on both hydraulic and mechanical properties of unsaturated media

Damage induced by microcracking affects not only the mechanical behaviour of geomaterials but also their hydraulic properties. Evaluating these impacts is important for many engineering applications, such as the safety assessment of radioactive waste disposal facilities. This paper presents a new constitutive model accounting simultaneously for the impact of damage on hydraulic and mechanical properties of unsaturated poroplastic geomaterials. The hydro‐mechanical coupling is formulated by means of the thermodynamic framework for partially saturated media, extended by taking into account isotropic damage and plasticity. State and complementary laws are governed by the so‐called plastic effective stress and equivalent pore pressure. Assuming a bimodal pore size distribution for cracked porous media, the hydraulic part (water retention curve and hydraulic conductivity) is modelled using phenomenological functions of damage variable. The participation of damage on both mechanical and hydraulic part enables this model to describe bilateral couplings between them. This coupled model is then validated against a number of experimental data obtained from Callovo‐Oxfordian argillite, which is the possible host rock for a radioactive waste disposal in France. Parametric studies are also carried out to check the consistency and to better demonstrate the bilateral couplings in the model. Copyright © 2015 John Wiley & Sons, Ltd.     

Keck adaptive optics images of Jupiter’s north polar cap and Northern Red Oval

We present observations at near-infrared wavelengths (1-5 μm) of Jupiter’s north polar region and Northern Red Oval (NN-LRS-1). The observations were taken with the near-infrared camera NIRC2 coupled to the adaptive optics system on the 10-m W.M. Keck Telescope on UT 21 August 2010. At 5-μm Jupiter’s disk reveals considerable structure, including small bright rings which appear to surround all small vortices. It is striking, though, that no such ring is seen around the Northern Red Oval. In de Pater et al. [2010a. Icarus 210, 742-762], we showed that such rings also exist around all small vortices in Jupiter’s southern hemisphere, and are absent around the Great Red Spot and Red Oval BA. We show here that the vertical structure and extent of the Northern Red Oval is very similar to that of Jupiter’s Red Oval BA. These new observations of the Northern Red Oval, therefore, support the idea of a dichotomy between small and large anticyclones, in which ovals larger than about two Rossby deformation radii do not have 5-μm bright rings. In de Pater et al. [2010a. Icarus 210, 742-762], we explained this difference in terms of the secondary circulations within the vortices. We further compare the brightness distribution of our new 5-μm images with previously published radio observations of Jupiter, highlighting the depletion of NH₃ gas over areas that are bright at 5 μm.     

Head on collision of dust ion acoustic solitary waves in magnetized quantum dusty plasmas

The Head on collision of dust ion acoustic solitary waves (DIASWs) in a magnetized quantum dusty plasma is investigated. Two sides Korteweg-de Vries (KdV) equations are obtained, the analytical phase shifts and the trajectories after the head-on collision of two DIASWs in a three species quantum dusty plasma are derive by using the extended version of Poincaré-Lighthill-Kuo (PLK) method. It is observed that the phase shifts are significantly affected by the quantum parameters like quantum diffraction, the ion cyclotron frequency and the ratio of the densities of electrons to ions.     

Crack Initiation, Propagation and Coalescence in Rock-Like Material Containing Two Flaws: a Numerical Study Based on Bonded-Particle Model Approach

Cracking and coalescence behavior in a rectangular rock-like specimen containing two parallel (stepped and coplanar) pre-existing open flaws under uniaxial compression load has been numerically studied by a parallel bonded-particle model, which is a type of bonded-particle model. Crack initiation and propagation from two flaws replicate most of the phenomena observed in prior physical experiments, such as the type (tensile/shear) and the initiation stress of the first crack, as well as the coalescence pattern. Eight crack coalescence categories representing different crack types and trajectories are identified. New coalescence categories namely “New 1” and “New 2”, which are first observed in the present simulation, are incorporated into categories 3 and 4, and category 5 previously proposed by the MIT Rock Mechanics Research Group, respectively. The flaw inclination angle (β), the ligament length (L) (spacing between two flaws) and the bridging angle (α) (inclination of a line linking up the inner flaw tips, between two flaws) have different effects on the coalescence patterns, coalescence stresses (before, at or post the peak stress) as well as peak strength of specimens. Some insights on the coalescence processes, such as the initiation of cracks in the intact part of specimens at a distance away from the flaw tips, and coalescence due to the development and linkage of a number of steeply inclined to vertical macro-tensile cracks are revealed by the present numerical study.     

Statistical Aspects of Microheterogeneous Rock Fracture: Observations and Modeling

Rocks and other geomaterials are heterogeneous materials, with a well-recognized hierarchy of defects from micro-heterogeneities on the grain level to a large-scale network of cracks and layering structures. Their nature create a challenge for determining macroscopic properties, particularly for properties that are scale dependent, complicating both the property measurement and its appropriate application in modeling. This paper discusses the concept of a “representative volume”, which is commonly used in modeling microheterogeneous but statistically homogeneous material by an effective homogeneous continuum. The foundation of this concept is presented, along with its limitations in dealing with properties like strength and fracture toughness that exhibit a scale effect. This limitation is illustrated with a study of brittle fracture of a concrete where it is considered a model for statistically homogeneous rock. The study includes determining a scaling rule for the scale effect in fracture toughness, and shows that the fracture of brittle materials like rocks and concrete appears in the form of highly tortuous, stochastic paths. This reflects a complex interaction between a crack and pre-existing as well as newly formed micro-defects controlled by chance, and results in a large scatter of all fracture-related parameters. This behavior suggests a synthesis of fracture mechanics with probability and statistics, and so a brief exposition of statistical fracture mechanics (SFM) that addresses the statistical aspects of fracture is also presented. SFM is a formalism that combines fracture mechanics methods with probability theory and serves as the basis for an adequate modeling of brittle fracture.     

Persistent rings in and around Jupiter’s anticyclones – Observations and theory

We present observations and theoretical calculations to derive the vertical structure of and secondary circulation in jovian vortices, a necessary piece of information to ultimately explain the red color in the annular ring inside Jupiter’s Oval BA. The observations were taken with the near-infrared detector NIRC2 coupled to the adaptive optics system on the 10-m W.M. Keck telescope (UT 21 July 2006; UT 11 May 2008) and with the Hubble Space Telescope at visible wavelengths (UT 24 and 25 April 2006 using ACS; UT 9 and 10 May 2008 using WFPC2). The spatial resolution in the near-IR (∼0.1–0.15″ at 1–5 μm) is comparable to that obtained at UV–visible wavelengths (∼0.05–0.1″ at 250–890 nm). At 5 μm we are sensitive to Jupiter’s thermal emission, whereas at shorter wavelengths we view the planet in reflected sunlight. These datasets are complementary, as images at 0.25–1.8 μm provide information on the clouds/hazes in the troposphere–stratosphere, while the 5-μm emission maps yield information on deeper layers in the atmosphere, in regions without clouds. At the latter wavelength numerous tiny ovals can be discerned at latitudes between ∼45°S and 60°S, which show up as rings with diameters ?1000 km surrounding small ovals visible in HST data. Several white ovals at 41°S, as well as a new red oval that was discovered to the west of the GRS, also reveal 5-μm bright rings around their peripheries, which coincide with dark/blue rings at visible wavelengths. Typical brightness temperatures in these 5-μm bright rings are 225–250 K, indicative of regions that are cloud-free down to at least the ∼4 bar level, and perhaps down to 5–7 bar, i.e., well within the water cloud.Radiative transfer modeling of the 1–2 μm observations indicates that all ovals, i.e., including the Great Red Spot (GRS), Red Oval BA, and the white ovals at 41°S, are overall very similar in vertical structure. The main distinction between the ovals is caused by variations in the particle densities in the tropospheric–stratospheric hazes (2–650 mbar). These are 5–8 times higher above the red ovals than above the white ones at 41°S. The combination of the 5-μm rings and the vertical structure derived from near-IR data suggests anticyclones to extend vertically from (at least) the water cloud (∼5 bar) up to the tropopause (∼100–200 mbar), and in some cases into the stratosphere.Based upon our observations, we propose that air is rising along the center of a vortex, and descending around the outer periphery, producing the 5-μm bright rings. Observationally, we constrain the maximum radius of these rings to be less than twice the local Rossby deformation radius, L_R. If the radius of the visible oval (i.e., the clouds that make the oval visible) is >3000 km, our observations suggest that the descending part of the secondary circulation must be within these ovals. For the Red Oval BA, we postulate that the return flow is at the location of its red annulus, which has a radius of ∼3000 km.We develop a theory for the secondary circulation, where air is (baroclinically) rising along the center of a vortex in a subadiabatic atmosphere, and descending at a distance not exceeding ∼2× the local Rossby deformation radius. Using this model, we find a timescale for mixing throughout the vortex of order several months, which suggests that the chromophores that are responsible for the red color of Oval BA’s red annulus must be produced locally, at the location of the annulus. This production most likely results from the adiabatic heating in the descending part of the secondary circulation. Such higher-than-ambient temperature causes NH₃–ice to sublime, which will expose the condensation nuclei, such as the red chromophores.     

A multi-wavelength study of the 2009 impact on Jupiter: Comparison of high resolution images from Gemini,Keck and HST

Within several days of A. Wesley’s announcement that Jupiter was hit by an object on UT 19 July 2009, we observed the impact site with (1) the Hubble Space Telescope (HST) at UV through visible (225–924 nm) wavelengths, (2) the 10-m W.M. Keck II telescope in the near-infrared (1–5 μm), and (3) the 8-m Gemini-North telescope in the mid-infrared (7.7–18 μm). All observations reported here were obtained between 22 and 25 July 2009. Observations at visible and near-infrared wavelengths show that large (～0.75-μm radius) dark (imaginary index of refraction m_i ～ 0.01–0.1) particulates were deposited at atmospheric pressures between 10 and 200–300 mbar; analysis of HST-UV data reveals that in addition smaller-sized (～0.1 μm radius) material must have been deposited at the highest altitudes (～10 mbar). Differences in morphology between the UV and visible/near-IR images suggest three-dimensional variations in particle size and density across the impact site, which probably were induced during the explosion and associated events. At mid-infrared wavelengths the brightness temperature increased due to both an enhancement in the stratospheric NH₃ gas abundance and the physical temperature of the atmosphere. This high brightness temperature coincides with the center part of the impact site as seen with HST. This observation, combined with (published) numerical simulations of the Shoemaker-Levy 9 impacts on Jupiter and the Tunguska airburst on Earth, suggests that the downward jet from the terminal explosion probably penetrated down to the ～700-mbar level.     

Simulating the effects of induced anisotropy on liquefaction potential using a new constitutive model

The effects of induced anisotropy on the undrained behaviour of very loose and saturated sands have been a subject of intensive investigation, both experimentally and theoretically, by several authors in the past few years. This paper proposes an original constitutive model well‐adapted to simulate the behaviour of sands subject to complex stress histories, in particular, the preloading cycle along the classical drained stress path in compression. The developed model belongs to the family of critical state models. Its construction is based on a few theoretical concepts taken from the theory of ‘Bounding Surface Plasticity’ developed among others by Y. Dafalias and Popov (1975), the ‘Clay And Sand Model’ (CASM) of H. Yu (2006), the CJS model (B. Cambou and K. Jafari (1988)) and the hyperelastic isotropic model of P. Lade (1987). To accurately simulate volume changes, which represent a key element in soil behaviour, a state‐dependent dilatancy rule is proposed, which can account for the influences of stress and void ratio. The current void ratio depends implicitly on the irreversible strains already accumulated hence the strain history. A kinematic hardening is combined with an isotropic hardening, involving rotation and distortion of the bounding surface, in order to capture correctly the experimental observations. Comparisons of experimental results to numerical simulations show that the model is able to simulate with a good precision the major trends of undrained responses of loose and presheared sands. It predicts correctly rapid static liquefaction at small or null drained preloading, as well as the progressive transition to a completely stable behaviour typical of dense sands, while the sample is loose in reality. At intermediate to large amplitudes of preloadings, the model also predicts correctly the temporary stage of instability when the deviatoric stress decreases slightly before rising up again. Copyright © 2013 John Wiley & Sons, Ltd.     

Enantioselectivity of polychlorinated biphenyl atropisomers in sediment and biota from the Turtle/Brunswick River estuary, Georgia, USA

To investigate the potential for enantioselective transformation and accumulation, the enantiomer distributions of seven polychlorinated biphenyl (PCB) atropisomers were measured in the sediment and biota from a sub-tropical estuary heavily contaminated with Aroclor 1268, a technical mixture of highly chlorinated PCB congeners. Enantiomer fractions (EFs) of PCBs 91, 95, 136, 149, 174, 176, and 183 in marsh sediment, invertebrate, forage and predatory fish species, and bottlenose dolphins were determined. Non-racemic EFs greater than 0.75 were found in sediments for PCBs 136 and 174, likely the result of microbial dechlorination. Although enantiomer fractions in grass shrimp (Palaemonetes spp.) mirrored those of sediment, fish species had EFs that differed significantly from sediment or grass shrimp. Similarly, bottlenose dolphins were also found to contain non-racemic quantities of PCBs 91, 136, 174, 176, and 183. Non-racemic EFs in these biota were likely a result of both uptake of non-racemic proportions of PCBs from the diet and enantioselective biotransformation.