Dysaerobic conditions during Heinrich events 4 and 5: Evidence from phosphorus distribution in a North Atlantic deep-sea core

Reactive phosphorus undergoes diagenetic transformation once transferred into marine sediments. The degree of regeneration and redistribution of phosphorus depends on early diagenetic and environmental conditions, which may be linked to larger scale phenomena, such as bottom water circulation, water column ventilation, and organic carbon flux. Phosphorus phases of the <50-μm-sized fraction of deep-sea sediments from core SU 90-09 (North Atlantic, 43°31′N, 30°24′W, 3375 m below sea level) have been analyzed using a sequential extraction technique (SEDEX method) to reconstruct phosphorus geochemistry during Heinrich events 4 and 5. Comparison with Holocene samples from the same site indicates that postdeposition diagenetic transformation has not affected phosphorus distribution in the deep part of the sediments. Total and reactive phosphorus average 0.40 ± 0.04 mg/g and 0.30 ± 0.05 mg/g, respectively, and are comparable to values found in analog deep-sea environments in the North Atlantic. Detrital phosphorus, the phase linked to igneous- and metamorphic-derived material, sharply increases during Heinrich events and covaries with the ice-rafted debris record, whereas authigenic and Fe-bound phosphorus phases, both influenced by redox conditions, decrease or even disappear. These findings suggest that during the deposition of Heinrich layers (HLs), environmental parameters hampered the precipitation of these phases. Large freshwater discharges in relation to iceberg surges may have provoked a temporary stratification of the water column. Accordingly, dysaerobic conditions in the sediments may have fostered the loss of dissolved phosphorus from the sediments to the water column, in a direct and rapid response to the changed conditions. Decreasing trends in organic matter elemental ratios (total organic carbon/organic phosphorus) and Rock-Eval oxygen index values, along with the presence of partly authigenic dolomite and ankerite within HLs, also support this assumption.     

Geographical distribution and simultaneity of occurrence of F-lacunae

Observation of ionograms recorded at about fifteen high latitude stations shows there the same morphological types of F-lacunae (disappearance of echoes from the F1, the F2 or the complete F-layer) as in Terre Adélie. The phenomenon is aestival and diurnal everywhere, but the shape of occurrence histograms varies from one station to another. A statistical study shows that the occurrence in the various stations (of the same hemisphere) is correlated, all the more as the considered stations have similar invariant latitudes. Occurrence is correlated with the daily index of magnetic activity A_p, a correlation which is maximum at about 75° invariant latitude and decreases on both sides. A study of particular events shows a clear relation between lacunae occurrence and the position and moving of the cleft (as deduced empirically from the K_p index), results which can be interpreted in terms of a previously described model.     

Simulation of Turbulent Flow in An Urban Forested Park Damaged by a Windstorm

The damage caused by windstorms to forest ecosystems is often very heterogeneous. In order to improve the stability of forested landscapes, it is of great importance to identify the factors responsible for this spatial variability. The structure of the landscape itself may play a role, through possible influences of canopy heterogeneities on the development of turbulence. For the purpose of investigating the role of landscape fragmentation on turbulence development, we used a numerical flow model with a k–ε turbulence scheme model, previously validated in simple cases with well-defined surface changes (roughness change and forest edge flow). A series of two- and three-dimensional simulations were performed over a heterogeneous urban forested park in Europe, which was severely damaged in various places by the Lothar windstorm in December 1999. The model shows the development of a region of strong turbulence, resulting from the generation of large wind shear at the top of the canopy. A sensitivity study shows how the location, extension and intensity of the region depend on canopy characteristics such as the leaf density, the nature of the edge or the presence of gaps and clearings. Simulations performed in conditions representative of the windstorm show that the location of the damaged areas corresponds very closely to the regions where the turbulent kinetic energy was above a certain threshold.     

F-lacuna events in Terre-Adelie and their relationship with the state of the ionosphere

F-lacuna event is a typical phenomenon of the high latitude ionosphere occurring during summer days. It consists in a disappearance of echoes from the F-layer on ionograms and a simultaneous extra absorption of about 0.1 to 0.4 dB on 30 MHz cosmic waves. This paper, based on data from the Dumont d'Urville station, describes the properties of this phenomenon: correlation with magnetic activity, convection electric field, interplanetary magnetic field, absorption in the lower ionosphere and electron density in the F-layer. A tentative model of interpretation in terms of large scale electron density irregularities in the F-layer is suggested.     

New Olivine Reference Material for In Situ Microanalysis

A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements.     

Orbital cyclicity in sedimentary sequence and climatic indications of C-O isotopes from Lower Cretaceous in Qingxi Sag,Jiuquan Basin,NW China

Sedimentary deposits of the Lower Cretaceous Xiagou Formation form the most significant potential hydrocarbon reservoirs in the Qingxi Sag, Jiuquan Basin(NW China). Zircon U-Pb ages of the dated basalts at the top of the Xiagou Formation give an isochron age of 115.6 Ma, and the sedimentation interval of the Xiagou Formation was speculated to range from about 125/124 Ma to 115 Ma based on paleontological research and stratigraphic correlation analysis. Here we use GR logging data as a palaeoenvironmental and palaeoclimatic proxy to conduct a detailed cyclostratigraphic study of five selected wells. Power spectra, evolutionary fast Fourier transformation and wavelet analysis all reveal significant sedimentary cycles in the Xiagou Formation. The ratios of cycle wavelengths in these stratigraphic units are 33.82 m : 7.91 m : 3.06 m : 1.79 m, which is similar to the ratio of orbital targets of 20 : 5 : 2 : 1. The ratio of 20 : 5 : 2 : 1 is interpreted as Milankovitch cycles of 405 kyr long eccentricity,100 kyr short eccentricity, 37 kyr obliquity, and 22 kyr precession cycles respectively. A high-resolution astronomical time scale is constructed by tuning the stratigraphy into target curves of orbital cycles respectively. Based on the astronomical time scale, the absolute ages of 55 samples were estimated,which are used for subsequent stable carbon and oxygen isotope stratigraphy analysis. The analysis results of the five studied wells in the Qingxi Sag indicate:(1) a negative trend of δ~(13)C values upwards in the Xiagou Formation, and(2) negative δ~(18)O values with a positive trend upwards. Both relatively heavy values and pronounced covariances of δ~(13)C values and δ~(18)O values indicate an arid-evaporationcontrolled climate during the sedimentary period of the Lower Cretaceous Xiagou Formation, Qingxi Sag, Jiuquan Basin. Moreover, positive covariances of SQK_1g_(2+3) indicate extremely high temperature, and negative covariances of SQK_1g_1 indicate a relatively low temperature.     

Stereotomography assisted by migration of attributes

Depth velocity model building remains a difficult step within the seismic depth imaging sequence. Stereotomography provides an efficient solution to this problem but was limited until now to a picking of seismic data in the prestack time un-migrated domain. We propose here a method for stereotomographic data picking in the depth migrated domain. Picking in the depth migrated domain exhibits the advantage of a better signal-to-noise ratio and of a more regular distribution of picked events in the model, leading to a better constrained tomographic inverse problem. Moreover, any improvement on the velocity model will improve the migrated results, again leading to improved picking. Our strategy for obtaining a stereotomographic dataset from a prestack depth migration is based on migration of attributes (and not on a kinematic demigration approach!). For any locally coherent event in the migrated image, migration of attributes allows one to compute ray parameter attributes corresponding to the specular reflection angle and dip. For application to stereotomography, the necessary attributes are the source/receiver locations, the traveltime and the data slopes. For the data slope, when the migration velocity model is erroneous, some additional corrections have to be applied to the result of migration of the attributes. Applying these corrections, our picking method is theoretically valid whatever the quality of the migration velocity model. We first present the theoretical aspects of the method and then validate it on 2D synthetic and real seismic reflection data sets.     

A Sr,Nd, Hf,and Pb isotope perspective on the genesis and long-term evolution of alkaline magmas from Erebus volcano,Antarctica

We report new Nd, Hf, Sr, and high-precision Pb isotopic data for 44 lava and tephra samples from Erebus volcano. The samples cover the entire compositional range from basanite to phonolite and trachyte, and represent all three phases of the volcanic evolution from 1.3 Ma to the present. Isotopic analyses of 7 samples from Mt. Morning and the Dry Valley Drilling Project (DVDP) are given for comparison. The Erebus volcano samples have radiogenic ²⁰⁶Pb/²⁰⁴Pb, unradiogenic ⁸⁷Sr/⁸⁶Sr, and intermediate ¹⁴³Nd/¹⁴⁴Nd and ¹⁷⁶Hf/¹⁷⁷Hf, and lie along a mixing trajectory between the two end-member mantle components DMM and HIMU. The Erebus time series data show a marked distinction between the early-phase basanites and phonotephrites, whose Nd, Hf, Sr, and Pb isotope compositions are variable (particularly Pb), and the current ‘phase-three’ evolved phonolitic lavas and bombs, whose Nd, Hf, Sr, and Pb isotope compositions are essentially invariant. Magma mixing is inferred to play a fundamental role in establishing the isotopic and compositional uniformity in the evolved phase-three phonolites. In-situ analyses of Pb isotopes in melt inclusions hosted in an anorthoclase crystal from a 1984 Erebus phonolite bomb and in an olivine from a DVDP basanite are uniform and identical to the host lavas within analytical uncertainties. We suggest that, in both cases, the magma was well mixed at the time melt inclusions were incorporated into the different mineral phases.