The Use Of Environmental Isotopes And Chloride As Natural Tracers To Investigate The Effects Of Depressurisation Of A Coastal Aquifer For Lignite Mining,India

In order to mine lignite from the Neyveli opencast mines, about 200 km south of Madras, India, the Neyveli aquifer has been undergoing depressurisation continuously for almost three decades. To gain insight into the aquifer hydrodynamics, environmental-isotope and chloride measurements on selected groundwater samples were initiated two decades ago, and detailed studies were undertaken during 1985–91. This article demonstrates the effect of large-scale groundwater withdrawals on the hydrologic regime and the effects on environmental chloride and isotopic distributions. A feature common to both the radiocarbon and chloride data of 1991 is their marked variation in a small area between the recharge zone and the mine area where pumping is concentrated. Furthermore, an excellent correlation exists between the temporal increase in the apparent radiocarbon ages of groundwater sampled in 1991 and 1985 and the corresponding lowering of potentiometric levels. Isochlors based on 1991 and 1985 data also indicate a changed hydrologic regime. In certain areas, heavy withdrawals have resulted in increased groundwater salinity.     

Rn solution by the circulating fluids in a “hot dry rock” geothermal reservoir

The mechanism of²²²Rn release into fracture fluids by direct alpha-recoil, lattice and grain boundary/micro-crack diffusion is discussed. Experimental measurements of²²²Rn release into surrounding air and water phases have been made for crystalline rock specimens with well defined surface areas. The²²²Rn flux from an infinite plane surface and hence the effective diffusion length of²²²Rn in the rock matrix has been estimated.The²²²Rn flux from plane crystalline rock surfaces has been used in conjunction with a simple hydrological model of the reservoir to calculate the²²²Rn content of the return fluids of a geothermal doublet circulation system. For given production rate and piezometric difference between the injection and production wells, the²²²Rn content of the return fluid is dependent upon the distribution of flow path lengths and fracture apertures in the reservoir. Matching of the calculated and experimental²²²Rn contents of the return fluids has been used to select appropriate parameters for the reservoir model and hence to estimate the extent of the heat-transfer surface. The model estimates the fracture width of the flow paths, total swept surface area and fracture volume within the reservoir.     

Geodynamic evolution and crustal growth of the central Indian Shield: Evidence from geochemistry of gneisses and granitoids

The rare earth element patterns of the gneisses of Bastar and Bundelkhand are marked by LREE enrichment and HREE depletion with or without Eu anomaly. The spidergram patterns for the gneisses are characterized by marked enrichment in LILE with negative anomalies for Ba, P and Ti. The geochemical characteristics exhibited by the gneisses are generally interpreted as melts generated by partial melting of a subducting slab. The style of subduction was flat subduction, which was most common in the Archean. The rare earth patterns and the multi-element diagrams with marked enrichment in LILE and negative anomalies for Ba, P and Ti of the granitoids of both the cratons indicate interaction between slab derived melts and the mantle wedge. The subduction angle was high in the Proterozoic. Considering the age of emplacement of the gneisses and granitoids that differs by ∼ 1 Ga, it can be assumed that these are linked to two independent subduction events: one during Archaean (flat subduction) that generated the precursor melts for the gneisses and the other during the Proterozoic (high angle subduction) that produced the melts for the granitoids. The high values of Mg #, Ni, Cr, Sr and low values of SiO₂ in the granitoids of Bastar and Bundelkhand cratons compared to the gneisses of both the cratons indicate melt-mantle interaction in the generation of the granitoids. The low values of Mg#, Ni, Cr, Sr and high values of SiO₂ in the gneisses in turn overrules such melt-mantle interaction.     

Recharge processes: piston flow vs preferential flow in semi-arid aquifers of India

Study of groundwater recharge processes is vital for quantification of total natural recharge to the aquifers. One of the recharge processes demonstrated earlier by tracer experiments in the unsaturated zone is that of piston flow movement of soil moisture. Based on this recharge process, environmental tritium, chloride and injected tritium studies have been carried out extensively in various geological environs of India. The purpose of this paper is to evaluate the validity of the piston flow concept in different geological environs viz. consolidated fractured and weathered granites, semi-consolidated sandstones and unconsolidated alluvial tracts, and quantify the contribution from this process as well as that from the preferential flow mechanism using different tracers. Analysis of tracer data demonstrates that the preferential flow recharge process contributes very significantly (an average of 75% of total recharge) in the case of fractured granites and is important (an average of 33% of total recharge) for semi-consolidated sandstones, whereas the preferential flow recharge component is minimal in unconsolidated alluvial tracts (piston flow model is applicable). These findings necessitate re-evaluation of the total natural recharge potential of the above mentioned geological environs in view of the significant preferential flow recharge that is evidenced and estimated. Electronic Publication     

Evaluation of gridded precipitation data in the Hindu Kush–Karakoram–Himalaya mountainous area

The accurate measurement of precipitation is crucial for hydrological studies. This is especially true for the Hindu Kush–Karakoram–Himalaya (HKKH) mountain region, which is characterized by high spatiotemporal precipitation variability. The paucity of raingauges makes it difficult to measure precipitation in this region precisely. We conducted evaluation of TMPA 3B42V7 and APHRO 1101 in the HKKH area on a daily basis at a spatial resolution of 0.25°?×?0.25°, using 27 raingauges. Statistically, the largest error in the gridded data arose mainly from elevation, followed by volumetric error and Nash–Sutcliffe efficiency. Overall, the TMPA data have a poor correlation with ground observations in the HKKH area, especially for higher altitudes. The western areas are relatively more underestimated and the Karakoram shows higher frequency of bias in the TMPA retrievals. This method could help improve the satellite precipitation estimation algorithm as it considers local physiography and climatic factors.     

pH variability off Goa (eastern Arabian Sea) and the response of sea urchin to ocean acidification scenarios

The increasing atmospheric CO₂ concentration in the last few decades has resulted in a decrease in oceanic pH. In this study, we assessed the natural variability of pH in coastal waters off Goa, eastern Arabian Sea. pH_T showed large variability (7.6–8.1) with low pH conditions during south-west monsoon (SWM), and the variability is found to be associated with upwelling rather than freshwater runoff. Considering that marine biota inhabiting dynamic coastal waters off Goa are exposed to such wide range of natural fluctuations of pH, an acidification experiment was carried out. We studied the impact of low pH on the local population of sea urchin Stomopneustes variolaris (Lamarck, 1816). Sea urchins were exposed for 210 days to three treatments of pH_T: 7.96, 7.76 and 7.46. Our results showed that S. variolaris at pH_T 7.96 and 7.76 were not affected, whereas the ones at pH_T 7.46 showed adverse effects after 120 days and 50% mortality by 210 days. However, even after exposure to low pH for 210 days, 50% organisms survived. Under low pH conditions (pH_T 7.46), the elemental composition of sea urchin spines exhibited deposition of excess Sr²⁺ as compared to Mg²⁺ ions. We conclude that although the sea urchins would be affected in future high CO₂ waters, at present they are not at risk even during the south-west monsoon when low pH waters reside on the shelf.     

Comparisons of images derived from independent Zeeman Doppler imaging codes

We compare surface brightness and magnetic field surface maps for the K0 dwarf AB Doradus, obtained using two independently developed Zeeman Doppler imaging codes. We find that even the fine structure in the two sets of images shows excellent agreement. Magnetic field maps appear to be less sensitive to line-modelling effects than brightness maps. We argue that these results point to the consistency and reliability of Doppler imaging techniques even when using poorly sampled data sets, provided that the spectra used are of sufficiently high signal-to-noise ratio.     

Stable isotope dynamics of groundwater interactions with Ganges river

Groundwater depletion has been an emerging crisis in recent years, especially in highly urbanized areas as a result of unregulated exploitation, thus leaving behind an insufficient volume of usable freshwater. Presently Ganges river basin, the sixth largest prolific fluvial system and sustaining a huge population in South Asia, is witnessed to face (i) aquifer vulnerability through surface waterborne pollutant and (ii) groundwater stress due to summer drying of river as a result of indiscriminate groundwater abstraction. The present study focuses on a detailed sub-hourly to seasonally varying interaction study and flux quantification between river Ganges and groundwater in the Indian subcontinent which is one of the first documentations done on a drying perennial river system that feeds an enormous population. Contributing parameters to the total discharge of a river at its middle course on both temporal and spatial scale is estimated through three-component hydrograph separation and end-member mixing analysis using high-resolution water isotope (δ¹⁸O and δ²H) and electrical conductivity data. Results from this model report groundwater discharge in river to be the highest in pre-monsoon, that is, 30%, whereas, during post-monsoon the contribution lowers to 25%; on the contrary, during peak monsoon, the flow direction reverses thus recharging the groundwater which is also justified using annual piezometric hydrographs of both river water and groundwater. River water-groundwater interaction also shows quantitative variability depending on river morphometry. The current study also provides insight on aquifer vulnerability as a result of pollutant mixing through interaction and plausible attempts towards groundwater management. The present study is one of the first in South Asian countries that provides temporally and spatially variable detailed quantification of baseflow and estimates contributing parameters to the river for a drying mega fluvial system.