Radon modelling and the heat transfer surface area of the British hot dry rock geothermal reservoir

A simple thermal model is developed to evaluate the heat exchange surface area of a hot dry rock geothermal reservoir. This model, in conjunction with the Rn model of Andrews and coworkers, is applied to RH12/RH15 system of the British HDR reservoir. Results suggest that although the estimated Rn transfer surface area represents the actual swept surface area, it is between 25 and 45 times larger than the heat transfer surface area. The difference is explained as due to clustering of several fractures within a range of thermal interaction, over the duration of the circulation. It is also shown that the decline in the measured temperatures of circulation fluids since 1985 to the present is consistent with the heat exchange surface area going through a maximum in 1987.     

Integrated geo-microbial and trace metal anomalies for detection of hydrocarbon microseepage in Ahmedabad block of Cambay basin,India

The aim of the present work is to define the geo-microbial signatures along with trace metals, and to investigate whether the geo-microbial anomalies have correlation with trace metal anomalies in Ahmedabad block of Cambay basin. The surface geochemical techniques are based on seepage of light hydrocarbon gases from the oil and gas pools to the shallow surface and can bring up near-surface oxidation reduction zones that favor the development of a diverse array of chemical and mineralogical changes. The paper reports the role of hydrocarbon microseepage in surface alterations of trace metal concentrations and hydrocarbon oxidizing bacteria and its interrelationship. For the purpose a total of 90 soil samples are collected in grid pattern of 2 x 2 km interval. The paper reports the chemical alterations associated with trace metals in soils that are related to hydrocarbon microseepages above some of the major oil and gas fields of this petroliferous region. The concentrations of V (0 to149 ppm), Cr (2 to 192 ppm), Cu (4 to 171 ppm), Se (98 to 440 ppm), Zn (56 to 1215 ppm) are obtained. It is observed that the concentrations of trace elements are tremendously increased when they are compared with their normal concentrations in soils. In this study the hydrocarbon oxidizing bacterial counts ranged between 1.0 x 10³ and 1.59 x 10⁶ cfu/g of soil sample respectively. The attempt has made for the first time, which revealed good correlation as both these anomalies are found as apical in relation. Integrated studies between trace elements and hydrocarbon oxidizing bacterial anomalies showed positive correlation with existing oil and gas wells in the study area.     

Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.     

Petrophysical parameters and modelling of the Eocene reservoirs in the Qadirpur area,Central Indus Basin,Pakistan: implications from well log analysis

The Eocene rock units of the Qadirpur field, Central Indus Basin (Pakistan), are investigated petrophysically for their detailed reservoir characterization. The different petrophysical parameters determined include the following: true resistivity, shale volume, total porosity, effective porosity, density and neutron porosity, water and hydrocarbon saturation, bulk volume of water, lithology, gas effect, P-wave velocity, movable hydrocarbon index and irreducible water saturation and integrated with different cross-plots. The Eocene reservoirs are excellent with high effective porosity (2–32 %) and hydrocarbon saturation (10–93 %). Among these, the Sui Upper Limestone is an overall a poor reservoir; however, it has some hydrocarbon-rich intervals with high effective porosity and better net pay. All the net pay zones identified show low and variable shale volume (5–30 %). The secondary porosity has added to the total and effective porosities in these reservoirs. The main contributors to the porosity are the chalky, intercrystalline and vuggy/fracture types. The thickness of the reservoirs zones ranges from 4.5 to 62 m. These reservoirs are gas-producing carbonates with almost irreducible water saturation (0.002–0.01) and are likely to produce water-free hydrocarbons. The lower values of moveable hydrocarbon index (0.07–0.9) show that the hydrocarbons are moveable spontaneously to the well bore. The proposed correlation model shows that the reservoirs have an inclined geometry and are a part of an anticlinal trap.     

Lunar concrete: Prospects and challenges

The possibility of using concrete as a construction material at the Moon surface is considered. Dissimilarities between the Earth and the Moon and their possible effects on concrete are also emphasized. Availability of constituent materials for concrete at lunar surface is addressed. An emphasis is given to two types of materials, namely, hydraulic concrete and sulfur concrete. Hydraulic concrete necessitates the use of water and sulfur concrete makes use of molten sulfur in lieu of cement and water.     

Geochemistry of Archaean amphibolites from Karnataka State,Peninsular India

Ortho- and para-amphibolites occur throughout the Dharwar schists, gneisses and ultramafics in Karnataka State, India. From the chemical data alone, these ortho- and para-amphibolites cannot be very clearly differentiated. While the ortho-amphibolites follow the Karroo trend, the para-amphibolites appear to have been evolved from the metamorphism of low-Si and -K graywackes. The amphibolitic xenoliths occurring in Peninsular gneisses follow both the igneous and graywacke field, indicating that probably both para and ortho types constitute these enclaves. Their trace element concentrations, like those of Ni, Co and Cr, are not related to the Mg and Fe contents of the amphibolites. Probably these amphibolites have been derived from basic rocks, which were predominant over the Archaean crust, either directly or after having gone through a sedimentary cycle. The higher concentration of Ni, Co, Cr and other elements, such as Mg, in these amphibolites, as compared with younger oceanic basalts, thus indicates the higher concentration of these elements in Archaean basalts and the proto-mantle.