Downstream changes in antimony and arsenic speciation in sediments at a mesothermal gold deposit in British Columbia,Canada

This study investigates Sb speciation in sediments along the drainage of the Upper Peter adit at the Bralorne Au mine in southern British Columbia, Canada, and compares the behavior of Sb with that of As. The Upper Peter mineralization consists of native Au in quartz-carbonate veins with 1 wt.% sulfides dominated by pyrite and arsenopyrite although stibnite, the primary Sb-bearing sulfide mineral, can be locally significant. Dissolved Sb concentrations can reach up to 349 μg L⁻¹ in the mine pool. Sediments were collected for detailed geochemical and mineralogical characterization at locations along the 350-m flow path, which includes a 100-m shallow channel within the adit, a sediment settling pond about 45 m beyond the adit portal and an open wetland another 120 m farther downstream. From the mine pool to the wetland outlet, dissolved Sb in the drainage drops from 199 μg L⁻¹ to below the detection limit due to the combined effect of dilution and removal from solution. Speciation analyses using X-ray absorption near-edge structure (XANES) spectroscopy indicate that Sb(III)–S accounts for around 70% of total Sb in the sediments in the main pool at the far end of the adit. At a short distance (24 m) downstream of the main adit pool, however, Sb(III)–O and Sb(V)–O species represent ?50% of total Sb in the bulk sediments, indicating significant oxidation of the primary sulfides inside the adit. Although Sb appears largely oxidized in the bulk samples collected near the portal, Sb(III)–S species are nevertheless present in the <53-μm fraction, suggesting a higher oxidation rate for stibnite in the coarser grains, possibly due to galvanic interaction with pyrite. Secondary Sb species released from the sulfide oxidation are most likely sorbed/co-precipitated with Fe-, Mn-, and Al-oxyhydroxides along the flow channel in the adit and in the sediment settling pond, with the Fe phase being the dominant sink for Sb.     

Gravel seeding – A suitable technique for restoring the seabed following marine aggregate dredging?

Restoration of offshore marine habitats is a relatively new concept, with attempts in the European Union being largely instigated by requirements of various strategic directives. In this experiment, we investigate the practicality and effectiveness of gravel seeding, using a commercial aggregate dredging vessel, in order to recreate a gravel habitat. The experimental design consisted of a Treatment and Control site, both within an area of historic dredging characterised by an overburden of sand, and a gravel dominated Reference site. All sites were surveyed, using a combination of acoustic, camera and grab techniques, 2 months before, and then at 0, 12 and 22 months after the deposition of 4444 m³ of gravel dominated sediments within the Treatment site. Although financial and practical constraints limited replication of the Treatment to one area, and so precluded strong statistical conclusions, our results suggested that the technique was both practically feasible, and successful in terms of returning the physical and biological attributes at the Treatment site to a state more representative of gravelly substrata in the wider, un-impacted environment.     

Understanding the cost of establishing marine protected areas

While the recurrent cost of managing marine protected areas (MPAs) has been documented and estimated, there has been virtually no attempt to quantify the cost of establishing MPAs in the first place. This lack of attention is likely the result of the complexity of the process, involving often uncoordinated efforts of a multitude of governmental and non-governmental entities over a protracted period of time with no clear start and end-point. Using information gathered from a representative subset of MPAs worldwide, this paper presents the first attempt to identify and describe the various components, and explore potential predictors of the total funds spent in the course of establishment. The thirteen MPAs studied vary in size (from <1 to >360,000 km²), location (including near- and offshore in both developed and developing countries), objectives and degree of protection. Variation in MPA start-up costs is shown to be most significantly related to both MPA size and the duration of the establishment phase. Development of a method to estimate the potential cost of establishing proposed MPAs should play a crucial role in the conservation planning process.     

Differences in physiological response to increased seawater temperature in nearshore and offshore corals in northern Vietnam

Effects of elevated seawater temperature show high spatial heterogeneity and variation within and among coral species. The objective of this study was to investigate how two coral species, Porites lutea and Galaxea fascicularis, from two high latitude reefs differently exposed to chronic disturbance, respond to elevated seawater temperatures. Corals were collected from reefs nearshore (i.e. subjected to high sediment load, higher chlorophyll α concentrations, turbidity etc.) and offshore (i.e. less exposed). The corals were exposed in the lab to gradually increasing temperatures (25.5-33.5?°C) for 72?h after which they were allowed to recover to ambient temperature (25.5?°C) for 24?h. Production and respiration were measured after 24, 48, 72 and 96?h. The results show that P. lutea from nearshore reefs suffered an initial decrease in gross primary production/respiration (GP/R) ratio after 24?h, after only a moderate temperature increase (+2?°C, from 25.5 to 27.5?°C), while there was no difference in GP/R ratio between heat-exposed and controls the other days, indicating that the chronic disturbance in the nearshore reef had no effect on their thermotolerance. Furthermore, P. lutea from the offshore reef showed a decrease in GP/R ratio both after 24?h and 72?h (33.5?°C) of exposure. In comparison, G. fascicularis showed a decrease in GP/R ratio after 48?h, 72?h and 96?h of exposure for the nearshore corals. Also, after 72?h these corals had withdrawn their polyps. There were no differences between heat-treated and controls for the offshore G. fascicularis. This implies that the chronically disturbed G. fascicularis had lower thermotolerance when exposed to a temperature increase. This study, hence, shows that the response of corals to elevated seawater temperature varies with species and environmental background history.     

Starspots: The zebra effect

Recent observations of brightness variations on the Sun during the solar cycle have motivated us to re-examine the widely held view that cool, dark starspots, covering a significant fraction of the star, are the centers of magnetic activity on BY Dra stars. We propose that the magnetic regions are better described by a bright facular network, and that the dark areas which give rise to photometric rotational modulation are actually regions where the underlying quiet photosphere is seen. This interpretation is consistent with recent observations of late-type stars that show that bright areas covering much of the star have magnetic fields with strengths of several thousand gauss. It resolves several problems with the current model, including the size, location, and stability of the starspots required to match photometric and Doppler-imaging observations. It also has interesting observational implications for the correlation of photometric rotational modulation and long term brightness variations with other surface activity, and for the positions of magnetically active stars in the H-R diagram.Hubble Fellow.     

The Kwakshua Watersheds Observatory,central coast of British Columbia,Canada

The Kwakshua Watersheds Observatory (KWO) is an integrative watersheds observatory on the coastal margin of a rain-dominated bog-forest landscape in British Columbia (BC), Canada. Established in 2013, the goal of the KWO is to understand and model the flux of terrestrial materials from land to sea – the origins, pathways, processes and ecosystem consequences – in the context of long-term environmental change. The KWO consists of seven gauged watersheds and a network of observation sites spanning from land to sea and along drainage gradients within catchments. Time-series datasets include year-round measurements of weather, soil hydrology, streamflow, aquatic biogeochemistry, microbial ecology and nearshore oceanographic conditions. Sensor measurements are recorded every 5 min and water samples are collected approximately monthly. Additional observations are made during high-flow conditions. We used remote sensing to map watershed terrain, drainage networks, soils and terrestrial ecosystems. The watersheds range in size from 3.2 to 12.8 km², with varying catchment characteristics that influence hydrological and biogeochemical responses. Despite local variation, the overall study area is a global hotspot for yields of dissolved organic carbon, dissolved organic nitrogen and dissolved iron at the coastal margin. This observatory helps fill an important gap in the global network of observatories, in terms of spatial location (central coast of BC), climate (temperate oceanic), hydrology (very high runoff, pluvial regime), geology (igneous intrusive, glacially scoured), vegetation (bog rainforest) and soils (large stores of organic carbon).