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11.
Joseph B. Lambert Suzanne C. Johnson George O. Poinar James S. Frye 《Geoarchaeology》1993,8(2):141-155
The carbon-13 nuclear magnetic resonance spectra of fossil resins from New Zealand and Australia have been compared with those of modern and semifossilized materials. The great majority of the fossilized samples have strong spectral similarities to modern Agathis resins and to North American fossil resins, which have been attributed to Agathis. The Agathis-related spectra are different from those of modern Hymenaea and Araucaria. A small subgroup of Late Cretaceous resins from Australia and Papua New Guinea appears to derive from a different botanical source and shows strong resemblances to Claiborne amber from Arkansas. The spectral resonances of the exomethylene carbons degrade over time and on average provide an approximate measure of the geological age of Agathis-related fossil resins. © 1993 John Wiley & Sons, Inc. 相似文献
12.
Suzanne E. Hollins Scott F. Heron Peter V. Ridd 《Estuarine, Coastal and Shelf Science》2009,82(4):615-620
The typically anaerobic nature of mangrove sediments provides significant challenges to the mangrove trees and biota inhabiting them. The burrowing activities and flow of water through the numerous and complex animal burrows perforating the sediments of mangroves have a major influence on the biogeochemistry of the sediments and are important to the enhancement of nutrient and oxygen exchange. Two new methods are presented for monitoring the tidal flushing of Sesarma messa and Alpheus cf macklay burrows in a Rhizophora stylosa mangrove forest – by measuring oxygen content of burrow water and by determining the change in fluorescence of a dye tracer through tidal inundation. A case study using the first of these showed oxygen consumption rates at the burrow wall deep within the burrow were found to be between 210 and 460 μmol O2 m−2 h−1. The influx of oxygen during a flood tide was found to be significant and indicated that approximately 40% of the burrow water is flushed during a single tidal event. However, the high consumption rate of oxygen within the burrow resulted in the oxygen concentration remaining at or below one-third of the oxygen content of the flooding tidal water. A test application of the second method, using rhodamine dye as a tracer, indicated that the exchange of water between the burrow and the flooding tide was found to be in the order of 30% of the burrow volume. These new techniques provide a means to further study the nutrient exchange within these burrow systems and verify the initial findings that several tidal inundations are necessary to completely flush the burrows. 相似文献
13.
Annual export of 11 major and trace solutes for the Yukon River is found to be accurately determined based on summing 42 tributary contributions. These findings provide the first published estimates of tributary specific distribution of solutes within the Yukon River basin. First, we show that annual discharge of the Yukon River can be computed by summing calculated annual discharges from 42 tributaries. Annual discharge for the tributaries is calculated from the basin area and average annual precipitation over that area using a previously published regional regression equation. Based on tributary inputs, we estimate an average annual discharge for the Yukon River of 210 km3 year–1. This value is within 1% of the average measured annual discharge at the U.S. Geological Survey gaging station near the river terminus at Pilot Station, AK, for water years 2001 through 2005. Next, annual loads for 11 solutes are determined by combining annual discharge with point measurements of solute concentrations in tributary river water. Based on the sum of solutes in tributary water, we find that the Yukon River discharges approximately 33 million metric tons of dissolved solids each year at Pilot Station. Discharged solutes are dominated by cations calcium and magnesium (5.65 × 109 and 1.42 × 109 g year–1) and anions bicarbonate and sulphate (17.3 × 109 and 5.40 × 109 g year–1). These loads compare well with loads calculated independently at the three continuous gaging stations along the Yukon River. These findings show how annual solute yields vary throughout a major subarctic river basin and that accurate estimates of total river export can be determined from calculated tributary contributions. Copyright © 2011. This article is a U.S. Government work and is in the public domain in the USA. 相似文献
14.
15.
Residence of trace elements in metasomatized spinel lherzolite xenoliths: a proton-microprobe study 总被引:19,自引:0,他引:19
Suzanne Y. O'Reilly W. L. Griffin C. G. Ryan 《Contributions to Mineralogy and Petrology》1991,109(1):98-113
Minerals occurring in dry and modally metasomatized spinel lherzolites from western Victoria have been analysed by proton microprobe for Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Ba, Pb, Br, rare-earth elements (REE), Th and U. Mass-balance calculations demonstrate that these trace elements are contained in specific acceptor minerals and do not occur in significant concentrations at clean grain boundaries. The level of particular trace elements in the rock depends on the presence of specific phases: for example high levels of REE, Sr (and U, Th, Br) require apatite, while Ba, Nb and Ta are strongly concentrated in amphibole±mica. Mantle metasomatism in these spinel lherzolites is inferred to result from an open-system process involving infiltration of fluids released by crystallizing silicate melts. This process produces metasomatic zones with different modal mineralogy and hence greatly different trace-element signatures. The data demonstrate that large-ion-lithophile (LIL) and high-field strength (HFS) elements in metasomatized spinel lherzolites are strongly concentrated in non-refractory phases, which will break down easily in heated volumes such as the walls of magma conduits. The heterogeneity observed in trace-element patterns of intraplate alkali basaltic rocks may not reflect source heterogeneity, but may result largely from contamination by metasomatized mantle wall rock. The KDs for most trace elements show little temperature dependence except for KDSr between orthopyroxene and clinopyroxene where KD decreases with increasing temperature. The generally uniform KDs can be used to test for disequilibrium in such assemblages. 相似文献
16.
The trapped fluid phase in upper mantle xenoliths from Victoria,Australia: implications for mantle metasomatism 总被引:5,自引:0,他引:5
T. Andersen Suzanne Y. O'Reilly W. L. Griffin 《Contributions to Mineralogy and Petrology》1984,88(1-2):72-85
Mantle-derived xenoliths of spinel lherzolite, spinel pyroxenite, garnet pyroxenite and wehrlite from Bullenmerri and Gnotuk maars, southwestern Victoria, Australia contain up to 3 vol.% of fluids trapped at high pressures. The fluid-filled cavities range in size from fluid inclusions (1–100 m) up to vugs 11/2 cm across, lined with euhedral high-pressure phases. The larger cavities form an integral part of the mosaic microstructure. Microthermometry and Raman laser microprobe analysis show that the fluids are dominantly CO2. Small isolated inclusions may have densities 1.19 g/cm3, but most inclusions show microstructural evidence of partial decrepitation during eruption, and these have lower fluid densities. Mass-spectrometric analysis of gases released by crushing or heating shows the presence of He, N2, Ar, H2S, COs and SO2 in small quantities; these may explain the small freezing-point depressions observed in some inclusions. Petrographic, SEM and microprobe studies show that the trapped fluids have reacted with the cavity walls (in clinopyroxene grains) to produce secondary amphiboles and carbonates. The trapped CO2 thus represents only a small residual proportion of an original volatile phase, which has undergone at least two stages of modification — first by equilibration with spinel lherzolite to form amphibole (±mica±apatite), then by limited reaction with the walls of the fluid inclusions. The inferred original fluid was a CO2-H2O mixture, with significant contents of (at least) Cl and sulfur species. Generation of this fluid phase in the garnet-peridotite stability field, followed by its migration to the spinel peridotite stability field, would provide an efficient mechanism for metasomatic enrichment of the upper mantle in LIL elements. This migration could involve either a volatile flux or transport in small volumes of silicate melt that crystallize in the spinel peridotite field. These observations suggest that some portions of the subcontinental upper mantle contain large reservoirs of free fluid CO2, which may be liberated during episodes of rifting or magmatism, to induce granulite-facies metamorphism of the lower crust. 相似文献
17.
Sonja Aulbach William L. Griffin Norman J. Pearson Suzanne Y. O’Reilly Buddy J. Doyle 《Contributions to Mineralogy and Petrology》2007,154(4):409-427
Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the
mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate
positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr2O3 contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are
high at a given Al2O3 content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high
olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa
(residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration
(∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a
residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites
(>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these
rocks, which are characterised by low SiO2 contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of
melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced
olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by
lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6). 相似文献
18.
Annual topographic surveys were carried out at the Saltend mudflat (Humber estuary, UK) between 1998 and 2006. These surveys formed part of an ongoing monitoring programme to examine the potential effects on the mudflat topography of the construction and operation of a waste water treatment works (WwTW) development by Yorkshire Water. Of particular concern was the potential disruption to the sedimentological regime within the special protection area (SPA) and candidate special area of conservation (cSAC) which could affect the invertebrate communities and ornithological functioning of the site. In addition to the development of the WwTW located to the extreme north-west of the site, a port extension removing 10 ha of the Saltend intertidal mudflat (outside the SPA but immediately south east of the WwTW) also occurred between 1999 and 2006. Minimal change was noted across the site following the construction and operation of the WwTW between 1998 and 2000. However, the construction of the bund in closer proximity to the SPA and cSAC masked any potential impact the WwTW could have had across the site after 2000. Profiles and contour mapping indicate that significant mudflat accretion occurred in the immediate area of the bund, with a general increase recorded across the western section of the site since 2000. In contrast the alternations to channel planform and subsequent rapid accretion of the mudflat to the east of the jetty, being a significant distance from the developments, are attributed to natural cyclical changes. 相似文献
19.
青藏高原北羌塘新生代高钾钙碱岩系火山岩角闪石类型有痕量元素地球化学 总被引:12,自引:2,他引:12
利用电子探针和激光探针剥蚀系统(LA-ICP-MS)对北羌塘新第三纪高钾钙碱岩系英安岩中角闪石的主元素和微量、角闪石强烈富集Sc、Ti、V、Cr、Co、Ni等不相容亲铁元素,而相对亏损Th、U、Pb、Rb等强不相容的大离子亲石元素。稀土元素丰度高,且无Eu异常,批示北羌塘这套高钾钙碱岩系火山岩可能是青藏高原加厚的相当于榴辉岩相物质组成的下部陆壳脱水熔融的产物。 相似文献
20.
We investigated the incidence of endozoochory in the semi-arid South African Karoo shrubland and Kalahari savanna by dissecting and germinating seed from dung samples from a wide range of wild mammals and domestic livestock. Intact seeds occurred at a mean density of 1575 seeds kg−1in livestock air-dried dung and 3613 seeds kg−1in air-dried dung of indigenous animals. Seedlings emerged from dung at an average density of 153 kg−1air-dry dung. Seeds of Aizoaceae, Mesembryanthemaceae, Chenopodiaceae and Poaceae were abundant in the dung of wild and domestic herbivores as well as such ant- and termite-eating insectivores as aardvark (Orycteropus afer) and bat-eared fox (Otocyon megalotis). Seeds of fleshy-fruited shrubs occurred in dung of browsing herbivores and the bat-eared fox. Five non-indigenous weeds were found in the dung samples. Although the floras of the Kalahari and Karoo are considered to be largely wind and water-dispersed, endozoochory is a primary or secondary dispersal mechanism in many plant families and for many plant life-forms. Animals dispersed seeds of many species characteristic of fertile and disturbed habitats. In Mesembryanthemaceae, a family in which seeds are primarily dispersed very short distances by raindrops, endozoochory enables occasional long-distance dispersal. 相似文献