Laboratory simulation of volatilisation from melts induced by micrometeoroid impacts

The laboratory simulation experiments on volatilization from the melts formed due to micrometeoroid impacts on the lunar surface were carried out. The simulation was performed using modulated laser pulses incident on rocks and minerals in vacuum; in so doing microcraters on the targets, glass particles, condensates were formed and gases solved in the bulk of the rock and mineral grains were released. It is shown that volatilization from only the crater glass layers is negligible, which fully confirms the theoretical predictions of Nussinov and Chernyak.The volatilizations from the drops formed by the micrometeoric impacts can be noticeable. For micron-sized drops, predominant among the others after the impact, the volatilization of Na, K and other volatiles can be up to 10 to 20%. For larger-sized (d10² m) drops the volatilization should lead to the appearance of the significant gradients of the element concentrations over the particle cross-section and as a result of their normalization it leads to the surface enrichment by some elements (Si and others).The mechanism of dust formation due to the surface rocks attack by volatilizing alkaline metals (Naughtonet al.) on the Moon probably is not effective. It is the consequence of such a fact that the condensate of the target materials evaporated due to other simultaneous micrometeoric impacts and had the same (as the target has) elemental composition is the very strong background for volatilizing and condensating alkaline elements.Preliminary conclusions about a possible correlation between the composition and the sizes of dust particles in the Solar system and in the Universe (at similar initial composition) have been drawn.     

Haze Research in Brunei Darussalam During the 1998 Episode

— Brunei Darussalam experienced a severe haze episode between the beginning of February and the end of April 1998 due mainly to local peat and forest fires in Brunei and in neighbouring Sabah and Sarawak. The extensive research studies of the haze carried out in Brunei are outlined together with selected results. Particulate matter (PM₁₀) was the only significant criteria pollutant and it exceeded WHO guidelines and accepted air quality standards on most days during the haze episode. Gaseous criteria pollutants (CO, SO₂, NO₂, O₃) were generally well below WHO guidelines and at these concentrations they are expected to have no significant health or environmental effects. Measurements of volatile organic compounds (VOCs) revealed the presence of benzene, toluene, ethylbenzene, and xylenes (BTEX), aldehydes, phenol, and polynuclear aromatic hydrocarbons (PAHs). Personal exposure monitoring of PM₁₀ revealed significant differences in exposure patterns between different individuals depending on the location, time and activity. Data on outpatient visits showed an increase for some illnesses (e.g., acute respiratory infection) during the months of haze. No significant impacts of haze on rainwater acidity or deposition were noted. Emission factors for some volatile compounds were determined in combustion experiments in which peat was burned at temperatures typical of smouldering.     

SENSITIVITY OF MALARIA, SCHISTOSOMIASIS AND DENGUE TO GLOBAL WARMING

Global assessment of the potential impacts of anthropogenically-induced climate change on vector-borne diseases suggests an increase in extent of the geographical areas susceptible to transmission of malarial Plasmodium parasites, dengue Flavivirus and Schistosoma worms. The transmission potential of the three associated vector-borne diseases studied is highly sensitive to climate changes on the periphery of the currently endemic areas and at higher altitudes within such areas. Our findings vis-à-vis the present endemic areas indicate that the increase in the epidemic potential of malaria and dengue transmission may be estimated at 12–27% and 31–47%, respectively, while in contrast, schistosomiasis transmission potential may be expected to exhibit a 11–17% decrease.     

Cation ordering of orthopyroxenes from the Skaergaard Intrusion: implications for the subsolidus cooling rates and permeabilities

 We have determined the quenched cation ordering states of five orthopyroxene crystals collected from the marginal border group and the lower zone a and b of the Skaergaard intrusion, and modeled these data to retrieve their closure temperatures (T _c) of Fe–Mg ordering and cooling rates. According to existing thermal models for the Skaergaard pluton, conductive cooling dominated the high and low temperature regimes, which were separated by an intermediate temperature regime in which the cooling was controlled primarily by convective fluid circulation. The cooling rates retrieved from the quenched cation ordering states of the orthopyroxene crystals strictly apply to temperatures around the closure temperatures of the ordering states, ∼340–400^° C, which fall at the transition from convective to the lower temperature conductive cooling. The cooling rates obtained from the cation ordering states of orthopyroxene vary from ∼1 to 270 K/ka. These results agree well with a thermal model calculated using an assumed average permeability of 10^-12 cm² for the pluton, but not completely with a model calculated on the basis of an average permeability of 10^-13 cm², although both values produced shifts of δ¹⁸O that are comparable to those observed in the pluton. Received: 27 February 1995/Accepted: 20 July 1995     

Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.