Solubility and near-equilibrium dissolution rates of quartz in dilute NaCl solutions at 398-473 K under alkaline conditions

The dissolution-precipitation of quartz controls porosity and permeability in many lithologies and may be the best studied mineral-water reaction. However, the rate of quartz-water reaction is relatively well characterized far from equilibrium but relatively unexplored near equilibrium. We present kinetic data for quartz as equilibrium is approached from undersaturation and more limited data on the approach from supersaturated conditions in 0.1 molal NaCl + NaOH + NaSiO(OH)₃ solutions with pH 8.2-9.7 at 398, 423, 448, and 473 K. We employed a potentiometric technique that allows precise determination of solution speciation within 2 kJ mol⁻¹ of equilibrium without the need for to perturb the system through physical sampling and chemical analysis. Slightly higher equilibrium solubilities between 423 and 473 K were found than reported in recent compilations. Apparent activation energies of 29 and 37 kJ mol⁻¹ are inferred for rates of dissolution at two surface sites with different values of connectedness: dissolution at Q¹ or Q² silicon sites, respectively. The dissolution mechanism varies with ΔG such that reactions at both sites control dissolution up until a critical free energy value above which only reactions at Q¹ sites are important. When our near-equilibrium dissolution rates are extrapolated far from equilibrium, they agree within propagated uncertainty at 398 K with a recently published model by Bickmore et al. (2008). However, our extrapolated rates become progressively slower than model predictions with increasing temperature. Furthermore, we see no dependence of the postulated Q¹ reaction rate on pH, and a poorly-constrained pH dependence of the postulated Q² rate. Our slow extrapolated rates are presumably related to the increasing contribution of dissolution at Q³ sites far from equilibrium. The use of the potentiometric technique for rate measurement will yield both rate data and insights into the mechanisms of dissolution over a range of chemical affinity. Such measurements are needed to model the evolution of many natural systems quantitatively.     

Minimizing dredging disposal via sediment management in New York Harbor

The Port of New York/New Jersey is naturally shallow, and therefore dredging is required to maintain depths necessary for navigation. About six million cubic yards of material must be dredged annually to maintain navigation channels and berthing areas. Opportunities for disposal of dredged materials in the metropolitan region are limited. The existing ocean disposal site that has, until recently, received the majority of dredged materials is nearing capacity. Under the new, more stringent, guidance for ocean disposal, a large percentage of the dredged material is not considered acceptable for ocean disposal because of contamination. This paper explores nondredging alternatives to reduce the volume of materials to be dredged, thus reducing the disposal volume. These alternatives include short-term options (e.g., reprofiling operations, in which sediments from high spots in berths are dragged to depressions in lower spots) and long-term sedimentation minimization options (e.g., subsurface berms or air bubblers deployed around berths and interpier areas). These methods require an understanding of sedimentation/circulation patterns of the harbor as a whole and the local area in which the specific methodology may be employed.     

The Effects of Integrated Marsh Management (IMM) on Salt Marsh Vegetation,Nekton, and Birds

An integrated marsh management (IMM) project in an urbanized watershed on Long Island, New York, USA, aimed to mitigate salt marsh degradation and to reduce mosquito production by an innovative combination of restoration and open marsh water management methods. The grid ditch network at two treatment marshes was replaced with naturalized tidal channels and ponds. Effects of the hydrologic alterations were monitored utilizing a before–after–control–impact approach. The treatment marshes experienced a number of beneficial outcomes including a fourfold reduction in the invasive Phragmites australis and increased native vegetation cover in the most degraded portions of the marsh, increased abundance and diversity of marsh killifish and estuarine nekton species, higher shorebird and waterfowl densities, and increased avian species diversity. The successful implementation of IMM concept led to improved marsh health and diminished mosquito production. Therefore, this study may serve as a template for similar large-scale integrated salt marsh restoration projects.     

The privatisation of secondary schooling and the desegregation of central Johannesburg

African education controlled by the state's Department of Education and Training has collapsed. Insufficient spending, low standards and persistent student boycotts have made township schools undesirable places of learning. African students with any financial means now seek secondary education at multi-racial private schools in affluent white suburbs or at street-academies in the centre of Johannesburg. The establishment of schooling services for African pupils in the traditionally white central business district contributes to the wider process of desegregation of South Africa's major urban area, Johannesburg.     

Distribution and Characteristics of Dinosaur Eggs in China

正China is one of the most prolific countries for dinosaur material in the world,from skeletons to footprints and eggs.At present,China has documented more than 160kinds of dinosaur,35 genera and 39 ichnospecies of dinosaur footprints,and 17 genera and 44 oospecies of dinosaur eggs.The dinosaur eggs in China are mainly distributed in Xinjiang,Inner Mongolia,Ningxia,Gansu,     

Fatty acids and Pb-210 geochronology of a sediment core from Buzzards Bay,Massachusetts

Four sections of a Pb-210 dated core of 62 cm length from Buzzards Bay, Massachusetts, were analyzed for fatty acids. A comparison of fatty acids extracted by Soxhlet extraction (unbound fatty acids) with fatty acids extracted by subsequent saponification extraction of the same sample (bound fatty acids) showed the former did not undergo diagenetic loss any faster than the latter. However, compositional differences between bound and unbound fatty acids were apparent in the top section of 1–2 cm and were less apparent in the 54–58 cm section. At least 14% of the bound fatty acids are esterified to non-solvent extractable material. The net conversion of fatty acids to other compounds is 32 μ/g dry weight sediment over the first 30 yr after deposition.     

Using simulated hydrologic response to revisit the 1973 Lerida Court landslide

Hydrologically driven mass wasting in the form of landslides on steep slopes is a worldwide occurrence. High-profile events in, for example, Brazil, Chile, the Philippines, Puerto Rico, and Venezuela during the last three decades all clearly illustrate, based upon significant losses of life and property, that hydrologically driven slope instability in developed (urban) areas can be a major geologic/environmental hazard. The focus of this study is the 1973 hydrologically driven Lerida Court landslide in Portola Valley, CA, USA. Physics-based hydrologic-response simulation, with the comprehensive Integrated Hydrology Model, was employed to forensically estimate the spatiotemporal pore pressure distributions for the Lerida Court site. Slope stability, driven by the simulated pore pressure dynamics, was estimated for the Lerida Court site with the infinite slope/Factor of Safety approach. The pore pressure dynamics for the Lerida Court site were reasonably captured by the hydrologic-response simulation. The estimated time of slope failure for the Lerida Court site compares well with field observations. A recommendation is made that hydrologically driven slope stability estimates including variably saturated subsurface flow be standard protocol for development sites in steep urban settings.     

Latest Pleistocene and Holocene glacier variations in the European Alps

In the Alps, climatic conditions reflected in glacier and rock glacier activity in the earliest Holocene show a strong affinity to conditions in the latest Pleistocene (Younger Dryas). Glacier advances in the Alps related to Younger Dryas cooling led to the deposition of Egesen stadial moraines. Egesen stadial moraines can be divided into three or in some cases even more phases (sub-stadials). Moraines of the earliest and most extended advance, the Egesen maximum, stabilized at 12.2 ± 1.0 ka based on ¹⁰Be exposure dating at the Schönferwall (Tyrol, Austria) and the Julier Pass-outer moraine (Switzerland). Final stabilization of moraines at the end of the Egesen stadial was at 11.3 ± 0.9 ka as shown by ¹⁰Be data from four sites across the Alps. From west to east the sites are Piano del Praiet (northwestern Italy), Grosser Aletschgletscher (central Switzerland), Julier Pass-inner moraine (eastern Switzerland), and Val Viola (northeastern Italy). There is excellent agreement of the ¹⁰Be ages from the four sites. In the earliest Holocene, glaciers in the northernmost mountain ranges advanced at around 10.8 ± 1.1 ka as shown by ¹⁰Be data from the Kartell site (northern Tyrol, Austria). In more sheltered, drier regions rock glacier activity dominated as shown, for example, at Julier Pass and Larstig valley (Tyrol, Austria). New ¹⁰Be dates presented here for two rock glaciers in Larstig valley indicate final stabilization no later than 10.5 ± 0.8 ka. Based on this data, we conclude the earliest Holocene (between 11.6 and about 10.5 ka) was still strongly affected by the cold climatic conditions of the Younger Dryas and the Preboreal oscillation, with the intervening warming phase having had the effect of rapid downwasting of Egesen glaciers. At or slightly before 10.5 ka rapid shrinkage of glaciers to a size smaller than their late 20th century size reflects markedly warmer and possibly also drier climate. Between about 10.5 ka and 3.3 ka conditions in the Alps were not conducive to significant glacier expansion except possibly during rare brief intervals. Past tree-line data from Kaunertal (Tyrol, Austria) in concert with radiocarbon and dendrochronologically dated wood fragments found recently in the glacier forefields in both the Swiss and Austrian Alps points to long periods during the Holocene when glaciers were smaller than they were during the late 20th century. Equilibrium line altitudes (ELA) were about 200 m higher than they are today and about 300 m higher in comparison to Little Ice Age (LIA) ELAs. The Larstig rock glacier site we dated with ¹⁰Be is the type area for a postulated mid-Holocene cold period called the Larstig oscillation (presumed age about 7.0 ka). Our data point to final stabilization of those rock glaciers in the earliest Holocene and not in the middle Holocene. The combined data indicate there was no time window in the middle Holocene long enough for rock glaciers of the size and at the elevation of the Larstig site to have formed. During the short infrequent cold oscillations between 10.5 and 3.3 ka small glaciers (less than several km²) may have advanced to close to their LIA dimensions. Overall, the cold periods were just too short for large glaciers to advance. After 3.3 ka, climate conditions became generally colder and warm periods were brief and less frequent. Large glaciers (for example Grosser Aletschgletscher) advanced markedly at 3.0–2.6 ka, around 600 AD and during the LIA. Glaciers in the Alps attained their LIA maximum extents in the 14th, 17th, and 19th centuries, with most reaching their greatest LIA extent in the final 1850/1860 AD advance.