Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

萨拉乌苏河流域萨拉乌苏组砂丘砂沉积特征

The Salawusu Formation of Milanggouwan section in Salawusu River Valley includes 7 layers of paleo-mobile dune sands, and 4 layers of paleo-fixed and semi-fixed dune sands. Their structures have been observed and their grain size, surface textural features and several main chemical elements have been analyzed. The results showed that： 1） Some of the aeolian structural characteristics of these dune sands are similar to that of the recent dune sands. 2） They are also similar to the recent dune sands in grain size components, and parameters of Mz,σ, Sk and Kg, as well as in several main chemical components. 3） The scattergrams of Mz-σ and SiO2-Al2O3＋TOFE and the probability curves of grain size showed that these paleo-dune sands are different from paleosols and fluvio-lacustrine facies, but are consistency with recent dune sands. 4） Quartz sands have well roundness and surface textural features such as dish-shaped pits, crescent-shaped pits, pockmarked pits, upturned cleavage plates, siliceous precipitates and siliceous crevasses, indicating that they had been carried for a long time by the wind. As the 11 layers of paleo-dune sands possess the aeolian characteristics in structure, grain size, surface textural features and chemical elements, the origin of their formation should be attributed to eolation.     

利用地震噪声准实时监测短周期面波波速变化

依据由噪声信号提取面波格林函数的原理,利用福建省地震台网25个宽频带台站2007年7月2日—8月29日的脉动观测资料,得到了瑞雷波群速度在福建地区的分布,并将该结果作为下一步相对变化动态成像的背景速度分布．分布结果表明,福建地区周期为3—5s的瑞雷波群速度大致在2.9—3.1km/s之间,平均速度为3.0km/s,瑞雷波群速度分布呈北高南低的现象,这与福建地区北部多山、南部多平原盆地的地理环境有很好的吻合．而且,该群速度分布图在漳州盆地地区表现出一个非常明显的低速,这主要是因为受到盆地沉积层的影响．通过滑动窗（窗长为20d,步长1d）技术得到了观测区内周期约为3-5s的瑞雷波波速分布变化的连续图像;再利用扣除背景影响的技术,得到了2007年8月14日—2008年7月1日福建地区瑞雷波波速的相对变化时空动态图像．通过分析相对变化时空动态图像与该时间范围内发生的地震的对应关系,表明福建地区瑞雷波波速在多次网内中等强度的地震或震群（ML＞3.0）中均表现出震前波速升高,震后下降恢复的变化趋势．初步分析认为,这可能与震前整个地区受到的应力增大震后应力得到释放所导致的介质变化有关．      

水汽和潜热释放对背风波影响的数值试验

利用中尺度数值模式ARPS进行了理想场的数值模拟,分析研究了水汽和潜热释放对大气层结稳定度的影响以及其在背风波的发展和演变过程中的作用,研究发现,潜热释放对大气层结分布的影响要远大于水汽对大气层结分布的直接影响,如果没有潜热的释放,水汽对背风波的发展和演变的作用非常小,而潜热释放可以使湿层结稳定度急剧下降,迅速破坏原有的层结分布,使这个区域出现非拦截的强烈的垂直运动,波动的崩溃更加迅速和明显。但需要说明的是在试验中,将数值模式里控制潜热释放的参数设为:0、1/2、2的假定情况,则在实际的大气运动过程中是不可能存在的。     

下击暴流实例分析

通过实地灾情调查,本文提供了一个证据较为充分、说服力较强的下击暴流实例,加深了人们对下击暴流的感性认识。实践证明,在观测密度(时间和空间上)远不能满足中小尺度分析要求、探测手段受到很大限制的情况下,用实地灾情调查和地面拍照的办法进行下击暴流这类中小尺度系统的分析是可行的。     

呼和浩特市降水化学特征分析

对2006年呼和浩特市降水离子监测资料进行分析,结果表明:降水呈碱性,季节分布明显,夏季降水集中且pH值为全年最低,冬季降水量少,pH值较高;SO42-离子为主要致酸离子,阳离子中Ca2+,Mg2+离子的浓度很高;降水中主要成分之间相关性显著,Ca2+的中和作用较强;降水气团的后向轨迹分析表明蒙古国的沙漠地区是呼和浩特冬春季碱性降水的主要来源,夏季较低的pH值降水则部分源于我国的华中、华北地区的酸性污染物中长距离输送。     

基于GIS技术的甘肃省气温空间分布特征

利用40 a气象站气温观测数据,结合GIS技术,建立甘肃省气温空间化模型,以高分辨率的DEM作为模型的输入参数实现气温数据的空间化,同时与传统的气温内插方法 (反距离加权法(IDW)、克里格(Kriging)、协同克里格(Co-Kriging))的插值结果进行比较分析,结果反映利用多元回归分析+克里格方法建立的气温数据栅格化结果较好,比传统的气温内插方法插值精度高,插值结果很好的再现了原始测量结果。     

Comparison of manual and automatic methods for measurement of methane emission from rice paddy fields

The methane emission flux from rice paddies was simultaneously measured with automatic and manual methods in the suburban of Suzhou. Both methods were based on the static chamber/ GC-FID techniques. Detail analysis of the experimental results indicates: a) The data of methane emission measured with the automatic method is reliable. b) About 11 or 19 o’clock of local time is recommended as the optimum sampling time for the manual spot measurement of methane emission from rice paddies. The methane emission fluxes measured by manual sampling at local time other than the optimum time have to be corrected. The correction coefficient may be determined by automatic and continuous measurement. c) In order to get a more accurate result, an empirical correction factor, such as 18%, is recommended to correct the seasonally total amount of measured methane emission by enlarging the au-tomatically measured data or reducing the manually measured ones.     

Simulation Study on High Energy Cosmic Electron Detection by Shower Image

Many projects have recently been carried out and proposed for observing high energy electrons since it is realized that cosmic ray electrons are very important when study-ing the dark matter particles and the acceleration mechanism of cosmic rays. An imaging calorimeter,BETS (Balloon-borne Electron Telescope with Scintillator fiber),has been de-veloped for this purpose. Using pattern analysis of the shower development,the electrons can be selected from those primary cosmic ray proton events with flux heights one-tenth that of the electrons. The Monte-Carlo simulation is indispensable for the instrument design,the sig-nal trigger and the data analysis. We present different shower simulation codes and compare the simulation results with the beam test and the flight data of BETS. We conclude that the code FLUKA2002 gives the most consistent results with the experimental data.