Synthesis and characterisation of a multifunctional oil-based drilling fluid additive

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.     

考虑渗透率变化的煤层气储层数值模拟及参数敏感性研究

煤层气开采过程中储层渗透率的变化对产气量影响较大,通过引入S＆D渗透率变化模型,建立了考虑渗透率变化的煤储层三维气水两相渗流数学模型,完成模型检验后应用所编制软件研究了煤储层参数、吸附参数及渗透率模型特征参数对开发效果的影响。结果表明,煤层气产量随着初始含气量、煤层有效厚度、裂缝渗透率和Langmuir压力的增大而增大,随储层原始压力、裂缝孔隙度和Langmuir体积的增大而减小,而解吸时间对产气量影响不大;裂缝渗透率随着杨氏模量和基质收缩/膨胀系数的增大而增大,随泊松比和裂缝压缩系数的增大而减小。引入S＆D模型后计算的累积产气量要比常规模型低1.3%,因此不可忽视煤层气产出过程中渗透率的变化。     

胶州湾海域水质预测

在已建潮流模型的基础上,用ADI法建立了胶州湾扩大域变动边界的平流—扩散输运模型,以COD为指示因子,预测了胶州湾海域1995年、2000年的水质、青岛环海公路海上段、沧口区北半部污水截流、北水南调、集中排放以及胶州湾西部经济开发对海域水质的影响等。为青岛市环保部门制定环保规划提供决策依据。     

2017年春季季风间期南海中北部浮游植物生长与微型浮游动物摄食

Phytoplankton growth rates and mortality rates were experimentally examined at 21 stations during the 2017 spring intermonsoon(April to early May) in the northern and central South China Sea(SCS) using the dilution technique, with emphasis on a comparison between the northern and central SCS areas which had different environmental factors. There had been higher temperature but lower nutrients and chlorophyll a concentrations in the central SCS than those in the northern SCS. The mean rates of phytoplankton growth(μ_0) and microzooplankton grazing(m) were(0.88±0.33) d~(–1) and(0.55±0.22) d~(–1) in the central SCS, and both higher than those in the northern SCS with the values of μ_0((0.81±0.16) d~(–1)) and m((0.30±0.09) d~(–1)), respectively.Phytoplankton growth and microzooplankton grazing rates were significantly coupled in both areas. The microzooplankton grazing impact(m/μ_0) on phytoplankton was also higher in the central SCS(0.63±0.12) than that in the northern SCS(0.37±0.06). The microzooplankton abundance was significantly correlated with temperature in the surface. Temperature might more effectively promote the microzooplankton grazing rate than phytoplankton growth rate, which might contribute to higher m and m/μ_0 in the central SCS. Compared with temperature, nutrients mainly affected the growth rate of phytoplankton. In the nutrient enrichment treatment,the phytoplankton growth rate(μn) was higher than μ_0 in the central SCS, suggesting phytoplankton growth in the central SCS was nutrient limited. The ratio of μ_0/μn was significantly correlated with nutrients concentrations in the both areas, indicating the limitation of nutrients was related to the concentrations of background nutrients in the study stations.     

直排式真空预压法加固吹填土地基的固结沉降分析

直排式真空预压法可以很好缩短工期、效果明显,是近年来在我国沿海地区广泛应用的软土地基处理方法。如何判别地基加固的程度,除了理论分析外,常常以地基处理过程中的沉降、孔隙水压力等指标的实时监测资料作为依据。以杭州湾地区吹填土加固工程为例,采用地表沉降和孔隙水压力的监测资料,分析加固地基固结沉降程度。结果表明,以沉降和孔隙水压力实时监测数据可准确判别吹填土地基固结程度,可为类似工程提供参考。     

中国近海龙介虫科 (多毛纲：缨鳃虫目)的研究Ⅱ

本文是中国近海多毛纲、缨鳃虫目、龙介虫科(石灰虫科)分类区系研究的第二篇报道。本科动物除吴宝铃、陈木(1981、1985)报道5种(含2新种)，杨德渐、孙瑞平(1988)报道6种，孙瑞平(1998)报道南沙群岛6种(含1新种)， Fiege and Sun(1999)报道海南岛22种，以及孙瑞平、杨德渐(2000)第一篇报道龙介虫科的盘管虫属 Hydroides 28种外，迄今国内尚无系统研究。作者对中国科学院海洋研究所历年收藏的标本进行了研究，现报道龙介虫科的伪柱盖虫属 Pseudovermilia、龙介虫属 Serpula、半龙介虫属 Semiserpula、半柱盖虫属 Semivermilia、旋鰓虫属 Spirobranchus和柱盖虫属 Vermiliopsis共6属23种(2新种，7种为我国首次记录和1个复合种)。模式标本保存在中国科学院海洋研究所标本馆，其种名录如下(有*者为我国首次记录)。     

海带中抑藻活性化合物的分离及抑藻活性分析

以2000 g海带为原料、米氏凯伦藻为测试微藻,采用甲醇浸提、液液萃取、硅胶柱层析、Seph-adax LH-20凝胶柱层析和硅胶薄层层析等分离方法,纯化可能具有抑藻活性的化合物,制备到5个薄层纯样品,B21(1.39 g)、B131(0.51 g)、B132(0.48 g)、C211(0.016 g)和C212(0....     

煤田地质超深孔钻探工艺

在对深部煤田地质钻孔钻进工艺研究的基础上,有针对性选择使用聚合物泥浆,解决了基浆配制用水及泥浆抗地表水水质污染问题。通过改变双管钻具长度和改换取心钻头的切削具,满足软硬互层对钻头钻进效率的影响。在煤系地层钻进中,除采用常规的单管钻具钻进外,在见煤预告下过后,采用加长双管取心钻具,既可保证了回次进尺,又可保证岩心的采取。多项措施落实,不仅解决了生产中的一些难题,收到了较好的效果,而且创造了河北省煤田地质局煤田地质单孔钻探深度2 009.12m的新纪录,为今后深部钻孔的施工积累了经验。     

海拉尔盆地乌尔逊—贝尔凹陷白垩系沉积相配置及演化研究

在等时地层格架的基础上,通过对海拉尔盆地乌尔逊—贝尔凹陷130口钻井岩心的精细描述、薄片鉴定和电测曲线分析,根据岩石类型组合、沉积结构和构造以及沉积序列等沉积相标志在海拉尔盆地下白垩统识别出冲积扇、扇三角洲、曲流河三角洲、湖泊和湖底扇5种沉积相类型,进一步划分出15种亚相以及21种微相类型.铜钵庙组沉积时期盆地为填平补...     

Temporal Variability of Total Ozone in the Asian Region Inferred from Ground-Based and Satellite Measurement Data

This paper reports investigation data on the temporal variability of total ozone content (TOC) in the Central Asian and Tibet Plateau mountain regions obtained by conventional methods, as well as by spectral, cross-wavelet, and composite analyses. The data of ground-based observation stations located at Huang He, Kunming, and Lake Issyk-Kul, along with the satellite data obtained at SBUV/SBUV2 (SBUV merged total and profile ozone data, Version 8.6) for 1980–2013 and OMI (Ozone Monitoring Instrument) and TOU (Total Ozone Unit) for 2009–2013 have been used. The average relative deviation from the SBUV/SBUV2 data is less than 1% in Kunming and Issyk-Kul for the period of 1980–2013, while the Huang He Station is characterized by an excess of the satellite data over the ground-based information at an average deviation of 2%. According to the Fourier analysis results, the distribution of amplitudes and the periods of TOC oscillations within a range of over 14 months is similar for all series analyzed. Meanwhile, according to the cross-wavelet and composite analyses results, the phase relationships between the series may considerably differ, especially in the periods of 5–7 years. The phase of quasi-decennial oscillations in the Kunming Station is close to the 11-year oscillations of the solar cycle, while in the Huang He and Issyk-Kul stations the TOC variations go ahead of the solar cycle.