Measurement of PAN in the Polluted Boundary Layer and Free Troposphere Using a Luminol-NO2 Detector Combined with a Thermal Converter

Peroxyacetyl nitrate (PAN,CH³C(O)O₂NO₂) has been measured inthe polluted boundary layer and free troposphere by thermal conversion tonitrogen dioxide (NO₂) followed by detection of thedecomposition product with a Scintrex LMA-3 NO₂-luminolinstrument. Following laboratory tests of the efficiency of PAN conversionand investigations of possible interferences, the technique was evaluated atthe West Beckham TOR (Tropospheric Ozone Research) Station near the northNorfolk coast in Eastern England between September 1989 and August 1990. PANmeasured by the new technique was reasonably well correlated with PANrecorded using electron capture gas chromatography (EC/GC). PAN was alsowell correlated with ozone (O³) in the summer months. Springand autumn episodes of simultaneously high concentrations of PAN andO³ were examined in conjunction with air parcelback-trajectories and synoptic- and local-scale meteorology in a study ofthe sources of photooxidants on the east coast of England. Spring-timemeasurements of PAN made in the free troposphere in a light aircraft ataltitudes up to 3.1 km showed the presence of 0.54 and 0.26 ppbv PAN inpolar maritime and mid-latitude oceanic air masses, respectively. Thetechnique is particularly suited to airborne applications because potentialinterferences are minimised and the frequency of measurements is higher thangenerally achieved with EC/GC methods.     

Electron spin resonance spectra of marine and fresh-water manganese nodules

Eighty ferromanganese nodules from a wide variety of marine and fresh-water environments have been analyzed by electron spin resonance spectroscopy. The purpose has been to gain information on the forms in which the major constituents of manganese nodules are present. Contributions to ESR spectra of the nodules come mainly from Mn²⁺ and Fe³⁺. Deep-sea samples generally showed only broad resonance lines, and those with larger peaks close to g = 2.0 are believed to contain more Mn²⁺ than others. Some Antarctic and fresh-water nodules lack a strong Mn²⁺ resonance and have a peak around g = 4.0 which is most likely tetrahedral Fe³⁺. A number of smaller peaks in several samples could not be readily interpreted in terms of contributions from individual ionic species because of fundamental problems in preparing standards having the ion of interest in the same micro-environment as it experiences in the nodules.     

Intracratonic asthenosphere upwelling and lithosphere rejuvenation beneath the Hoggar swell (Algeria): Evidence from HIMU metasomatised lherzolite mantle xenoliths

The mantle xenoliths included in Quaternary alkaline volcanics from the Manzaz-district (Central Hoggar) are proto-granular, anhydrous spinel lherzolites. Major and trace element analyses on bulk rocks and constituent mineral phases show that the primary compositions are widely overprinted by metasomatic processes. Trace element modelling of the metasomatised clinopyroxenes allows the inference that the metasomatic agents that enriched the lithospheric mantle were highly alkaline carbonate-rich melts such as nephelinites/melilitites (or as extreme silico-carbonatites). These metasomatic agents were characterized by a clear HIMU Sr–Nd–Pb isotopic signature, whereas there is no evidence of EM1 components recorded by the Hoggar Oligocene tholeiitic basalts. This can be interpreted as being due to replacement of the older cratonic lithospheric mantle, from which tholeiites generated, by asthenospheric upwelling dominated by the presence of an HIMU signature. Accordingly, this rejuvenated lithosphere (accreted asthenosphere without any EM influence), may represent an appropriate mantle section from which deep alkaline basic melts could have been generated and shallower mantle xenoliths sampled, respectively. The available data on lherzolite xenoliths and alkaline lavas (including He isotopes, Ra < 9) indicate that there is no requirement for a deep plume anchored in the lower mantle, and that sources in the upper mantle may satisfactorily account for all the geochemical/petrological/geophysical evidence that characterizes the Hoggar swell. Therefore the Hoggar volcanism, as well as other volcanic occurrences in the Saharan belt, are likely to be related to passive asthenospheric mantle uprising and decompression melting linked to tensional stresses in the lithosphere during Cenozoic reactivation and rifting of the Pan–African basement. This can be considered a far-field foreland reaction of the Africa–Europe collisional system since the Eocene.     

Numerical modelling of depositional sequences in half-graben rift basins

ABSTRACT A three‐dimensional numerical model of sediment transport and deposition in coarse‐grained deltas is used to investigate the controls on depositional sequence variability in marine half‐graben extensional basins subject to eustatic sea‐level change. Using rates of sea‐level change, sediment supply and fault slip reported from active rift basins, the evolution of deltas located in three contrasting structural settings is documented: (1) footwall‐sourced deltas in high‐subsidence locations near the centre of a fault segment; (2) deltas fed by large drainage catchments at fault tips; and (3) deltas sourced from drainage catchments on the hangingwall dip slope. Differences in the three‐dimensional form and internal stratigraphy of the deltas result from variations in tilting of the hangingwall and the impact of border fault slip rates on accommodation development. Because subsidence rates near the centre of fault segments are greater than all but the fastest eustatic falls, footwall‐sourced deltas lack sequence boundaries and are characterized by stacked highstand systems tracts. High subsidence and steep bathymetry adjacent to the fault result in limited progradation. In contrast, the lower subsidence rate settings of the fault‐tip and hangingwall dip‐slope deltas mean that they are subject to relative sea‐level fall and associated fluvial incision and forced regression. Low gradients and tectonic tilting of the hangingwall influence the geometry of these deltas, with fault‐tip deltas preferentially prograding axially along the fault, creating elongate delta lobes. In contrast, broad, sheet‐like delta lobes characterize the hangingwall dip‐slope deltas. The model results suggest that different systems tracts may be coeval over length scales of several kilometres and that key stratal surfaces defining and subdividing depositional sequences may only be of local extent. Furthermore, the results highlight pitfalls in sequence‐stratigraphic interpretation and problems in interpreting controlling processes from the preserved stratigraphic product.     

EURD: First Year Results

EURD (Espectrógrafo Ultravioleta extremo de Radiación Difusa), one of the instruments onboard the Spanish satellite MINISAT-01, is a spectrograph specially designed to detect diffuse radiation, covering the wavelength range of 350-1100 Å, with a spectral resolution of 6-8 Å. Its main scientific objectives are the detection of the emission line spectrum from the hot phase of the interstellar medium and the spectrum of the upper atmospheric airglow. In order to reduce geocoronal noise, EURD always observes in the anti-sun direction and only when the satellite is in orbital eclipse. After more than one year of observation we have obtained the best spectrum of the upper atmospheric nightglow in this wavelength range, the spectrum of 15 OB stars and the spectrum of the full Moon throughout the year. This revised version was published online in July 2006 with corrections to the Cover Date.     

Satellite-derived vegetation index and cover type maps for estimating carbon dioxide flux for arctic tundra regions

The spatial variability and co-variability of two different types of remote sensing derivatives that portray vegetation and geomorphic patterns are analyzed in the context of estimating regional-scale CO₂ flux from land surfaces in the arctic tundra. For a study area encompassing the Kuparuk River watershed of the North Slope of Alaska, we compare satellite-derived maps of the normalized difference vegetation index (NDVI) generated at two different spatial resolutions to a map of vegetation types derived by image classification of data from the Landsat multispectral scanner (MSS). Mean values of NDVI for each cover type stratum are unique (with the exception of moist acidic tundra and shrubland types). Based on analysis of semi-variograms generated for SPOT-NDVI data, most of the vegetation cover and landform features of this arctic tundra landscape have spatial dimensions of less than 1 km. Thaw lakes on the coastal plain and glacial depositional landforms, such as moraines in the foothills, seem to be the largest features, with vegetation units having dimensions no larger than 700 m. Frequency distributions of NDVI and vegetation types extracted for sampling transects flown by an aircraft sensing CO₂ flux, relative to distributions for the entire Kuparuk River watershed, suggest a slight sampling bias towards greater cover of mesic wet sedge tundra and thaw lakes and associated lower NDVI values. The regional pattern of NDVI for the North Slope of Alaska corresponds primarily to differences between the two major physiographic provinces of this region.