Petrochemistry of the silicic-mafic complexes at Vesturhorn and Austurhorn, Iceland: evidence for zoned/stratified magma

Within the Austurhorn and Vesturhorn silicic intrusions of southeastern Iceland are composite complexes that consist of pillow-like bodies of mafic and intermediate rock entirely surrounded by silicic rock. The pillows with cuspate and chilled boundaries are interpreted to indicate a liquid-liquid relationship with a silicic magma. Some pillow-like bodies have a chilled and sharp cuspate boundary, whereas others have a distinct chemical and visible gradational contact with the silicic rock. The visible scale of mixing is of the same order of magnitude as the size of the pillows enclosed in the silicic rock (mm to meters).Two important types of chemical variation in the pillows are recognized. The first type of variation occurs from mafic pillow interiors to margins and into the surrounding silicic rock. These variations are due to mechanical mixing between mafic magma and the silicic magma. The second type of chemical variation occurs between individual pillows. Large variations occur between pillows in P and Ti at nearly constant silica. These variations cannot have resulted from in situ simple magma mixing or crystal fractionation, and must have originated at depth below the present level of exposure. These compositions could have been derived from separate mafic (or intermediate) magma bodies or from a single zoned and/or stratified magma body. Because the Austurhorn, Vesturhorn, and Ardnamurchan composite complexes all exhibit similar variations in P and Ti and because these occurrences are separated in space and time, they are thought to have had similar processes occur during their evolution. The chemical variations are interpreted to have resulted from mafic magma that has underplated silicic magma and become zoned/stratified due to the effects of magma mixing and cooling-crystallization.     

A chemical survey of the Mississippi estuary

A “snap shot” survey of the Mississippi estuary was made during a period of low river discharge, when the estuarine mixing zone was within the deltaic channels. Concentrations of H⁺, Ca²⁺, inorganic phosphorus and inorganic carbon suggest that the waters of the river and the low salinity (<5‰) portion of the estuary are near saturation with respect to calcite and sedimentary calcium phosphate. An input of oxidized nitrogen species and N₂O was observed in the estuary between 0 and 4‰ salinity. The concentrations of dissolved NH₄ ⁺ and O₂, over most of the estuary, appeared to be influenced by decomposition of terrestrial organic matter in bottom sediments. The estuarine bottom also appears to be a source of CH₄ which has been suggested to originate from petroleum shipping and refining operations. Estuarine mixing with offshore Gulf waters was the dominant influence on distributions of dissolved species over most of the estuary (i.e., from salinities >5‰). The phytoplankton abundance (measured as chlorophylla) increased as the depth of the mixed layer decreased in a manner consistent with that expected for a light-limited ecosystem. Fluxes of NO₃ ^?+NO₂ ^? and soluble inorganic phosphorus to the Gulf of Mexico were estimated to be 3.4±0.2×10³ g N s^?1 and 1.9±0.2 g P s^?1 respectively, at the time of this study.     

A revised identification of the oldest sea-floor spreading anomalies between Australia and Antarctica

We propose that magnetic anomalies south of Australia and along the conjugate margin of Antarctica that were originally identified as anomalies 19 to 22 may be anomalies 20 to 34. The original anomaly identification has two troublesome aspects: (1) it does not account for an “extra” anomaly between anomalies 20 and 21, and (2) it provides no explanation for the rough topography comprising the Diamantina Zone. With our revised identification there is no “extra” anomaly and the Diamantina Zone is attributed to a period of very slow spreading (～4.5mm/yr half rate) between 90 and 43 m.y. The ages bounding the interval of slow spreading (90 and 43 m.y.) correspond to times of global plate reorganizations. Our revised identification opens up the possibility that part of the magnetic quiet zone south of Australia formed during the Cretaceous long normal polarity interval. Breakup of Australia and Antarctica probably occurred sometime between 110 and 90 m.y. B.P. The “breakup unconformity” identified by Falvey in the Otway Basin may correspond to a eustastic sea level change.     

Environmental oxidation rate of manganese(II): bacterial catalysis

A simple mass balance for dissolved manganese(II) in waters containing low levels of oxygen in Saanich Inlet indicates that the residence time for Mn(II) removal to the solid phase is on the order of a few days. The average oxidation state of Mn in particulate material sampled from the region of Mn removal was 2.3–2.7, and electron micrographs revealed structures characteristic of bacterially formed Mn precipitates. Radiotracer experiments utilizing ⁵⁴Mn(II) indicated that removal of Mn from solution in the region of active uptake was substantially blocked by a poison mixture, demonstrating that Mn(II) binding to particulates is catalyzed by bacteria in this environment.     

ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions

Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies.     

The physical volcanology of the 1600 eruption of Huaynaputina, southern Peru

Volcán Huaynaputina is a group of four vents located at 16°36'S, 70°51'W in southern Peru that produced one of the largest eruptions of historical times when ~11 km³ of magma was erupted during the period 19 February to 6 March 1600. The main eruptive vents are located at 4200 m within an erosion-modified amphitheater of a significantly older stratovolcano. The eruption proceeded in three stages. Stage I was an ~20-h sustained plinian eruption on 19-20 February that produced an extensive dacite pumice fall deposit (magma volume ~2.6 km³). Throughout medial-distal and distal parts of the dispersal area, a fine-grained plinian ashfall unit overlies the pumice fall deposit. This very widespread ash (magma volume ~6.2 km³) has been recognized in Antarctic ice cores. A short period of quiescence allowed local erosion of the uppermost stage-I deposits and was followed by renewed but intermittent explosive activity between 22 and 26 February (stage II). This activity resulted in intercalated pyroclastic flow and pumice fall deposits (~1 km³). The flow deposits are valley confined, whereas associated co-ignimbrite ash fall is found overlying the plinian ash deposit. Following another period of quiescence, vulcanian-type explosions of stage III commenced on 28 February and produced crudely bedded ash, lapilli, and bombs of dense dacite (~1 km³). Activity ceased on 6 March. Compositions erupted are predominantly high-K dacites with a phenocryst assemblage of plagioclase>hornblende>biotite>Fe-Ti oxides-apatite. Major elements are broadly similar in all three stages, but there are a few important differences. Stage-I pumice has less evolved glass compositions (~73% SiO₂), lower crystal contents (17-20%), lower density (1.0-1.3 g/cm³), and phase equilibria suggest higher temperature and volatile contents. Stage-II and stage-III juvenile clasts have more evolved glass (~76% SiO₂) compositions, higher crystal contents (25-35%), higher densities (up to 2.2 g/cm³), and lower temperature and volatile contents. All juvenile clasts show mineralogical evidence for thermal disequilibrium. Inflections on a plot of log thickness vs area^1/2 for the fall deposits suggest that the pumice fall and the plinian ash fall were dispersed under different conditions and may have been derived from different parts of the eruption column system. The ash appears to have been dispersed mainly from the uppermost parts of the umbrella cloud by upper-level winds, whereas the pumice fall may have been derived from the lower parts of the umbrella cloud and vertical part of the eruption column and transported by a lower-altitude wind field. Thickness half distances and clast half distances for the pumice fall deposit suggests a column neutral buoyancy height of 24-32 km and a total column height of 34-46 km. The estimated mass discharge rate for the ~20-h-long stage-I eruption is 2.4᎒⁸ kg/s and the volumetric discharge rate is ~3.6᎒⁵ m³/s. The pumice fall deposit has a dispersal index (Hildreth and Drake 1992) of 4.4, and its index of fragmentation is at least 89%, reflecting the dominant volume of fines produced. Of the 11 km³ total volume of dacite magma erupted in 1600, approximately 85% was evacuated during stage 1. The three main vents range in size from ~70 to ~400 m. Alignment of these vents and a late-stage dyke parallel to the NNW-SSE trend defined by older volcanics suggest that the eruption initiated along a fissure that developed along pre-existing weaknesses. During stage I this fissure evolved into a large flared vent, vent 2, with a diameter of approximately 400 m. This vent was active throughout stage II, at the end of which a dome was emplaced within it. During stage III this dome was eviscerated forming the youngest vent in the group, vent 3. A minor extra-amphitheater vent was produced during the final event of the eruptive sequence. Recharge may have induced magma to rise away from a deep zone of magma generation and storage. Subsequently, vesiculation in the rising magma batch, possibly enhanced by interaction with an ancient hydrothermal system, triggered and fueled the sustained Plinian eruption of stage I. A lower volatile content in the stage-II and stage-III magma led to transitional column behavior and pyroclastic flow generation in stage II. Continued magma uprise led to emplacement of a dome which was subsequently destroyed during stage III. No caldera collapse occurred because no shallow magma chamber developed beneath this volcano.     

Use of a reservoir water quality model to simulate global climate change effects on fish habitat

A case study was conducted on the potential impacts of climate change on fish habitat in a southeastern reservoir. A reservoir water quality model and one year of baseline meteorologic, hydrologic, and inflow water quality input were used to simulate current reservoir water quality. Total adult striped bass habitat, defined by specific quantitative temperature and dissolved oxygen criteria, was simulated. Daily reservoir volumes with optimal, suboptimal, and unsuitable temperature and DO were predicted for the year. Output from recent runs of atmospheric general circulation models (GCMs), in which atmospheric carbon dioxide concentrations have been doubled, was then used to adjust the baseline inputs to the water quality model. New sets of input data were created for two grid cells for each of three GCMs. All six climate scenarios are predicted to cause overall declines in the available summer striped bass habitat, mostly due to lake water temperatures exceeding striped bass tolerance levels. These predictions are believed to result from the consensus among GCM scenarios that air temperatures and humidity will rise, and the sensitivity of the reservoir model to these parameters. The reservoir model was found to be a promising tool for examining potential climate-change impacts. Some of the assumptions required to apply GCM output to the reservoir model, however, illustrate the problems in using large-scale gridcell output to assess small-scale impacts.