Multicomponent reactive transport modeling of uranium bioremediation field experiments

A reaction network integrating abiotic and microbially mediated reactions has been developed to simulate biostimulation field experiments at a former Uranium Mill Tailings Remedial Action (UMTRA) site in Rifle, Colorado. The reaction network was calibrated using data from the 2002 field experiment, after which it was applied without additional calibration to field experiments performed in 2003 and 2007. The robustness of the model specification is significant in that (1) the 2003 biostimulation field experiment was performed with 3 times higher acetate concentrations than the previous biostimulation in the same field plot (i.e., the 2002 experiment), and (2) the 2007 field experiment was performed in a new unperturbed plot on the same site. The biogeochemical reactive transport simulations accounted for four terminal electron-accepting processes (TEAPs), two distinct functional microbial populations, two pools of bioavailable Fe(III) minerals (iron oxides and phyllosilicate iron), uranium aqueous and surface complexation, mineral precipitation and dissolution. The conceptual model for bioavailable iron reflects recent laboratory studies with sediments from the UMTRA site that demonstrated that the bulk (∼90%) of initial Fe(III) bioreduction is associated with phyllosilicate rather than oxide forms of iron. The uranium reaction network includes a U(VI) surface complexation model based on laboratory studies with Rifle site sediments and aqueous complexation reactions that include ternary complexes (e.g., calcium-uranyl-carbonate). The bioreduced U(IV), Fe(II), and sulfide components produced during the experiments are strongly associated with the solid phases and may play an important role in long-term uranium immobilization.     

Association of phosphate with rhyolite glass in marine Neogene tuffs from Patagonia,Argentina

The precipitation/replacement of Ca‐phosphate is a complex process that commonly takes place during the early diagenesis in marine sediments. The unusual occurrence of shallow marine, early diagenetic phosphatic deposits associated with glassy tuffs in the Neogene Gaiman Formation, in the Chubut Province, Patagonia, Argentina, constitutes a good case example for the study of replacement and precipitation of Ca‐phosphate on an unstable substrate. Isocon diagrams illustrate that chemical changes during glass diagenesis include gains in loss on ignition and Ca, and losses of K. These changes are the result of glass hydration during sea water–glass interaction, together with adsorption and diffusion of ions into the bulk shard; combined, these represent an incipient process of volcanic glass replacement by Ca‐phosphate. Subsequent early diagenetic P enrichment in the pore solutions led to phosphate precipitation, associated with pitting on the glass shards and pumice. The associated development of a reactive surface promoted the incorporation of P and Ca into their margins. Lastly, precipitation of calcium phosphate filled the vesicles and other open cavities, inhibiting further glass dissolution. The high porosity and reactivity of the volcanic glass provided an appropriate substrate for phosphate precipitation, leading to the development of authigenic apatite concretions in the volcanic‐glass bearing strata of the Gaiman Formation. This research is of significance for those concerned with marine phosphatic deposits and sheds light on the processes of early diagenetic phosphate precipitation by replacement of an atypical, unstable substrate like hydrated volcanic glass.     

Stability and dynamics of the continental tectosphere

Continental cratons overlie thick, high-viscosity, thermal and chemical boundary layers, where the chemical boundary layers are less dense than they would be due to thermal effects alone, perhaps because they are depleted in basaltic constituents. If the continental tectosphere is the same age as the overlying Archaean crust, then the continental tectosphere must be able to survive for several billion years without undergoing a convective instability, despite being both cold and thick. Since platforms and shields correlate only weakly with Earth's gravity and geoid anomalies, acceptable models of the continental tectosphere must also satisfy this gravity constraint. We investigate the long-term stability of the continental tectosphere by carrying out a number of numerical convection experiments within a two-dimensional Cartesian domain. We initiate our experiments with a tectosphere (thermal and chemical boundary layers) immersed in a region of uniform composition, temperature, and viscosity, and consider the effects on the stability of the tectosphere of (1) activation energy (used to define the temperature dependence of viscosity), (2) compositional buoyancy, and (3) linear or non-linear rheology. The large lateral thermal gradients required to match oceanic and tectosphere structures initiate the dominant instability, a “drip” which develops at the side of the tectosphere and moves to beneath its center. High activation energies and high background viscosities restrict the amount and rate of entrainment. Compositional buoyancy does not significantly change the flow pattern. Rather, compositional buoyancy slows the destruction process somewhat and reduces the stress within the tectosphere. With a non-Newtonian rheology, this reduction in stress helps to stiffen the tectosphere. In these experiments, dynamical systems that adequately model the present ocean-continent structures have activation energy E*≥180 kJ mole⁻¹ — a value about one third the estimate of activation energy for olivine, E*≈520 kJ mole⁻¹. Although for E*≈520 kJ mole⁻¹, compositional buoyancy is not required for the tectosphere to survive, the joint application of longevity and gravity constraints allows us to reject all models not containing compositional buoyancy, and to predict that the ratio of compositional to thermal buoyancy within the continental tectosphere is approximately unity.     

The identification of distinct patterns in California temperature trends

Regional changes in California surface temperatures over the last 80 years are analyzed using station data from the US Historical Climate Network and the National Weather Service Cooperative Network. Statistical analyses using annual and seasonal temperature data over the last 80 years show distinctly different spatial and temporal patterns in trends of maximum temperature (Tmax) compared to trends of minimum temperature (Tmin). For trends computed between 1918 and 2006, the rate of warming in Tmin is greater than that of Tmax. Trends computed since 1970 show an amplified warming rate compared to trends computed from 1918, and the rate of warming is comparable between Tmin and Tmax. This is especially true in the southern deserts, where warming trends during spring (March?CMay) are exceptionally large. While observations show coherent statewide positive trends in Tmin, trends in Tmax vary on finer spatial and temporal scales. Accompanying the observed statewide warming from 1970 to 2006, regional cooling trends in Tmax are observed during winter and summer. These signatures of regional temperature change suggest that a collection of different forcing mechanisms or feedback processes must be present to produce these responses.     

Late Quaternary record of Indian summer monsoon-induced stratification and productivity collapse in the Andaman Sea

During each summer monsoon, the northeastern Indian Ocean receives a huge amount of rain and river discharge, resulting in strong stratification and prevalence of oligotrophic conditions. These water column changes impact upper ocean productivity which is reflected in the planktonic foraminifera distribution, providing an opportunity to study the effect of monsoon forcing and stratification history. Analogous to modern-day stratification, very intense water column stratification and productivity collapse were observed associated with Indian summer monsoon (ISM) evolution. This paper reports significant stratification events during MIS 3 (37.0 to 33 and 27 to 24 cal ka), Bølling/Allerød (B/A), early Holocene (10.0 to 8.0 cal ka) and mid-Holocene (7.0 to 5.0 cal ka) which slowly muted upwelling and productivity. The deglacial intensification of the ISM started in the early stages of the Bølling/Allerød (B/A) followed by slight weakening during the Younger Dryas and regained strength during the early Holocene, coinciding with the highest summer insolation at 30°N. A progressive decline in the abundances of productivity and salinity proxies from 4.2 to 2.0 cal ka suggests a gradual weakening of the ISM. The late Quaternary productivity variations in the Bay of Bengal and the Andaman Sea are primarily controlled by salinity-related stratification.     

Variability of tree transpiration across three zones in a southeastern U.S. Piedmont watershed

Quantifying the spatial variability of species-specific tree transpiration across hillslopes is important for estimating watershed-scale evapotranspiration (ET) and predicting spatial drought effects on vegetation. The objectives of this study are to (1) assess sap flux density (J_s) and tree-level transpiration (T_s) across three contrasting zones a (riparian buffer, mid-hillslope and upland-hillslope, (2) determine how species-specific J_s responds to vapour pressure deficit (VPD) and (3) estimate watershed-level transpiration (T_w) using T_s derived from each zone. During 2015 and 2016, we measured J_s in eight tree species in the three topographic zones in a small 12-ha forested watershed in the Piedmont region of central North Carolina. In the dry year of 2015, loblolly pine (Pinus taeda), Virginia pine (Pinus virginiana) and sweetgum (Liquidambar styraciflua) J_s rates were significantly higher in the riparian buffer when compared to the other two zones. In contrast, J_s rates in tulip poplar (Liriodendron tulipifera) and red maple (Acer rubrum) were significantly lower in the buffer than in the mid-hillslope. Daily T_s varied by zone and ranged from 10 to 93 L/day in the dry year and from 9 to 122 L/day in the wet year (2016). J_s responded nonlinearly to VPD in all species and zones. Annual T_w was 447, 377 and 340 mm based on scaled-J_s data for the buffer, mid-hillslope and upland-hillslope, respectively. We conclude that large spatial variability in J_s and scaled T_w was driven by differences in soil moisture at each zone and forest composition. Consequently, spatial heterogeneity of vegetation and soil moisture must be considered when accurately quantifying watershed level ET.     

Performance of the Nuclear Compton Telescope

On 1 June 2005, the prototype Nuclear Compton Telescope (NCT) flew on a high altitude balloon from Fort Sumner, New Mexico. NCT is a balloon-borne soft γ-ray (0.2–10 MeV) telescope for studying astrophysical sources of nuclear line emission and γ-ray polarization. Our program is designed to develop and test technologies and analysis techniques crucial for the Advanced Compton Telescope; however, our detector design and configuration is also well matched to the focal plane requirements for focusing Laue lenses. The NCT prototype utilizes two, 3D imaging germanium detectors (GeDs) in a novel, ultra-compact design optimized for nuclear line emission in the 0.5–2 MeV range. Our prototype flight provides a critical test of the novel detector technologies, analysis techniques, and background rejection procedures developed for high resolution Compton telescopes.     

On the absence of critical levels in the solar atmosphere

We consider the propagation of linear oscillations in a stratified atmosphere permeated by an oblique but nearly horizontal uniform magnetic field. Our results do not show any of the strong characteristics associated with critical level singularities in the exactly horizontal field case. This suggests that critical levels may be of more mathematical interest than physical relevance in the solar atmosphere where the planar horizontal field approximation is seldom adequate.Currently a Nuffield Foundation Science Research Fellow.