Recommended Sampling Intervals for Arsenic in Private Wells

Geogenic arsenic in drinking water is a worldwide problem. For private well owners, testing (e.g., private or government laboratory) is the main method to determine arsenic concentration. However, the temporal variability of arsenic concentrations is not well characterized and it is not clear how often private wells should be tested. To answer this question, three datasets, two new and one publicly available, with temporal arsenic data were utilized: 6370 private wells from New Jersey tested at least twice since 2002, 2174 wells from the USGS NAWQA database, and 391 private wells sampled 14 years apart from Bangladesh. Two arsenic drinking water standards are used for the analysis: 10 µg/L, the WHO guideline and EPA standard or maximum contaminant level (MCL) and 5 µg/L, the New Jersey MCL. A rate of change was determined for each well and these rates were used to predict the temporal change in arsenic for a range of initial arsenic concentrations below an MCL. For each MCL and initial concentration, the probability of exceeding an MCL over time was predicted. Results show that to limit a person to below a 5% chance of drinking water above an MCL, wells that are ½ an MCL and above should be tested every year and wells below ½ an MCL should be tested every 5 years. These results indicate that one test result below an MCL is inadequate to ensure long-term compliance. Future recommendations should account for temporal variability when creating drinking water standards and guidance for private well owners.     

Tile drainage causes flashy streamflow response in Ohio watersheds

Artificial subsurface (tile) drainage is used to increase trafficability and crop yield in much of the Midwest due to soils with naturally poor drainage. Tile drainage has been researched extensively at the field scale, but knowledge gaps remain on how tile drainage influences the streamflow response at the watershed scale. The purpose of this study is to analyse the effect of tile drainage on the streamflow response for 59 Ohio watersheds with varying percentages of tile drainage and explore patterns between the Western Lake Erie Bloom Severity Index to streamflow response in heavily tile-drained watersheds. Daily streamflow was downloaded from 2010 to 2019 and used to calculated mean annual peak daily runoff, mean annual runoff ratio, the percent of observations in which daily runoff exceeded mean annual runoff (T_Qmean), baseflow versus stormflow percentages, and the streamflow recession constant. Heavily-drained watersheds (>40% of watershed area) consistently reported flashier streamflow behaviour compared to watersheds with low percentages of tile drainage (<15% of watershed area) as indicated by significantly lower baseflow percentages, T_Qmean, and streamflow recession constants. The mean baseflow percent for watersheds with high percentages of tile drainage was 20.9% compared to 40.3% for watersheds with low percentages of tile drainage. These results are in contrast to similar research regionally indicating greater baseflow proportions and less flashy hydrographs (higher T_Qmean) for heavily-drained watersheds. Stormflow runoff metrics in heavily-drained watersheds were significantly positively correlated to western Lake Erie algal bloom severity. Given the recent trend in more frequent large rain events and warmer temperatures in the Midwest, increased harmful algal bloom severity will continue to be an ecological and economic problem for the region if management efforts are not addressed at the source. Management practices that reduce the streamflow response time to storm events, such as buffer strips, wetland restoration, or drainage water management, are likely to improve the aquatic health conditions of downstream communities by limiting the transport of nutrients following storm events.     

Distribution and concentrations of petroleum hydrocarbons associated with the BP/Deepwater Horizon Oil Spill,Gulf of Mexico

We examined the geographic extent of petroleum hydrocarbon contamination in sediment, seawater, biota, and seafood during/after the BP/Deepwater Horizon Oil Spill (April 20–July 15, 2010; 28.736667°N, −88.386944°W). TPH, PAHs, and 12 compound classes were examined, particularly C1-benzo(a)anthracenes/chrysenes, C-2-/C-4-phenanthrenes/anthracenes, and C3-naphthalenes. Sediment TPH, PAHs, and all classes peaked near Pensacola, Florida, and Galveston, Texas. Seawater TPH peaked off Pensacola; all of the above classes peaked off the Mississippi River, Louisiana and Galveston. Biota TPH and PAHs peaked near the Mississippi River; C-3 napthalenes peaked near the spill site. Seafood TPH peaked near the spill site, with PAHs and all classes peaking near Pensacola. We recommend that oil concentrations continued to be monitored in these media well after the spill has ceased to assist in defining re-opening dates for fisheries; closures should be maintained until hydrocarbon levels are deemed within appropriate limits.     

Evaluation of temporal concentration profiles for ungauged rivers following pollution incidents

Abstract

In order to predict the impact of pollution incidents on rivers, it is necessary to predict the dispersion coefficient and the flow velocity corresponding to the discharge in the river of interest. This paper explores methods for doing this, particularly with a view to applications on ungauged rivers, i.e. those for which little hydraulic or morphometric data are available. An approach based on neural networks, trained on a wide-ranging database of optimized parameter values from tracer experiments and corresponding physical variables assembled for American and European rivers, is proposed. Tests using independent cases showed that the neural networks generally gave more reliable parameter estimates than a second-order polynomial regression approach. The quality of predictions of temporal concentration profiles was heavily influenced by the accuracy of the velocity prediction.

Citation Piotrowski, A. P., Napiorkowski, J. J., Rowinski, P. M. & Wallis, S. G. (2011) Evaluation of temporal concentration profiles for ungauged rivers following pollution incidents. Hydrol. Sci. J. 56(5), 883–894.     

安徽铜陵地区幔源镁铁质团块研究及其地质意义

幔源岩石包体研究,是认识上地幔岩石圈物质组成、幔源岩浆演化及壳幔动力学过程的重要手段。铜陵地区小铜官山石英二长闪长岩中发育有微粒闪长质包体,并且这些微粒闪长质包体中不均匀地分布着镁铁质团块,三者的形成过程可视为铜陵地区岩浆演化的缩影,为了解本区深部岩浆作用过程提供了有力的证据。在前人研究的基础上,笔者借助电子探针、扫描电镜、电镜能谱和二次飞行时间离子探针(Tof-SIMS)对产于铜陵地区微粒闪长质包体中的镁铁质团块进行了详细的研究,首次获得了一套精确的矿物化学资料和元素分布图,总结了镁铁质团块的特征,并讨论了本区的深部岩浆作用过程。矿物学研究表明,镁铁质团块中的角闪石和辉石均已发生了不同程度的透闪石化和阳起石化蚀变,蚀变过程中,从镁钙闪石到镁角闪石,再到透闪石,随着Si的增加,角闪石呈现出Mg的富集和Ti、Al贫化的特点。团块中的富Cr磁铁矿、Ti磁铁矿和少量的铝直闪石指示了其具有深源性。Tof-SIMS元素分布图显示,透闪石主要由Al、Si、Ca、Sc、V、Cr、Mn、Cu和Sr元素组成,透辉石主要由Si、Mg、Ca、Cu和Rb组成。在铜陵地区,上地幔部分熔融形成一套玄武岩浆,受岩浆底侵作用影响,玄武岩浆上侵,进入下地壳深位岩浆房,与下地壳硅镁层发生同化混染作用,形成一套轻度演化的中基性(辉长质)玄武岩浆,镁铁质团块就是这类中基性玄武岩浆直接结晶形成的。后受构造作用影响,这类中基性玄武岩浆上侵到中地壳岩浆房(12~16 km),与中地壳的变质岩系发生同化混染和结晶分异作用形成一套中性闪长质岩浆,微粒闪长质包体就是这套闪长质岩浆发生结晶分异作用而形成的。镁铁质团块和微粒闪长质包体清楚地解释了铜陵地区深部岩浆作用过程,并有力地证明了铜陵地区中地壳的闪长质岩浆来源于下地壳的壳幔混源岩浆。     

Hydrothermal alteration of kimberlite by convective flows of external water

Kimberlite volcanism involves the emplacement of olivine-rich volcaniclastic deposits into volcanic vents or pipes. Kimberlite deposits are typically pervasively serpentinised as a result of the reaction of olivine and water within a temperature range of 130–400 °C or less. We present a model for the influx of ground water into hot kimberlite deposits coupled with progressive cooling and serpentisation. Large-pressure gradients cause influx and heating of water within the pipe with horizontal convergent flow in the host rock and along pipe margins, and upward flow within the pipe centre. Complete serpentisation is predicted for wide ranges of permeability of the host rocks and kimberlite deposits. For typical pipe dimensions, cooling times are centuries to a few millennia. Excess volume of serpentine results in filling of pore spaces, eventually inhibiting fluid flow. Fresh olivine is preserved in lithofacies with initial low porosity, and at the base of the pipe where deeper-level host rocks have low permeability, and the pipe is narrower leading to faster cooling. These predictions are consistent with fresh olivine and serpentine distribution in the Diavik A418 kimberlite pipe, (NWT, Canada) and with features of kimberlites of the Yakutian province in Russia affected by influx of ground water brines. Fast reactions and increases in the volume of solid products compared to the reactants result in self-sealing and low water–rock ratios (estimated at <0.2). Such low water–rock ratios result in only small changes in stable isotope compositions; for example, δO¹⁸ is predicted only to change slightly from mantle values. The model supports alteration of kimberlites predominantly by interactions with external non-magmatic fluids.     

Volatile organic sulfur compounds as biomarkers complementary to methane: Infrared absorption spectroscopy of CH3SH enables insitu measurements on Earth and Mars

As universal products of biological processes, volatile organic sulfur compounds such as methyl mercaptan (CH₃SH) may be essential in the search for signs of life on Mars and in exoplanet atmospheres. Methyl mercaptan is implicated in the origin of life at sites of low-temperature hydrothermal activity driven by serpentinization. Serpentinization may occur on Mars, in icy satellite oceans, and in other small wet bodies to a greater extent than on Earth, with important implications for life. We characterized absorption features in pure laboratory sample spectra of CH₃SH using the Carbon Isotope Laser Spectrometer (CILS), an infrared $(3.27\mathrm{\mu }\mathrm{m})$ tunable diode laser spectrometer with capabilities nearly identical to those of the Tunable Laser Spectrometer (TLS) instrument on the Mars Science Laboratory. The molecular species proves detectable by CILS and TLS at the sensitivities approaching the level of parts per trillion with pre-concentration. These measurements demonstrate the possibility for detection of methyl mercaptan, with implications for its possible use as an in situ biosignature for Earth-based and extraterrestrial exploration.     

Ensemble properties of comets in the Sloan Digital Sky Survey

We present the ensemble properties of 31 comets (27 resolved and 4 unresolved) observed by the Sloan Digital Sky Survey (SDSS). This sample of comets represents about 1 comet per 10 million SDSS photometric objects. Five-band (u, g, r, i, z) photometry is used to determine the comets’ colors, sizes, surface brightness profiles, and rates of dust production in terms of the Afρ formalism. We find that the cumulative luminosity function for the Jupiter Family Comets in our sample is well fit by a power law of the form N(<H) ∝ 10^{(0.49±0.05)H} for H < 18, with evidence of a much shallower fit N(<H) ∝ 10^{(0.19±0.03)H} for the faint (14.5 < H < 18) comets. The resolved comets show an extremely narrow distribution of colors (0.57 ± 0.05 in g ? r for example), which are statistically indistinguishable from that of the Jupiter Trojans. Further, there is no evidence of correlation between color and physical, dynamical, or observational parameters for the observed comets.     

THUNDERSTORM CLIMATOLOGY BASED ON LIGHTNING DETECTOR DATA,MANITOBA, CANADA

Comparisons are made between thunderstorm data collected from a lightning detector network and from conventional climatic stations for the province of Manitoba, Canada. The greater resolution in time and space of lightning detector (direction finder) data makes it a valuable source of thunderstorm information and lends itself to some important applications. Data were collected for the forest fire season of 1985 using a network of 7 lightning direction finders distributed throughout the province. Some 67,912 cloud-to-ground lightning strikes were recorded by time and location during 122 thunderstorm days. July was the most active month with 27,260 strikes over 28 days. Two regions of the province had the greatest concentration of lightning strikes, indicating some influence by topography and position of large lakes. Case studies are presented of the most active lightning storms of 1985 and 1986. These storms are exclusively frontal storms, with most having similar synoptic weather patterns to those of large hailstorms and tornadoes in Manitoba. Relationships between meteorological parameters and lightning strike distribution are presented. These relationships may prove useful in the suppression of lightning-caused forest fires, especially in remote areas of the province. [Key words: lightning, thunderstorm, synoptic climatology, natural hazards, fire prevention.]