Characteristics of tin-streaming channels on Dartmoor,UK

The remnants of former tin-streaming channels on the North Teign River, Dartmoor have been investigated using techniques adopted from palaeohydrology, sedimentology, and environmental chemistry. the pattern of multiple streaming channels in the lower reaches, and a single channel in the upper reaches coincides with a reduction of potential stream power from 250 Wm⁻² at a drainage area of 8.7 km². the streaming sections were engineered to maximize the efficiency to separate cassiterite (SnO₂) from its gravel matrix, and the palaeohydraulic properties of channels suggests that sorting was most efficient for the sand and fine gravel size ranges. This was confirmed when the residual tin content of streaming-sediments was assessed. Residual levels of tin were found only in the silt fraction (<63 μm).     

Terrane sutures in the Maine Appalachians,USA and adjacent areas

Terrane sutures in the Maine Appalachians and adjacent areas are recognized as melange dominated, deformed accretionary prisms of Ordovician age, and as a broad synmetamorphic transcurrent fault zone of probable Late Silurian-Early Devonian age. Although the accretionary prisms are associated with present day aeromagnetic and Bouguer gravity anomalies, they are probably not associated with present day crustal penetrating boundaries. The geology of the accretionary prisms indicates subduction-obduction dominated regimes during which (1) the Gander and Boundary Mountain (Dunnage) terranes amalgamated and (2) the composite Boundary Mountain-Gander terrane accreted to the Laurentian margin. The Penobscottian orogeny produced and deformed the older of the two accretionary prisms. This accretionary prism indicates that the Penobscottian was a continuous or perhaps diachronous event which spanned the late Cambrian to early Late Ordovician. The younger accretionary prism was produced and deformed during the Taconian orogeny during late Middle to early Late Ordovician. Initial deformation of this accretionary prism may have overlapped the waning stages of the Penobscottian. Portions of the Taconian arc locally overlie the Penobscottian accretionary prism. A synmetamorphic fault zone lies within Precambrian(?) to Ordovician(?) bimodal metavolcanic and metapelitic rocks assigned here to the Avalon terrane. This zone is several kilometres wide and is interpreted to be the postsubduction suture between the Avalon and Gander terranes, and may, in part, represent a fossil transform fault system. The fault zone contains phyllonites as well as shear zones which generally record dextral motion. The phyllonites were previously interpreted as a stratigraphic unit, whereas the shear zones span or are contained within mappable compositional units. Formation of and movement along these phyllonites and shear zones ceased before the intrusion of Early Devonian plutons. Not all faults in south-western Maine are related to the suture. Younger dip and/or strike-slip and thrust faults are approximately parallel to, or may lie within, the older shear zones and they complicate the recognition of the older faults.     

Trace elements and polycyclic aromatic hydrocarbons (PAHs) concentrations in deep Gulf of Mexico sediments

The concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace elements were determined for surface (top 2 cm) sediment samples collected during the deep Gulf of Mexico benthos (DGoMB) study .These elements and compounds are known to be toxic to organisms at high concentrations and may affect biological communities. There is no indication of major anthropogenic input of the elements Be, Co, Cr, Fe, Si, Tl, V, K, Mg, Ca, Sr and Zn, based on normalization to Al. The concentrations of these metals in the sediment are a function of the relative amounts of trace-metal-rich Mississippi River-derived silicate material and trace-metal-poor plankton-derived carbonate. This is not true for the elements Ba, Ni, Pb, Cd, As, Cu and Mn, whose concentrations show considerable scatter when normalized to Al and a general enrichment. On a normalized basis, Mn is enriched 5–10 fold, Cu and Ni 2–3 fold and Pb 2 fold over Mississippi River-derived material. These enrichments are likely the result of remobilization of metals from depths in the sediment column where reducing conditions exist. The Ba concentrations at selected sites are higher than those of average clay-rich sediments, but are typical of sediments from near oil well platforms in the northern Gulf of Mexico. In the case of Ba, it seems likely that the enrichments, as high as a factor of 10, are due to disposal of oil well drilling mud. The Ba-enriched samples are from the three shallowest water sites in the Mississippi Trough (sites MT1, 2 and 3) and from site C1 and WC5. All are in an area of intense petroleum exploration and development. PAH concentrations are also elevated at MT1, MT3 and C1. The total PAH concentration ranged from not detected (ND) to 1033 ng/g with a mean of 140 ng/g. Even at the sites most enriched in PAHs and trace elements, the concentrations are not at the levels expected to adversely affect the biota. However, these predicted non-effects are based on research using mostly near-shore estuarine species, not on the indigenous species at the sampling sites.     

Guiding ecological principles for marine spatial planning

The declining health of marine ecosystems around the world is evidence that current piecemeal governance is inadequate to successfully support healthy coastal and ocean ecosystems and sustain human uses of the ocean. One proposed solution to this problem is ecosystem-based marine spatial planning (MSP), which is a process that informs the spatial distribution of activities in the ocean so that existing and emerging uses can be maintained, use conflicts reduced, and ecosystem health and services protected and sustained for future generations. Because a key goal of ecosystem-based MSP is to maintain the delivery of ecosystem services that humans want and need, it must be based on ecological principles that articulate the scientifically recognized attributes of healthy, functioning ecosystems. These principles should be incorporated into a decision-making framework with clearly defined targets for these ecological attributes. This paper identifies ecological principles for MSP based on a synthesis of previously suggested and/or operationalized principles, along with recommendations generated by a group of twenty ecologists and marine scientists with diverse backgrounds and perspectives on MSP. The proposed four main ecological principles to guide MSP—maintaining or restoring: native species diversity, habitat diversity and heterogeneity, key species, and connectivity—and two additional guidelines, the need to account for context and uncertainty, must be explicitly taken into account in the planning process. When applied in concert with social, economic, and governance principles, these ecological principles can inform the designation and siting of ocean uses and the management of activities in the ocean to maintain or restore healthy ecosystems, allow delivery of marine ecosystem services, and ensure sustainable economic and social benefits.     

Pyrolysis-high resolution gas chromatography and pyrolysis gas chromatography-mass spectrometry of kerogens and kerogen precursors

A series of kerogens and kerogen precursors isolated from DSDP samples, oil shales and Recent algal mats have been examined by Curie point pyrolysis-high resolution gas chromatography and gas chromatography-mass spectrometry. This study has shown that the three main types of kerogens (marine, terrestrial and mixtures of both) can be characterized using these techniques. The marine (algal) kerogens yield principally aliphatic products and the terrestrial kerogens yield more aromatic and phenolic products with some n-alkanes and n-alkenes. The yields of n-alkanes and n-alkenes increase and phenols decrease with increasing geologic age, however, pyrolysis-GC cannot be used to characterize the influence of short term diagenesis on the kerogen structure.     

The changing distribution of sex ratios in the british urban system

The preponderance of females in society has steadily decreased since the last war. This paper uses Metropolitan Economic Labour Areas to examine the differential effect of these changes and suggests associations with retirement migration and increasing female economic activity rates.     

Hawaiian glacial ages

Four glacial drifts that are interstratified with lava flows and tephra layers on the upper slopes of Mauna Kea demonstrate that an ice cap formed repeatedly at the summit of the volcano during the middle and late Pleistocene. The oldest drift (Pohakuloa Formation) probably was deposited shortly after eruption of a lava flow having a $\text{K}\text{Ar}$ age of 278,500 ± 68,500 yr. Drift of the Waihu Formation, marked by a belt of subdued end moraines, is correlated with hyaloclastite cones and associated lava flows that were erupted beneath an ice cap about 170,000–175,000 yr ago. One of four younger subglacially erupted lavas at the crest of the volcano has a $\text{K}\text{Ar}$ age of 41,300 ± 8300 yr. Tephra layers that antedate the last glaciation are about 29,700 to 37,200 ¹⁴C yr old and underlie dune sand that is believed to correlate with drift of the Makanaka Formation deposited during the last ice advance. The late Makanaka ice cap, which covered an area of about 70 km² and was as much as 100 m thick, is reconstructed from end moraines and limits of erratic stones that encircle the summit region. The ice cap disappeared from the summit before about 9080 yr ago. Postglacial lavas and tephra overlie the youngest drift on the upper south flank of the mountain and buried a widespread post-Makanaka soil on the lower south rift zone about 4500 ¹⁴C yr ago. The island of Hawaii is subsiding isostatically due to crustal loading by Quaternary volcanic rocks, with subsidence near the midpoint of Mauna Kea estimated as about 2.5 ± 0.5 mm/yr. A curve depicting an inferred long-term subsidence rate has been used to adjust equilibrium-line altitudes (ELAs) of former ice caps that are calculated on the basis of reconstructed glacier topography and an assumed accumulation-area ratio of 0.6 ± 0.05. The results indicate that ELA depression was greatest during Waihu glaciation, least during Pohakuloa glaciation, and that the ELA during late Makanaka glaciation was somewhat lower than that of the early Makanaka advance. Available radiometric dates show that late Makanaka glaciation correlates with stage 2 of the marine oxygen-isotope record, and suggest that early Makanaka, Waihu, and Pohakuloa glaciations correlate, respectively, with isotope stages 4, 6, and 8. Because ice caps could have formed on Mauna Kea only after the snowline was lowered many hundreds of meters below its inferred present level, episodes of Hawaiian glaciation probably were restricted to times of maximum ice volume on the continents. The asymmetry of the late Makanaka ice cap and the southeast-descending gradient of its equilibrium line are consistent with a southeast (tradewinds) source of precipitation during the last glaciation. Although departures of glacial-age temperature and precipitation from present values are difficult to assess quantitatively, growth of former ice caps on Mauna Kea most likely was due to enhanced winter snowfall and to reduced ablation rates brought about by lower air temperature and increased cloudiness.     

On the causes of 18O-depletion and 18O/16O homogenization during regional metamorphism; the East Humboldt Range core complex,Nevada

 Previous stable isotope studies at Lizzies Basin revealed that metasedimentary rocks are ¹⁸O-depleted relative to protolith values, particularly in the lower parts of the section (Lower Zone) where the rocks are also isotopically homogeneous on a scale of hundreds of meters (quartz δ¹⁸O=+9.0 to +9.6 per mil). In contrast, metasedimentary rocks at higher levels at Lizzies Basin (Upper Zone) are less ¹⁸O-depleted and more heterogeneous in δ¹⁸O. In order to understand more fully the isotopic evolution of this terrane, a series of detailed, meter-scale traverses across various metamorphic and igneous lithologies were completed at Lizzies Basin, and at the structurally higher Angel Lake locality. Traverses in the Lizzies Basin Lower Zone and in the lower parts of Angel Lake (Angel Lake Lower Sequence) across various silicate lithologies, including abundant granitoids, reveal similar degrees of homogeneity, although the average δ¹⁸O values are higher at Angel Lake. In contrast, traverses which include substantial thicknesses of marble and calc-silicate gneiss and very little granitoid have more heterogeneous quartz δ¹⁸O values (+11.9 to +13.4 per mil), and also have a higher average δ¹⁸O (+12.9 per mil), than observed elsewhere. The scale of ¹⁸O/¹⁶O homogeneity in quartz observed at Lizzies Basin and Angel Lake (meters to hundreds of meters) requires fluid-mediated isotope exchange, which accompanied Tertiary metamorphism. There is a correlation between the degree of ¹⁸O-depletion in metasedimentary rocks, ¹⁸O/¹⁶O homogenization between lithologies, and the proportion of granitoids (leucogranites in particular) within any part of the section, and a corresponding anticorrelation with the proportion of marble. This points to a causal relationship, whereby the leucogranites (as well as the Tertiary hornblende diorite and biotite monzogranite) acted as both a relatively low-¹⁸O reservoir and a source of fluids to enhance exchange, while the marbles hindered isotope depletion and homogenization by acting as relatively high-¹⁸O reservoirs and impermeable layers. Material balance calculations help delineate the plausible mechanisms of exchange between granitoids and metasediments. Single-pass infiltration of magmatic fluids from the granitoids is not capable of reproducing all of the observations. Fluid-mediated exchange by convective recirculation of magmatic fluids on a scale of meters is the mechanism which explains all of the observations. The generalized model for the isotopic evolution of the East Humboldt Range core complex provides an excellent opportunity to establish the main causes and controlling factors of ¹⁸O-depletion and ¹⁸O/¹⁶O homogenization during regional metamorphism. Received: 27 July 1993 / Accepted: 1 July 1994