Evidence from kimberlitic zircon for a decreasing mantle Th/U since the Archean

A decoupling in MORB of measured Th/U (κ = 2.5) from that calculated by Pb isotopes (κ = 3.8) for the depleted asthenosphere is well established, and has been referred to as the second Pb paradox (Kramers, J.D., and Tolstikhin, I.N., 1997. Two terrestrial lead isotope paradoxes, forward transport modelling, core formation and the history of the continental crust. Chem. Geol., 139, 75–110.) or the kappa conundrum (Elliott, T., Zindler, A., and Bourdon, B., 1999. Exploring the kappa conundrum: the role of recycling in the lead isotope evolution of the mantle. Earth Planet. Sci. Lett., 169, 129–145.). More controversial has been the cause and timing of this phenomenon, although a higher return flux of U⁶⁺ relative to Th⁴⁺ and(or) the recycling of crustal Pb into the mantle have become the preferred explanations of most workers. Such a combined mechanism effectively operating over the past 2.5 Ga was modelled in plumbotectonics (Zartman, R.E., and Haines, S., 1988. The plumbotectonics model for Pb isotopic systematics among major terrestrial reservoirs—a case for bi–directional transport. Geochim. Cosmochim. Acta, 52, 1327–1339. 709.33.), and found to be quantitatively feasible.A large TIMS, SIMS and LA-ICPMS database of Th and U concentrations for kimberlite-hosted zircon, particularly from Cr-poor megacrystic suites, now exists (Kinny et al., 1989, Berryman et al., 1999, Griffin et al., 2000 and Spetsius et al., 2002; Appendix A and Appendix B, this work). Six suites comprising 10 or more zircon grains with ages between 90 and 2550 Ma reveal consistent patterns when plotted on Th/U vs. U diagrams. We interpret these patterns as resulting from fractional crystallization of a melt with kimberlite affinity presumably derived from the asthenosphere, permitting the extrapolation to an initial Th/U at the time zircon crystallization began. A two-fold decrease is seen in this ratio over the past 2.5 Ga, suggesting that during this time a similar change has occurred in the parent silicate melt. Estimates of Th and U distribution coefficients between zircon and coexisting melt permit calculation of Th/U in the melt, which, for these highly incompatible elements, presumably is the same as for its mantle source rock. Kimberlitic zircon may thus indeed give evidence of a reduction in κ, tentatively calculated as from 4 to 2, since the Archean for the depleted asthenosphere.     

Combining dissolved, suspended and bed load stream geochemistry to explore for volcanic massive sulfide deposits: Big Salmon Complex, northern British Columbia

Exploration successes for volcanogenic massive sulfide (VMS) deposits, such as Kudz Ze Kayah, Wolverine and Fyre Lake in the Yukon–Tanana Terrane and Slide Mountain Terrane (southern Yukon Territory) have spurred interest in the correlative rocks in the Big Salmon Complex in northern British Columbia. In an effort to further the utility of multi-media stream geochemistry in exploration frontiers that are forested, heavily drift covered, or buried, the primary streams of 19 watersheds from the East Teslin Lake (National Topographic System (NTS): 104N/9, 16) and Teh Creek areas (NTS: 104O/11, 12, 13, 14) of the Big Salmon Complex were analyzed for Cu, Pb, and Zn and other parameters in the dissolved load, suspended load and bed load. Traditionally, exploration based on stream geochemistry has employed the bed load and more recently the dissolved load chemistry, but almost never the suspended load despite strong differences in the geochemical signatures of the three media. Here, we document that copper, lead, and zinc partition into the dissolved, suspended, and bed loads differently and that the magnitude of anomalies is different for each media. The adsorbing capacity of the suspended load may make it a more sensitive indicator of mineral deposits on a regional basis than either the trace-element-poor dissolved load or the bulk-rock-diluted bed load which are likely better indicators of local mineralization. It is clear that each phase contributes unique information about the distribution of elements in the watershed that could be considered in exploration models.We also show that summing standardized element concentrations and summing the sums across media appears to be an effective method to reduce the data without loss of important information. We likewise investigated the utility of calculating major element normalized enrichments for exploration and find that it is a promising approach.     

Petrology of spinel lherzolite xenoliths from Youkou volcano,Adamawa Massif,Cameroon Volcanic Line: mineralogical and geochemical fingerprints of sub-rift mantle processes

The basaltic maar of Youkou, situated in the Adamawa Volcanic Massif in the eastern branch of the continental segment of the Cameroon Volcanic Line, contains mantle-derived xenoliths of various types in pyroclastites. Spinel-bearing lherzolite xenoliths from the Youkou volcano generally exhibit protogranular textures with olivine (Fo_89.4?90.5), enstatite (En_89???91Fs_8.7?9.8Wo_0.82?1.13), clinopyroxene, spinel (Cr#_Sp?=?9.4–13.8), and in some cases amphibole (Mg_#?=?88.5–89.1). Mineral equilibration temperatures in the lherzolite xenoliths have been estimated from three–two pyroxene thermometers and range between 835 and 937 °C at pressures of 10–18 kbar, consistent with shallow mantle depths of around 32–58 km. Trends displayed by bulk-rock MgO correlate with Al₂O₃, indicating that the xenoliths are refractory mantle residues after partial melting. The degree of partial melting estimated from spinel compositions is less than 10%: evidences for much higher degrees of depletion are preserved in one sample, but overprinted by refertilization in others. Trace element compositions of the xenoliths are enriched in highly incompatible elements (LREE, Sr, Ba, and U), indicating that the spinel lherzolites underwent later cryptic metasomatic enrichment induced by plume-related hydrous silicate melts. The extreme fertility (Al₂O₃?=?6.07–6.56 wt% in clinopyroxene) and the low CaO/Al₂O₃ ratios in the spinel lherzolites suggest that they could not be a simple residue of partial melting of primitive mantle and must have experienced refertilization processes driven by the infiltration of carbonatite or carbonated silicate melts.     

Estimation of strong ground motions from hypothetical earthquakes on the Cascadia subduction zone,Pacific Northwest

Strong ground motions are estimated for the Pacific Northwest assuming that large shallow earthquakes, similar to those experienced in southern Chile, southwestern Japan, and Colombia, may also occur on the Cascadia subduction zone. Fifty-six strong motion recordings for twenty-five subduction earthquakes ofM _s7.0 are used to estimate the response spectra that may result from earthquakesM _w<81/4. Large variations in observed ground motion levels are noted for a given site distance and earthquake magnitude. When compared with motions that have been observed in the western United States, large subduction zone earthquakes produce relatively large ground motions at surprisingly large distances. An earthquake similar to the 22 May 1960 Chilean earthquake (M _w 9.5) is the largest event that is considered to be plausible for the Cascadia subduction zone. This event has a moment which is two orders of magnitude larger than the largest earthquake for which we have strong motion records. The empirical Green's function technique is used to synthesize strong ground motions for such giant earthquakes. Observed teleseismicP-waveforms from giant earthquakes are also modeled using the empirical Green's function technique in order to constrain model parameters. The teleseismic modeling in the period range of 1.0 to 50 sec strongly suggests that fewer Green's functions should be randomly summed than is required to match the long-period moments of giant earthquakes. It appears that a large portion of the moment associated with giant earthquakes occurs at very long periods that are outside the frequency band of interest for strong ground motions. Nevertheless, the occurrence of a giant earthquake in the Pacific Northwest may produce quite strong shaking over a very large region.     

Evolution of the Miocene Tejeda magmatic system,Gran Canaria,Canary Islands

This paper is a companion to Clark (1988; hereafter Part I) which described the evolution of the Tejeda Magmatic System (TMS), a Miocene caldera complex, Gran Canaria, Spain, based on geochronologic, paleomagnetic and field data. In this study, petrochemical data are used to corroborate the history out-lined in Part I. Geochemical discriminant analysis shows that whereas the Extra-Caldera (EC) Mogan/Fataga volcanics are separated by a composition gap, no composition gap exists within the Intra-Caldera (IC) sequence. IC ignimbrites change rapidly but progressively from pantellerites and comendites to comenditic trachytes and finally to trachytes in a 0.47 Ma time interval. Significantly, the lower pantelleritic part of the IC series is similar to the EC pantellerites (units B, C and D) as expected based on results from Part I. The appearance of a compositional gap in the EC sequence is the result of flows having been trapped within the caldera during the 0.47 Ma Mogan-Fataga transition interval. The transitional IC sequence may be geochemically modelled by mixing of Mogan comendites and Fataga trachytes. The mixing was most probably induced by the high discharge of magma from the compositionally-zoned Tejeda magma body. The rate of change in erupted composition is best explained by imagining a continuous influx of Fataga or parental Fataga magma into a chamber whose previous silicic component (Mogan composition) was no longer being replenished and that the two magmas did not convectively mix prior to eruption. Repose times between successive eruptions in the lower to middle Mogan (from P1/T1 to A) were of order 30 000 a; the upper Mogan pantellerites and comendites/comenditic trachytes (B to F?) erupted once every 125 000 years or so. The longer repose time for the upper units is consistent with their more differentiated character.     

Chandra smells a RRAT

“Rotating RAdio Transients” (RRATs) are a newly discovered astronomical phenomenon, characterised by occasional brief radio bursts, with average intervals between bursts ranging from minutes to hours. The burst spacings allow identification of periodicities, which fall in the range 0.4 to 7 seconds. The RRATs thus seem to be rotating neutron stars, albeit with properties very different from the rest of the population. We here present the serendipitous detection with the Chandra X-ray Observatory of a bright point-like X-ray source coincident with one of the RRATs. We discuss the temporal and spectral properties of this X-ray emission, consider counterparts in other wavebands, and interpret these results in the context of possible explanations for the RRAT population. B.M.G. acknowledges the support of NASA through LTSA grant NAG5-13023 and of an Alfred P. Sloan Fellowship.