Antarctic circumpolar modes in a coupled ocean–atmosphere model

Eastward-propagating patterns in anomalous potential temperature and salinity of the Southern Ocean are analyzed in the output of a 1000-year simulation of the global coupled atmosphere–ocean GCM ECHO-G. Such features can be associated with the so-called Antarctic Circumpolar Wave (ACW). It is found that time–longitude diagrams that have traditionally been used to aid the visualization of the ACW are strongly influenced by the width of the bandpass time filtering. This is due to the masking of considerable low-frequency variability that occurs over a broad range of time scales. Frequency–wavenumber analysis of the ACW shows that the eastward-propagating waves do have preferred spectral peaks, but that both the period and wavenumber change erratically when comparing different centuries throughout the simulation. The variability of the ACW on a variety of time scales from interannual to centennial suggests that the waiting time for a sufficient observational record to determine the time scale of variability of the real world ACW (and the associated decadal time scale predictability of climate for southern landmasses) will be a very long one.Responsible Editor: Dirk Olbers     

Domestic and industrial water uses of the past 60 years as a mirror of socio-economic development: A global simulation study

To enhance global water use assessment, the WaterGAP3 model was improved for back-calculating domestic, manufacturing and thermoelectric water uses until 1950 for 177 countries. Model simulations were carried-out on a national scale to estimate water withdrawals and consumption as well as cooling water required for industrial processes and electricity production. Additionally, the amount of treated and untreated wastewater as generated by the domestic and manufacturing sectors was modeled. In the view of data availability, model simulations are based on key socio-economic driving forces and thermal electricity production. Technological change rates were derived from statistical records in order to consider developments in water use efficiency, which turned out to have a crucial role in water use dynamics. Simulated domestic and industrial water uses increased from ca. 300 km³ in 1950 to 1345 km³ in 2010, 12% of which were consumed and 88% of which were discharged back into freshwater bodies. The amount of domestic and manufacturing wastewater increased considerably over the last decade, but only half of it was untreated. The downscaling of the untreated wastewater volume to river basin scale indicates a matter of concern in East and Southeast Asia, Northern Africa, and Eastern and Southern Europe. In order to reach the Millennium Development Goals, securing water supply and the reduction of untreated wastewater discharges should be amongst the priority actions to be undertaken. Population growth and increased prosperity have led to increasing water demands. However, societal and political transformation processes as well as policy regulations resulting in new water-saving technologies and improvements counteract this development by slowing down and even reducing global domestic and industrial water uses.     

Influence of hardpan layers on arsenic mobility in historical gold mine tailings

Hardpans, or cemented layers, form by precipitation and cementation of secondary minerals in mine tailings and may act as both physical and chemical barriers. Precipitation of secondary minerals during weathering of tailings can sequester metal(loid)s, thereby limiting their release to the environment. At Montague Gold Mines in Nova Scotia, tailings are partially cemented by the Fe arsenate mineral scorodite (FeAsO₄·2H₂O). Previous studies have shown that the formation of scorodite can effectively limit aqueous As concentrations due to its relatively low solubility (<1 mg/L at pH 3–4) and high As content (43–52 wt.% As₂O₅, this study). Co-existing waters and solids were sampled at Montague Gold Mines to identify present-day field conditions influencing scorodite precipitation and dissolution, and to better understand the mineralogical and chemical relationship between hardpan and tailings. In addition to scorodite, hardpan cements were found to include amorphous Fe arsenate and Fe oxyhydroxide. Nearly all hardpan is associated with historical arsenopyrite-bearing concentrate which provides a source of acidity, As⁵⁺ and Fe³⁺ for secondary mineral precipitation. Pore waters sampled from the hardpan have pH values ranging from 2.43 to 7.06. Waters with the lowest pH values also have the highest As concentrations (up to 35.8 mg/L) and are associated with the most extensive hardpan and greatest amount of weathered sulfide. Samples from areas with discontinuous hardpan and less sulfide have near-neutral pH and lower As concentrations. Detailed petrographic observations indicate that the identity and stability of As-bearing secondary minerals depends on the continued availability of sulfide concentrate. The results of this study are being used to develop remediation strategies for highly weathered, hardpan-bearing tailings that consider the stability of both primary and secondary minerals under various cover scenarios.     

Influences of upwelling and downwelling winds on red tide bloom dynamics in Monterey Bay,California

It has recently been shown that inner shelf waters of NE Monterey Bay, California function as an “extreme bloom incubator”, frequently developing dense “red tide” blooms that can rapidly spread. Located within the California Current upwelling system, this open bay is strongly influenced by oceanographic dynamics resulting from cycles of upwelling favorable winds and their relaxation and/or reversal. Different wind forcing causes influx of different water types that originate outside the bay: cold nutrient-rich waters during upwelling and warm nutrient-poor waters during relaxation. In this study, we examine how the bay's bloom incubation area can interact with highly variable circulation to cause red tide spreading, dispersal and retention. This examination of processes is supported by satellite, airborne and in situ observations of a major dinoflagellate bloom during August and September of 2004. Remote sensing of high spatial, temporal and spectral resolution shows that the bloom originated in the NE bay, where it was highly concentrated in a narrow band along a thermal front. Upwelling circulation rapidly spread part of the bloom, mixing cool waters of an upwelling filament with warm bloom source waters as they spread. Vertical migration of the dinoflagellate populations was mapped by autonomous underwater vehicle surveys through the spreading bloom. Following bloom expansion, a two-day wind reversal forced intrusion of warm offshore waters that dispersed much of the bloom. Upwelling winds then resumed, and the bloom was further dispersed by an influx of cold water. Throughout these oceanographic responses to changing winds, an intense bloom persisted in sheltered waters of the NE bay, where extreme blooms are most frequent and intense. Microscopic examination of surface phytoplankton samples from the central bay showed that spreading of the bloom from the NE bay and mixing with regional water masses resulted in significantly increased abundance of dinoflagellates and decreased abundance of diatoms. Similar dinoflagellate bloom incubation sites are indicated in other areas of the California Current system and other coastal upwelling systems. Through frequent bloom development and along-coast transports, relatively small incubation sites may significantly influence larger regions of the coastal marine ecosystems in which they reside.     

Rhyolites at Kerlingarfjöll, Iceland: the evolution and lifespan of silicic central volcanoes

Kerlingarfjöll central volcano is Iceland’s second largest outcrop of Quaternary rhyolite and is part of the Icelandic Western Rift Zone. Geochemical and Ar/Ar age data show that at least 21 different rhyolite eruptions have taken place at Kerlingarfjöll over the last 350 ka. Ar/Ar dating was carried out on samples of obsidian which showed variable reproducibility, illustrating the difficulty in dating young Icelandic volcanics. Nevertheless, reasonable estimates of eruption age have been derived for a number of eruptive units that are consistent with observed stratigraphy, enabling an understanding of the temporal evolution of Kerlingarfjöll. Two rhyolite magma types are present. The first is an older, low-Nb rhyolite that was erupted episodically along a cryptic curved fracture system, to form a discontinuous ring of rhyolite mountains, between 350 and 250 ka. This discontinuous ring is similar to structures observed at other volcanoes in Iceland, suggesting that the development of a curved fracture that acts as a pathway for episodic silicic eruptions is a feature of central volcano development. The second magma is a younger, high-Nb rhyolite that was erupted episodically between 250 and 68 ka in the northern part of Kerlingarfjöll, forming two clusters, both of which have areas of intense hydrothermal activity. Repose periods for rhyolite volcanism are thought to be on the order of tens of thousands of years, and it is possible that Kerlingarfjöll will erupt rhyolite again in the future.     

Shell Middens,Cultural Chronologies,and Coastal Settlement on the Rhode River Sub‐Estuary of Chesapeake Bay,Maryland, USA

North America's Atlantic Coast has been a focus of human settlement and subsistence for millennia, but sea‐level rise, sedimentation, and other processes pose significant challenges for archaeological research. Radiocarbon dating of 31 shell middens near the Rhode River Estuary, Maryland provides an opportunity to evaluate human land use, settlement, and cultural chronologies on the Chesapeake Bay. Sixty calibrated radiocarbon dates on eastern oyster (Crassostrea virginica) shell and charcoal demonstrate that Native Americans, colonial, and historic peoples harvested oysters and other shellfish from at least 3200 years ago through the 19th century. The number of dated sites increases during the Late Woodland period after about 1000 cal yr B.P., a factor probably related to greater site visibility and preservation, as well as increased human exploitation of the watershed. Accumulation rates for five of the shell middens provide preliminary indications that some of the sites accumulated rapidly suggesting, along with other evidence, that many of the region's shell middens were logistical or perhaps seasonal camps. Our study demonstrates the importance of regional watershed surveys and radiocarbon dating programs to help build and refine cultural chronologies in coastal regions threatened by sea‐level rise and other processes.     

Deriving snow‐cover depletion curves for different spatial scales from remote sensing and snow telemetry data

During the melting of a snowpack, snow water equivalent (SWE) can be correlated to snow‐covered area (SCA) once snow‐free areas appear, which is when SCA begins to decrease below 100%. This amount of SWE is called the threshold SWE. Daily SWE data from snow telemetry stations were related to SCA derived from moderate‐resolution imaging spectroradiometer images to produce snow‐cover depletion curves. The snow depletion curves were created for an 80 000 km² domain across southern Wyoming and northern Colorado encompassing 54 snow telemetry stations. Eight yearly snow depletion curves were compared, and it is shown that the slope of each is a function of the amount of snow received. Snow‐cover depletion curves were also derived for all the individual stations, for which the threshold SWE could be estimated from peak SWE and the topography around each station. A station's peak SWE was much more important than the main topographic variables that included location, elevation, slope, and modelled clear sky solar radiation. The threshold SWE mostly illustrated inter‐annual consistency. Copyright © 2015 John Wiley & Sons, Ltd.     

A structural phase-transition in K(Mg1−xCux)F3 perovskite

A complete solid-solution series between cubic (Pm 3 m) KMgF₃ and tetragonal (I4/mcm) KCuF₃ was synthesized at 730–735 °C in an inert atmosphere. X-ray powder-diffraction at room temperature shows that the transition between the cubic and tetragonal perovskite structures in the series K (Mg_1?xCu_x) F₃ occurs at x ～ 0.6. Rietveld structure-refinements were done for selected compositions. In the cubic phase, all parameters are linear with composition up to the transition point. At the transition point, there is a strong discontinuity in the cell volume; this is strongly anisotropic with expansion along the a axes and contraction along the c axis due to a pronounced axial elongation of the (Mg, Cu) F₆ octahedron that increases with increasing Cu content. The phase transition is first-order, with a discontinuity of ≈2% in the symmetry-breaking strain at x_C. It is proposed that the phase transition in K (Mg, Cu) F₃ is due to the onset of the cooperative Jahn-Teller effect. Compositional relationships for lattice vibrations in this solid solution were established using thin-film infrared spectroscopy. A phase transition occurring above 60 mole % KCuF₃ is indicated by the appearance of one of the two modes expected for the tetragonal phase; the weaker mode is not resolved below 80 mole % KCuF₃. Modes common to both structures vary smoothly and continuously across the binary; however, frequencies do not depend linearly on composition, nor is mode-softening discernable. Two-mode behaviour is observed only for the bending motion of the cubic phase, because this peak alone has non-overlapping end-member components.     

Export Production in the Subarctic North Pacific over the Last 800 kyrs: No Evidence for Iron Fertilization?

The subarctic North Pacific is a high nitrate-low chlorophyll (HNLC) region, where phytoplankton growth rates, especially those of diatoms, are enhanced when micronutrient Fe is added. Accordingly, it has been suggested that glacial Fe-laden dust might have increased primary production in this region. This paper reviews published palaeoceanographic records of export production over the last 800 kyrs from the open North Pacific (north of ∼35°N). We find different patterns of export production change over time in the various domains of the North Pacific (NW and NE subarctic gyres, the marginal seas and the transition zone). However, there is no compelling evidence for an overall increase in productivity during glacials in the subarctic region, challenging the paradigm that dust-born Fe fertilization of this region has contributed to the glacial draw down of atmospheric CO₂. Potential reasons for the lack of increased glacial export production include the possibility that Fe-fertilization rapidly drives the ecosystem towards limitation by another nutrient. This effect would have been exacerbated by an even more stable mixed layer compared to today. This revised version was published online in July 2006 with corrections to the Cover Date.     

Sources of uncertainty in estimating stream solute export from headwater catchments at three sites

Uncertainty in the estimation of hydrologic export of solutes has never been fully evaluated at the scale of a small‐watershed ecosystem. We used data from the Gomadansan Experimental Forest, Japan, Hubbard Brook Experimental Forest, USA, and Coweeta Hydrologic Laboratory, USA, to evaluate many sources of uncertainty, including the precision and accuracy of measurements, selection of models, and spatial and temporal variation. Uncertainty in the analysis of stream chemistry samples was generally small but could be large in relative terms for solutes near detection limits, as is common for ammonium and phosphate in forested catchments. Instantaneous flow deviated from the theoretical curve relating height to discharge by up to 10% at Hubbard Brook, but the resulting corrections to the theoretical curve generally amounted to <0.5% of annual flows. Calibrations were limited to low flows; uncertainties at high flows were not evaluated because of the difficulties in performing calibrations during events. However, high flows likely contribute more uncertainty to annual flows because of the greater volume of water that is exported during these events. Uncertainty in catchment area was as much as 5%, based on a comparison of digital elevation maps with ground surveys. Three different interpolation methods are used at the three sites to combine periodic chemistry samples with streamflow to calculate fluxes. The three methods differed by <5% in annual export calculations for calcium, but up to 12% for nitrate exports, when applied to a stream at Hubbard Brook for 1997–2008; nitrate has higher weekly variation at this site. Natural variation was larger than most other sources of uncertainty. Specifically, coefficients of variation across streams or across years, within site, for runoff and weighted annual concentrations of calcium, magnesium, potassium, sodium, sulphate, chloride, and silicate ranged from 5 to 50% and were even higher for nitrate. Uncertainty analysis can be used to guide efforts to improve confidence in estimated stream fluxes and also to optimize design of monitoring programmes. © 2014 The Authors. Hydrological Processes published John Wiley & Sons, Ltd.