The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)

This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percentage was 88 ± 9%. The detection limit (LOD) of analytical procedure was less than 0.2 μg/kg d.w. for all analytes. The quantification limit (LOQ) of analytical procedure was less than 0.7 μg/kg d.w.The resulting distributions and weight ratios of specific compounds are discussed in terms of sampling location and origin of organic matter. A comparison with other studies of total PAHs suggests that the levels are within the concentration ranges already reported by other authors. From an eco-toxicological point of view, total PAH concentrations at seven out of the eight sites studied represent a relatively clean environment when compared to other sites.Organic matter content and PAH concentrations were found to be correlated and the compounds present in Stagnone sediments were shown to be mainly of pyrolitic origin, while a negligible quantity of PAHs may derive from biogenic sources since all the sediments contain perylene traces. There is no evidence of coal-tar contamination.Cluster analysis was carried out in order to discriminate between different PAH origins.     

On the stability of equivalent modons

In the framework of the equivalent barotropic dynamics, we show that the kinetic energy and enstrophy a small scale perturbation superimposed on a large scale solitary wave do not grow in time as long as the perturbation scale remains much less than that of the wave. This property is proved to hold for the equivalent modons of Flierl et al. which therefore turn out to be resistant to small scale perturbations. These conclusions appear to explain the numerical results of McWilliams et al. on non divergent modons.     

The effects of mechanical forcing on the mean meridional circulation and transfer properties of the atmosphere

Experiments using a quasi-geostrophic model and the ECMWF T21 spectral model with and without orography are performed to investigate the effects of mechanical forcing on the mean meridional circulation. Results show that mechanical forcing intensifies the horizontal poleward heat flux and redistributes the eddy angular momentum in the vertical, and that this changes significantly the intensity and location of the mean me-ridional circulation centres.It is shown how the mean meridional circulation is set up in such a way to satisfy both the dynamical and thermodynamical transport requirements of the model atmosphere. Whenever external forcing changes the eddy fluxes, the Coriolis torques from the upper horizontal branches of the mean meridional circulations change to balance the extra divergence of eddy momentum flux, and additional adiabatic heating is produced by the vertical branches of the toroids to balance the extra divergence of eddy heat flux. The mean meridional circula-tion is, therefore, confirmed to be very sensitive to mechanical forcing, and can be used as an efficient tool to quantitatively diagnose the adequacy of the orographic representation of numerical forecasting and general cir-culation models.     

Response of a harbour opened to a sea of variable depth

Wave-induced oscillations in a circular harbour with protruding breakwaters and narrow mouth are analytically investigated by using a variational method. The effects of the bottom topography of the contiguous external sea are studied, especially as far as Helmholtz resonance is concerned; it has been found that the amplitude of the resonance peak is quite sensitive to the depth variation, while the related resonance wavenumber is more stable.     

Tsunami trapping near circular islands

Trapping of long water waves that are induced by submarine earthquakes and that attack circular islands is studied by applying a theoretical model (Tinti andVannini, 1994) that is based on the linear shallow water approximation. The solution is computed as the superposition of the eigenmodes of the water basin. The tsunami trapping is seen in terms of the capability of the source to excite the trapped eigenmodes of the basin. The bottom depth dependence around the island is shown to be quite important in determining the trapping capability of the island: a depth profile that is downwardly concave as the distance from the island coasts increases is substantially more efficient in amplifying the incoming waves and in trapping their energy than a profile exhibiting an upward concavity.     

Suspended sediment transport analysis in two Italian instrumented catchments

Suspended sediment transport in streams is an effective indicator of soil erosion at the watershed scale. This process was studied using the data obtained from two continuous monitoring stations installed in Italian watersheds, the Rio Cordon and Torrente Carapelle. The catchments have substantially different climatic, morphological and land use characteristics. The Rio Cordon, a small Alpine watershed, has been monitored since 1986, while in the Torrente Carapelle, a medium-size Mediterranean watershed, the monitoring station has provided data since 2007. Several flood events with suspended sediment transport were isolated in the two catchments, excluding those determined by snowmelt in the Rio Cordon as this process does not affect the Carapelle watershed. Analysis of the events showed different behavior in terms of hysteresis loop trends between water discharge (m³ s^-1) and suspended sediment concentration (g l^-1) values, as the Rio Cordon confirms clockwise relationships most frequently, while counter-clockwise trends represent the majority of cases for the Carapelle Torrent. The different behavior of the two watersheds was further analyzed by evaluating relationships between the main hydrological parameters related to suspended sediment transport. Runoff controls the total sediment budget in both catchments. In contrast, it was noted that the runoff process does not interfere in the magnitude of the suspended sediment transport in the Rio Cordon catchment, while variations due to the larger size of the catchment area characterize the events in the Carapelle watershed. Lastly, a flow peak threshold that determines the advance or delay of the hydrograph peak with respect to the sedigraph peak was established for the Carapelle Torrent, while it was not reported in the Rio Cordon.     

Early detection of volcanic hazard by lidar measurement of carbon dioxide

Volcanic gases give information on magmatic processes. In particular, anomalous releases of carbon dioxide precede volcanic eruptions. Up to now, this gas has been measured in volcanic plumes with conventional measurements that imply the severe risks of local sampling and can last many hours. For these reasons and for the great advantages of laser sensing, the thorough development of volcanic lidars has been undertaken at ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development). In fact, lidar profiling allows one to scan remotely volcanic plumes in a fast and continuous way, and with high spatial and temporal resolution. A differential absorption lidar instrument will be presented in this paper: BILLI (BrIdge voLcanic LIdar). It is based on injection-seeded Nd:YAG laser, double-grating dye laser, difference frequency mixing and optical parametric amplifier. BILLI is funded by the ERC (European Research Council) project BRIDGE (BRIDging the gap between Gas Emissions and geophysical observations at active volcanos). It scanned the gas emitted by Pozzuoli Solfatara (Naples, Italy) and Stromboli Volcano (Sicily, Italy) during field campaigns carried out from October 13 to 17, 2014, and from June 24 to 29, 2015, respectively. Carbon dioxide concentration maps were retrieved remotely in few minutes in the crater areas. To our knowledge, it is the first time that carbon dioxide in a volcanic plume is retrieved by lidar. This result represents the first direct measurement of this kind ever performed on active volcanos and shows the high potential of laser remote sensing in early detection of volcanic hazard.