How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.     

Eliminierung und Rückgewinnung von Metallionen aus Abwässern — eine Übersicht

The present state and the trends of the recovery of heavy metals from wastewaters are presented. The classical precipitation techniques are insatisfactory due to increases of solubility in the presence of impurity ions and/or complexing agents. At present, ion-exchange processes constitute the most frequently used method of metal recycling with an effective enrichment of metal ions. For the effective separation of metals from solutions of a low concentration the electrolytic reduction demands large electrode surface areas. In cells with fixed-bed or fluidized cathodes one can obtain specific electrode surface areas of some 10³ m²/m^m3. For the future, processes of extraction and especially membrane separation will gain in importance. In the past few years, a large number of highly selective metal extracting agents as well as the liquid membrane permeation with suitable carriers were developed. Combinations of membrane separation processes with chemical reactions may attain the same importance, as e.g. ultrafiltration in connection with the fixation of metal ions to watersoluble polymers. In the long run, especially techniques will prevail which will not only result in metal enrichment but also in the recovery of the raw material water.     

Samarium-neodymium data on two late Proterozoic ophiolites of Saudi Arabia and implications for crustal and mantle evolution

Whole-rock and mineral samples from the Jabal al Wask and Jabal Ess ophiolites, northwestern Saudi Arabia, yield Sm-Nd isochron ages of 743+24 Ma and 782±38 Ma, respectively. These formation ages, which provide maximum limits for possible obduction ages, are in broad but not precise agreement with the previously known geologic history of the Arabian Shield. They indicate that the ophiolitic rocks are roughly coeval with nearby volcanic and plutonic rocks, supporting a back-arc origin for the two ophiolites. We suggest that the Jabal al Wask and Jabal Ess ophiolites were parts of the same northeast-southwest trending ophiolite belt, now offset along the Najd fault system. Initial _Nd values range from +6.6 to+ 7.6, indicating derivation from a mantle source that has been LIL-depleted for at least 2 Ga. Reported _Nd values from the Arabian Shield that are lower than this suggest the presence of older, reworked continental crust.     

Response of rigid body assemblies to dynamic excitation

Shaking table tests were conducted to investigate the response of rectangular wooden blocks and block assemblies of various sizes and slenderness to harmonic and earthquake base excitation. The shaking tests were followed by an analytical and a numerical study of response of single blocks and block assemblies. The analytical study was aimed at establishing criteria for the initiation of rocking and of overturning in response to harmonic base motion and consisted of solving numerically the differential equations of motion of a rigid block on a rigid foundation. The numerical study, in the course of which the response of both single blocks and block assemblies was examined, was implemented by means of the Distinct Element Method (DEM). Prior to the DE simulation of actual shaking tests, preliminary analyses were conducted to confirm numerical stability and to evaluate material and damping parameters. Comparing the recorded time histories with those given by the analytical study and the DE simulation, good agreement was found. The distinct element model in use appeared to follow the highly non-linear motion of rigid body assemblies faithfully to reality. On the basis of the results, provided that the necessary parameters are carefully estimated, the employed DE model can be regarded as an appropriate tool to simulate response of rigid body assemblies to dynamic base excitation.     

Measurements of Powder Snow Avalanches- Laboratory -

Laboratory simulation of powder snow avalanches serves for the validation of numerical models and as a tool in its own right for consulting and research purposes. Two-phase gravity currents are simulated in water with quartz powder or glass spheres as the particle phase. Particle-phase velocity profiles and particle-phase volume fraction profiles are measured with an ultrasonic device. The experimental setup and the current state of the measurement technique are described and preliminary results are presented.     

Winter precipitation variability and large-scale circulation patterns in Romania

Summary The spatial and temporal variability of winter precipitation and its links to the large-scale atmospheric circulation patterns in Romania are examined. The data set is composed of observed rainfall at 30 meteorological stations during the 1961–1996 period. The large-scale field is represented by the observed geopotential height at 500 hPa (Z500) over the same period, covering the latitudinal belt between 20° N–90° N (resolution 2.5°×2.5°).The Standard Normal Homogeneity Test (SNHT) is applied to detect inhomogeneities in the data, and the Mann-Kendall and Pettitt non-parametric tests are used in order to identify trends and change points in the winter precipitation time series. The empirical orthogonal functions (EOF) technique is used for data reduction in order to highlight the basic patterns of rainfall variability in Romania. The covariance map between precipitation EOF time series (PCs) and the Z500 field, as well as the correlation coefficients between the PCs and circulation indices are calculated in order to identify the influence of large-scale circulation patterns on winter precipitation in Romania.A significant decreasing trend is identified in winter precipitation with a downward shift in winter 1969/1970, most significant from a statistical point of view in the extra-Carpathian region. This change seems to be real since the SNHT test does not reveal any inhomogeneity during the period tested. Significant relationships are found between winter precipitation variability in Romania and the large-scale circulation pattern, such as the North Atlantic Oscillation and the blocking phenomenon in the Atlantic-European sector. The positive phase of the NAO and the reduction in blocking activity could be one of the causes of the decrease in winter precipitation in Romania.     

Effect of rod friction on vane shear tests in very soft organic harbour mud

Very soft organic harbour mud is increasingly used as a filling and construction material in harbour construction and reorganization. The undrained shear strength of such soft sediments is the critical geotechnical soil parameter with regard to any specific construction design. Field and laboratory vane shear testing is a standard method to quickly determine this important parameter. So far, the effect of rod friction on vane shear tests in very soft organic soils is unclear. In this study we present results from laboratory experiments on harbour mud from a construction site in northern Germany. Relations among vane and rod geometry, penetration depth, water content, rod friction and undrained shear strength are derived. Based on these relations the influence of rod friction on vane shear test results is investigated. The results indicate that field and laboratory vane shear test measurements may be significantly influenced by rod friction. Methods are proposed to correct for the rod influence, which is shown to increase with rising water contents.