The cosmic‐ray exposure history of the Twannberg iron meteorite (IIG)

The Twannberg iron meteorite is one out of only six members of the group IIG. The combined noble gas and radionuclide data obtained in this new systematic study indicate that Twannberg with its ~570 recently recovered specimens was a large object with a preatmospheric radius in the range of ~2 m, which corresponds to ~250 × 10³ kg. The cosmic‐ray exposure age for Twannberg is 182 ± 45 Ma. The most surprising result is the long terrestrial age of T_terr =  ka, which is unexpected considering the humid conditions in Switzerland. However, this age is in accord with glaciation events, indicating that the less shielded samples from Mt. Sujet were found close to the position of the original strewn field, whereas the samples from Gruebmatt and Twannbach, which are from more shielded positions, were glacially transported to the east–northeast during the second last ice age (185–130 ka ago) from an original position west of Mt. Sujet.     

Phytoscreening for Vinyl Chloride in Groundwater Discharging to a Stream

This study applies an optimized phytoscreening method to locate a chlorinated ethene plume discharging into a stream. To evaluate the conditions most suitable for successful phytoscreening, trees along the stream bank were monitored through different seasons with different environmental conditions and hence different uptake/loss scenarios. Vinyl chloride (VC) as well as cis‐dichloroethylene (cis‐DCE), trichloroethylene (TCE), and tetrachloroethylene (PCE) were detected in the trees, documenting that phytoscreening is a viable method to locate chlorinated ethene plumes, including VC, discharging to streams. The results reveal, that phytoscreening for VC is more sensitive to environmental conditions affecting transpiration than for the other chlorinated ethenes detected. Conditions leading to higher groundwater uptake by transpiration than contaminant loss by diffusion from the tree trunks are optimal (e.g., low relative humidity, plentiful hours of sunshine and an intermediate air temperature). Additionally, low precipitation prior to the sampling event is beneficial, as uptake of infiltrating precipitation dilutes the concentration in the trees. All chlorinated ethenes were sensitive to dilution by clean precipitation and in some months, this resulted in no detection of contaminants in the trees at all. Under optimal environmental conditions the tree cores allowed detection of chlorinated solvents and their metabolites in the underlying groundwater. Whereas, for less ideal conditions there was a risk of no detection of the more volatile VC. This study is promising for the future applicability of phytoscreening to locate shallow groundwater contamination with the degradation products of chlorinated solvents.     

Advanced three-dimensional seismic imaging of deep supercritical geothermal rocks in Southern Tuscany

The seismic K-Horizon is the key to gaining understanding on the deep supercritical geothermal rocks in Southern Tuscany. The K-Horizon is hosted in metamorphic rocks, which cause strong seismic wavefield scattering resulting in a poor signal-to-noise ratio. Our study aims to reveal high-resolution seismic images of the K-Horizon below a geothermal field in Southern Tuscany, using an advanced three-dimensional seismic depth imaging approach. The key seismic pre-processing steps in the time domain include muting a large amount of persistent noise based on the statistical analysis of the seismic amplitudes, and tomostatics technique to correct for static effects. We carried out seismic depth imaging using Kirchhoff Pre-Stack Depth Migration and Fresnel Volume Migration techniques. Each migration technique was tested with constant and heterogeneous three-dimensional velocity models. Due to the difficulties in determining emergent angles for this low signal-to-noise ratio data set, the migration results with the heterogeneous three-dimensional velocity model show less coherent reflections compared to the migration results using the constant velocity model. Both velocity models however lead to relatively the same structure and depth of the K-Horizon, indicating the similarity of the average velocities along the wave propagation paths in both velocity models. With both velocity models Fresnel Volume Migration yields the K-Horizon with better reflection coherency and higher signal-to-noise ratio than standard Kirchhoff Pre-Stack Depth Migration. Nevertheless, both migration techniques have been able to reveal the K-Horizon with relatively high resolution and provide a reliable basis for geothermal rock characterization as well as steering of the first geothermal well penetrating the K-Horizon.     

The first post‐injection seismic monitor survey at the Ketzin pilot CO2 storage site: results from time‐lapse analysis

The injection of CO₂ at the Ketzin pilot CO₂ storage site started in June 2008 and ended in August 2013. During the 62 months of injection, a total amount of about 67 kt of CO₂ was injected into a saline aquifer. A third repeat three‐dimensional seismic survey, serving as the first post‐injection survey, was acquired in 2015, aiming to investigate the recent movement of the injected CO₂. Consistent with the previous two time‐lapse surveys, a predominantly west–northwest migration of the gaseous CO₂ plume in the up‐dip direction within the reservoir is inferred in this first post‐injection survey. No systematic anomalies are detected through the reservoir overburden. The extent of the CO₂ plume west of the injection site is almost identical to that found in the 2012 second repeat survey (after injection of 61 kt); however, there is a significant decrease in its size east of the injection site. Assessment of the CO₂ plume distribution suggests that the decrease in the size of the anomaly may be due to multiple factors, such as limited vertical resolution, CO₂ dissolution, and CO₂ migration into thin layers, in addition to the effects of ambient noise. Four‐dimensional seismic modelling based on dynamic flow simulations indicates that a dynamic balance between the newly injected CO₂ after the second repeat survey and the CO₂ migrating into thin layers and being dissolved was reached by the time of the first post‐injection survey. In view of the significant uncertainties in CO₂ mass estimation, both patchy and non‐patchy saturation models for the Ketzin site were taken into consideration.     

The impact of interactive visualization on trade-off-based geospatial decision-making

In a previous work we developed GISwaps, a novel method for geospatial decision-making based on Even Swaps. In this paper, we present the results of an evaluation of a visualization framework integrated with this method, implemented within a decision support system. This evaluation is based on two different studies. In the quantitative study, 15 student participants used GISwaps with no visual features, and 15 participants used GISwaps with the integrated visual framework, as the tool in a solar farm site location case study. The results of the quantitative evaluation show positive impact of the visualization in terms of increased coherency in trade-offs. The results also show a statistically significant difference in average trade-off values between the groups, with users from the non-visual group setting on average 20% higher trade-off values compared with the users in the visual group. In the qualitative study, we had one expert in GIS, two experts in decision-making and two experts in solar energy as a focus user group. Data in this study were obtained by observations and semi-structured interviews with the participants. The impact of the visualization framework was assessed positively by all participants in the expert group.     

Towards a typology of urban centers and subcenters – evidence from German city regions

This study aims to characterize urban spatial structure with respect to its multidimensionality. Using an encompassing data set of socioeconomic variables, as well as variables pertaining to the built environment, accessibility and land use, we suggest a quantitatively based urban (sub-) center typology. The fine-grained spatial scale of 1 km² grid cells permits a higher spatial resolution than that used in most previous studies. Our suggested typology is two-layered: a “macro layer” based on cluster analyses sheds light on urban spatial configurations. A corresponding threshold-based “micro layer” identifies distinctive types of centers and subcenters at the local level. The application of this multi-scale and multivariate typology to four German city regions indicates both the core cities’ morphological dominance and the formation of subcenters with distinct profiles of regional economic importance, land use patterns and urban form. However, a substantial degree of spatial dispersion is observed because much activity is located in non-central locations.     

Nano-mechanical Properties and Pore-Scale Characterization of Different Rank Coals

Characterization of coal micro-structure and the associated rock mechanical properties are of key importance for coal seam exploration, coal bed methane development, enhanced coal bed methane production and CO₂ storage in deep coal seams. Considerable knowledge exists about coal chemical properties, but less is known about the nanoscale to the micro-scale structure of coals and how they change with coal strength across coal ranks. Thus, in this study, 3D X-ray micro-computed tomography (with a voxel size of 3.43 µm) and nano-indentation tests were conducted on coal samples of different ranks from peat to anthracite. The micro-structure of peats showed a well-developed pore system with meso- and micro-pores. The meso-pores essentially disappear with increasing rank, whereas the micro-pores persist and then increase past the bituminous rank. The micro-fracture system develops past the peat stage and by sub-bituminous ranks and changes into larger and mature fracture systems at higher ranks. The nano-indentation modulus showed the increasing trend from low- to high-rank coal with a perfect linear relationship with vitrinite reflectance and is highly correlated with carbon content as expected.

     

High-resolution P-Cable 3D seismic imaging of gas chimney structures in gas hydrated sediments of an Arctic sediment drift

The newly developed P-Cable 3D seismic system allows for high-resolution seismic imaging to characterize upper geosphere geological features focusing on geofluid expressions (gas chimneys), shallow gas and gas hydrate reservoirs. Seismic imaging of a geofluid system of an Arctic sediment drift at the Vestnesa Ridge, offshore western Svalbard, provides significantly improved details of internal chimney structures from the seafloor to ∼500 m bsf (below seafloor). The chimneys connect to pockmarks at the seafloor and indicate focused fluid flow through gas hydrated sediments. The pockmarks are not buried and align at the ridge-crest pointing to recent, topography-controlled fluid discharge. Chimneys are fuelled by sources beneath the base of gas hydrate stability zone (GHSZ) that is evident at ∼160–170 m bsf as indicated by a bottom-simulating reflector (BSR). Conduit centres that are not vertically straight but shift laterally by up to 200 m as well as discontinuous internal chimney reflections indicate heterogeneous hydraulic fracturing of the sediments. Episodically active, pressure-driven focused fluid flow could explain the hydro-fracturing processes that control the plumbing system and lead to extensive pockmark formation at crest of the Vestnesa Ridge. High-amplitude anomalies in the upper 50 m of the chimney structures suggest formations of near-surface gas hydrates and/or authigenic carbonate precipitation. Acoustic anomalies, expressed as high amplitudes and amplitude blanking, are irregularly distributed throughout the deeper parts of the chimneys and provide evidence for the variability of hydrate and/or carbonate formation in space and time.