Occurrence and Distribution of Organic Contaminants in the Aquatic System in Berlin.Part II: Substituted Phenols in Berlin Surface Water

In a surface water screening, 30 representative surface water samples collected from rivers, canals, and lakes in Berlin were investigated for the presence of 22 substituted phenols. The phenols selected include the 11 phenols considered as “priority pollutants” by the US Environmental Protection Agency (US-EPA). Surface water samples were extracted applying solid-phase extraction with styrenedivinylbenzene adsorbent. The recoveries, determined in spiking experiments, were between 80 % and 103 %. After derivatization with N-(tert-butyldimethylsilyl)-N-methyl-trifluoroacetamide (MTBSTFA) the samples were analyzed by capillary gas chromatography-mass spectrometry (GC-MS). Phenol, cresols, 2-ethylphenol, 2-chlorophenol, 4-chloro-3-methylphenol, pentachlorophenol, 2-nitrophenol, and 4-nitrophenol were detected in the surface water samples at concentrations between 0.02 μg/L and 7.8 μg/L, respectively. The distribution of these residues in the Berlin surface waters showed that the phenolic residues, with the exception of pentachlorophenol and 2-ethylphenol, do not originate primarily from municipal sewage treatment plants discharges. Some of the phenols are formed naturally or occur as ubiquitous anthropogenic contaminants in the aquatic system.     

A COMBINED REFRACTION-DIFFRACTION-DISSIPATION MODEL OF WAVE PROPAGATION

A numerical model based on the mild-slope equation of water wave propagation over complicated bathymetry,taking into account the combined effects of refraction,diffraction and dissipation due to wavebreaking is presented.Wave breaking is simulated by modifying the wave height probability density func-tion and the wave energy dissipation mechanism is parameterized according to that of the hydraulic jumpformulation.Solutions of the wave height,phase function,and the wave direction at every grid point areobtained by finite difference approximation of the governing equations,using Gauss-Seidel Iterative Method(GSIM)row by row.Its computational convenience allows it to be applied to large coast regions tostudy the wave transformation problem.Several case studies have been made and the results compare verywell with the experiment data and other model solutions.The capability and utility of the model forreal coast areas are illustrated by application to a shallow bay of northeast Australia.     

A possible active galactic nucleus in M82?

MERLIN and VLA observations of the galaxy M82 have detected a jet-like feature emanating from one of the compact sources, 44.01+59.6. The proximity of this source to the dynamical centre of M82 led us to suspect that it could be a weak active nucleus rather than an SNR. We imaged this source using the EVN at 15 mas and although it shows a compact shell-like structure which could be consistent with an SNR, we note that the EVN image shows a bright region within the source which is elongated along the jet direction. There are distinct similarities between this source and the Sgr A complex at the centre of our own Galaxy which contains the compact AGN, Sgr A^*.     

Soil Organic Carbon mapping of partially vegetated agricultural fields with imaging spectroscopy

Soil Organic Carbon (SOC) is one of the key soil properties, but the large spatial variation makes continuous mapping a complex task. Imaging spectroscopy has proven to be an useful technique for mapping of soil properties, but the applicability decreases rapidly when fields are partially covered with vegetation. In this paper we show that with only a few percent fractional maize cover the accuracy of a Partial Least Square Regression (PLSR) based SOC prediction model drops dramatically. However, this problem can be solved with the use of spectral unmixing techniques. First, the fractional maize cover is determined with linear spectral unmixing, taking the illumination and observation angles into account. In a next step the influence of maize is filtered out from the spectral signal by a new procedure termed Residual Spectral Unmixing (RSU). The residual soil spectra resulting from this procedure are used for mapping of SOC using PLSR, which could be done with accuracies comparable to studies performed on bare soil surfaces (Root Mean Standard Error of Calibration = 1.34 g/kg and Root Mean Standard Error of Prediction = 1.65 g/kg). With the presented RSU approach it is possible to filter out the influence of maize from the mixed spectra, and the residual soil spectra contain enough information for mapping of the SOC distribution within agricultural fields. This can improve the applicability of airborne imaging spectroscopy for soil studies in temperate climates, since the use of the RSU approach can extend the flight-window which is often constrained by the presence of vegetation.     

Terrestrial and Submerged Aquatic Vegetation Mapping in Fire Island National Seashore Using High Spatial Resolution Remote Sensing Data

The vegetation communities and spatial patterns on the Fire Island National Seashore are dynamic as the result of interactions with driving forces such as sand deposition, storm-driven over wash, salt spray, surface water, as well as with human disturbances. We used high spatial resolution QuickBird-2 satellite remote sensing data to map both terrestrial and submerged aquatic vegetation communities of the National Seashore. We adopted a stratified classification and unsupervised classification approach for mapping terrestrial vegetation types. Our classification scheme included detailed terrestrial vegetation types identified by previous vegetation mapping efforts of the National Park Service and three generalized categories of high-density seagrass, low-density seagrass coverages, and unvegetated bottom to map the submerged aquatic vegetation habitats. We used underwater videography, GPS-guided field reference photography, and bathymetric data to support remote sensing image classification and information extraction. This study achieved approximately 82% and 75% overall classification accuracy for the terrestrial and submnerged aquatic vegetations, respectively, and provided an updated vegetation inventory and change analysis for the Northeast Coastal and Barrier Network of the National Park Service.     

A ROSAT survey of Wolf–Rayet galaxies — II. The extended sample

We present results from an ongoing X-ray survey of Wolf–Rayet (WR) galaxies, a class of objects believed to be very young starbursts. This paper extends the first X-ray survey of WR galaxies by Stevens &38; Strickland by studying WR galaxies identified subsequent to the original WR galaxy catalogue of Conti.   Out of a sample of 40 new WR galaxies a total of 10 have been observed with the ROSAT PSPC, and of these seven have been detected (NGC 1365, NGC 1569, I Zw 18, NGC 3353, NGC 4449, NGC 5408 and a marginal detection of NGC 2366). Of these, all are dwarf starbursts except for NGC 1365, which is a barred spiral galaxy possibly with an active nucleus. We also report on observations of the related emission-line galaxy IRAS 0833+6517.   The X-ray properties of these galaxies are broadly in line with those found for the original sample; they are X-ray overluminous compared with their blue luminosity and have thermal spectra with typically kT  ∼ 0.4 − 1.0 keV. There are some oddities: NGC 5408 is very overluminous in X-rays, even compared with other WR galaxies; I Zw 18 has a harder X-ray spectrum; NGC 1365, although thought to contain an active nucleus, has X-ray properties that are broadly similar to other WR galaxies, and we suggest that the X-ray emission from NGC 1365 is due to starburst activity.   A good correlation between X-ray and blue luminosity is found for the WR galaxy sample as a whole. However, when just dwarf galaxies are considered there is little evidence of correlation. We discuss the implications of these results on our understanding of the X-ray emission from WR galaxies and suggest that the best explanation for the X-ray activity is starburst activity from a young starburst region.     

Sub‐meter acoustic surveying

Abstract

During May 1985, a comprehensive GPS and acoustic navigation data set was collected off the Monterey, California coast. Three types of GPS units, a LORAN‐C, and a Miniranger operated concurrently with an OCEANO acoustic system to resolve state‐of‐the‐art accuracies for at‐sea geodetic positioning. This report details the acoustic system which displayed baseline errors of only ±0.25 m over distances to 2600 m. Unfiltered point‐to‐point acoustic navigation errors had a standard deviation of ± 1.25 m, which included ship motion errors in addition to surveying errors. Ninety percent of the stations had navigation standard deviations below ±0.75 m The experiment showed that sub‐meter acoustic surveying is the state‐of‐the‐art.