郴桂地区中大比例尺成矿预测的方法与效果

郴桂地区是南岭多金属成矿带的重要地段，地质矿产工作研究程度较高，我院在此开展了大中比例尺成矿预测研究。本文扼要介绍了本区成矿预测的基本做法和预测方法，以及其主要成果和验证效果。     

鄂尔多斯盆地中生代晚期以来大地热流的变化及其对生态环境格局和演变的影响

鄂尔多斯盆地的西北部、东北部和南部三个区域现今大地热流平均值分别为56．3、67．3和65．3mW／m^2，对应的生态环境格局也有明显的差异。研究表明，大地热流每增加4～5mW／m^2可使年均地表温度升高约l℃，使最低月均地表温度升高2。C以上。鄂尔多斯盆地东北部的平均大地热流比西北部高出11mW／m^2，东北部年均地表温度可能比西北部高出2～3℃，其最低月均地表温度可能比西北部高出4～6℃。西北部的大地热流平均值已经低于维持地表生态系统延续所需大地热流的临界值(57mW／m^2)，其自然生态系统整体上已经处于脆弱境地；东北部和南部的大地热流均大于57mW／m^2，自然生态系统均尚较稳健。东北部的沙漠化可能是风沙侵入的结果，其生态应该是可以恢复的。整个西北部作为一个整体看，72万年以前大地热流就已衰减到临界值以下，区域生态系统渐趋脆弱，开始整体上向荒漠化演变。     

Determination and application of the weights for landslide susceptibility mapping using an artificial neural network

The purpose of this study is the development, application, and assessment of probability and artificial neural network methods for assessing landslide susceptibility in a chosen study area. As the basic analysis tool, a Geographic Information System (GIS) was used for spatial data management and manipulation. Landslide locations and landslide-related factors such as slope, curvature, soil texture, soil drainage, effective thickness, wood type, and wood diameter were used for analyzing landslide susceptibility. A probability method was used for calculating the rating of the relative importance of each factor class to landslide occurrence. For calculating the weight of the relative importance of each factor to landslide occurrence, an artificial neural network method was developed. Using these methods, the landslide susceptibility index (LSI) was calculated using the rating and weight, and a landslide susceptibility map was produced using the index. The results of the landslide susceptibility analysis, with and without weights, were confirmed from comparison with the landslide location data. The comparison result with weighting was better than the results without weighting. The calculated weight and rating can be used to landslide susceptibility mapping.     

Evolution of the eastern margin of Korea: Constraints on the opening of the East Sea (Japan Sea)

We interpreted marine seismic profiles in conjunction with swath bathymetric and magnetic data to investigate rifting to breakup processes at the eastern Korean margin that led to the separation of the southwestern Japan Arc. The eastern Korean margin is rimmed by fundamental elements of rift architecture comprising a seaward succession of a rift basin and an uplifted rift flank passing into the slope, typical of a passive continental margin. In the northern part, rifting occurred in the Korea Plateau that is a continental fragment extended and partially segmented from the Korean Peninsula. Two distinguished rift basins (Onnuri and Bandal Basins) in the Korea Plateau are bounded by major synthetic and smaller antithetic faults, creating wide and considerably symmetric profiles. The large-offset border fault zones of these basins have convex dip slopes and demonstrate a zig-zag arrangement along strike. In contrast, the southern margin is engraved along its length with a single narrow rift basin (Hupo Basin) that is an elongated asymmetric half-graben. Analysis of rift fault patterns suggests that rifting at the Korean margin was primarily controlled by normal faulting resulting from extension rather than strike-slip deformation. Two extension directions for rifting are recognized: the Onnuri and Hupo Basins were rifted in the east-west direction; the Bandal Basin in the east–west and northwest–southeast directions, suggesting two rift stages. We interpret that the east–west direction represents initial rifting at the inner margin; while the Japan Basin widened, rifting propagated southeastward repeatedly from the Japan Basin toward the Korean margin but could not penetrate the strong continental lithosphere of the Korean Shield and changed the direction to the south, resulting in east–west extension to create the rift basins at the Korean margin. The northwest–southeast direction probably represents the direction of rifting orthogonal to the inferred line of breakup along the base of the slope of the Korea Plateau; after breakup the southwestern Japan Arc separated in the southeast direction, indicating a response to tensional tectonics associated with the subduction of the Pacific Plate in the northwest direction. No significant volcanism was involved in initial rifting. In contrast, the inception of sea floor spreading documents a pronounced volcanic phase which appears to reflect asthenospheric upwelling as well as rift-induced convection particularly in the narrow southern margin. We suggest that structural and igneous evolution of the Korean margin, although it is in a back-arc setting, can be explained by the processes occurring at the passive continental margin with magmatism influenced by asthenospheric upwelling.     

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

改性碳酸氢铵的结构特征及其肥效增效机理研究

利用有机-无机(矿物)控释材料对碳酸氢铵进行改性，制成改性碳酸氢铵。盆栽试验结果显示，在等重条件下，改性碳酸氢铵较普通碳酸氢铵有较大幅度的增产。运用X射线衍射分析及红外光谱对改性碳酸氢铵的结构进行研究，发现其晶体结构发生较大的变化，差热分析结果也表明，改性碳酸氢铵的热分解温度比普通碳酸氢铵提高30℃。这种晶体结构的变化增加了改性碳酸氢氨的稳定性，从而延长了其肥效并提高了N的利用率。     

Microstructures of deformed grains in the augen gneisses of southern Menderes Massif (western Turkey) and their tectonic significance

A detailed fabric and microstructural analysis of the granitic mylonites was carried out on the southern side of Bes,parmak Mountain north of Selimiye (Milas). The mylonitic augen gneisses have?a blastomylonitic texture characterized by large retort-shape porphyroclasts or augen of feldspars, around which a more ductile, medium to fine-grained matrix of muscovite, biotite, quartz and feldspar is deflected. Feldspars behave in both plastic and brittle fashion, because size reduction occurs through grain boundary migration and/or subgrain rotation, and also through fracturing. Typical “core-and-mantle” structure, characterized by a large feldspar core surrounded by a mantle of fine recrystallized grains, is very characteristic. The majority of plagioclase twins obey the albite-twin law; however, the association with pericline-law twinning suggests that many of the twins are mechanical. Evidence of strain, such as deformation twins, bent or curved twins, undulatory extinction, deformation bands and kink bands occur characteristically in plagioclase. Myrmekite is ubiquitous at K-feldspar grain boundaries, most notably on the long sides of inequant grains parallel to the S-foliation direction, which invariably face the maximum finite shortening direction. Deformation of quartz in mylonitic augen gneisses commonly results in the development of core-and-mantle structure and “type-4” quartz ribbons of elongated, preferably oriented, newly recrystallized quartz aggregates suggesting a primary dynamic recrystallization. Undulatory extinction, deformation bands and lamellae are the strain-related features associated with quartz porphyroclasts. Micas, especially biotite, undergo internal deformation by bend gliding and kinking. Most of the micas are completely attenuated and aligned such that their (001) planes are subparallel or parallel to the margins of quartz ribbons and define the foliation in the rock. These microstructures of feldspars, quartz and mica in the mylonitic augen gneisses in this part of the southern Menderes Massif are broadly consistent with fabric development under upper-greenschist- to lower-amphibolite-facies conditions, rather than almandine–amphibolite facies, as was previously believed. This supports the previous contention of the authors that the protoliths of augen gneisses are younger granitoids and do not represent an exposed Precambrian Pan-African basement in the Menderes Massif.     

Impact of vegetation feedback on the temperature and its diurnal range over the Northern Hemisphere during summer in a 2 × CO2 climate

This study examines the potential impact of vegetation feedback on the changes in the diurnal temperature range (DTR) due to the doubling of atmospheric CO₂ concentrations during summer over the Northern Hemisphere using a global climate model equipped with a dynamic vegetation model. Results show that CO₂ doubling induces significant increases in the daily mean temperature and decreases in DTR regardless of the presence of the vegetation feedback effect. In the presence of vegetation feedback, increase in vegetation productivity related to warm and humid climate lead to (1) an increase in vegetation greenness in the mid-latitude and (2) a greening and the expansion of grasslands and boreal forests into the tundra region in the high latitudes. The greening via vegetation feedback induces contrasting effects on the temperature fields between the mid- and high-latitude regions. In the mid-latitudes, the greening further limits the increase in T _max more than T _min, resulting in further decreases in DTR because the greening amplifies evapotranspiration and thus cools daytime temperature. The greening in high-latitudes, however, it reinforces the warming by increasing T _max more than T _min to result in a further increase in DTR from the values obtained without vegetation feedback. This effect on T _max and DTR in the high latitude is mainly attributed to the reduction in surface albedo and the subsequent increase in the absorbed insolation. Present study indicates that vegetation feedback can alter the response of the temperature field to increases in CO₂ mainly by affecting the T _max and that its effect varies with the regional climate characteristics as a function of latitudes.     

Source identification of PM2.5 particles measured in Gwangju, Korea

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.     

Modelling Korean extreme rainfall using a Kappa distribution and maximum likelihood estimate

Summary Attempts to use the 4-parameter Kappa distribution (K4D) with the maximum likelihood estimates (MLE) on the summer extreme daily rainfall data at 61 gauging stations over South Korea have been made to obtain reliable quantile estimates for several return periods. A numerical algorithm for searching MLE of K4D by minimizing the negative log-likelihood function with penalty method has been described. The isopluvial maps of estimated design values corresponding to selected return periods have been presented. The highest return values are centered at sites in the south-western part of the Korean peninsula. The distribution of return values for annual maxima of 2-day precipitation (AMP2) is more similar to the climatological features of annual total precipitation of Korea than that of annual maxima of daily precipitation (AMP1). Our results of return values delineate well the horizontal patterns of the heavy precipitation over the Korean peninsula. Received January 15, 2001 Revised October 8, 2001