Biogenic emissions from Pinus halepensis: a typical species of the Mediterranean area

Volatile organic compounds (VOCs) emissions by vegetation present in the Mediterranean area are not well known. They may contribute with anthropogenic VOC emissions to the tropospheric ozone formation that reaches important level in the European Mediterranean region. The present work, carried out as part of the European ESCOMPTE project «fiEld experimentS to COnstrain Models of atmospheric Pollution and Transport of Emissions», adds a new contribution to the inventory of the main natural hydrocarbons sources likely to participate in the ozone production. The corresponding measurement campaign was conducted in La Barben, a site close to Marseilles (France), with the aim to quantify the terpenic emission pattern and the behaviour of Pinus halepensis, an important Mediterranean species slightly studied.The determination of biogenic emissions from P. halepensis was done by the enclosure of an intact branch in a Teflon cuvette. Main emitted monoterpenes were β trans-ocimene and linalool. The total monoterpenic emission rates thus recorded were found to reach maximum values around 30 μg g_{dry weight}⁻¹ h⁻¹. The normalized emission rates calculated at 30 °C and 1000 μmol m⁻² s⁻¹ with Guenther's algorithm was 14.76, 8.65 and 4.05 μg g_{dry weight}⁻¹ h⁻¹, respectively, for the total monoterpenes, β trans-ocimene and linalool.     

The oldest barnacle from the Caribbean is a rudist bivalve (Maastrichtian, Jamaica)

Four new specimens of Euscalpellum? coatesi Donovan and Davis-Strickland from the Maastrichtian of Jamaica are described; two of these occur in association with the right valve of the rudistid bivalve Chiapasella radiolitiformis (Trechmann). This demonstrates that E.? coatesi is not a barnacle, but rather represents an unusual preservational state of the left valve of C. radiolitiformis retaining only the cellular inner part of the shell.     

Shear-wave splitting beneath the Snake River Plain suggests a mantle upwelling beneath eastern Nevada, USA

The Snake River Plain (SRP), a 90-km-wide topographic depression in southern Idaho, is a topographically anomalous feature in the western U.S. Previous seismic studies focused on the northeastern SRP to study its relationship with the Yellowstone hotspot. We present new teleseismic shear-wave splitting data from six broadband seismic stations deployed along the axis of the SRP from June 2000 to September 2001. We also analyze splitting at HLID, a permanent station of the National Seismic Network located ∼100 km north of the plain. Splitting of individual teleseismic phases is consistent at all stations within 2σ errors, and we favor the interpretation of anisotropy with a single horizontal fast axis, although a dipping-axis interpretation is statistically permitted at two of the stations. Our station fast directions, as well as shear-wave splitting data from numerous other stations throughout the Basin and Range, are best explained by a lattice preferred orientation of olivine due to horizontal shear along the base of the plate associated with the gravitational spreading of buoyant plume-like upwelling material beneath eastern Nevada into a southwestward flowing asthenosphere (with respect to a fixed hotspot reference frame). This parabolic asthenospheric flow (PAF) model for the Great Basin is attractive because it explains the observed high elevations, high mantle buoyancy, low-velocity anomaly beneath eastern Nevada, high heat flow, and depleted geochemistry of some erupted basalts. The lack of Pliocene-Recent major volcanism in eastern Nevada suggests that a significant amount of the buoyancy flux is due to compositional buoyancy. Our splitting station delay times vary in a way not predicted by the PAF model, and can be explained by: a zone of aligned magma-filled lenses and/or partially molten dikes beneath the SRP lithosphere, a depleted olivine-rich residuum underneath the sides of the eastern SRP, and/or the effect of lateral lower crustal flow from beneath the eSRP toward its adjacent flanks.     

A polarimetric extension of the van Cittert-Zernike Theorem for use with microwave Interferometers

The van Cittert-Zernike theorem describes the Fourier transform relationship between an extended source and its visibility function. Developments in classical optics texts use scalar field formulations for the theorem. Here, we develop a polarimetric extension to the van Cittert-Zernike theorem with applications to passive microwave earth remote sensing. The development provides insight into the mechanics of two-dimensional inteferometric imaging, particularly the effects of polarization basis differences between the scene and the observer.     

Fluid flow in cataclastic thrust fault zones in sandstones, Sub-Andean Zone, southern Bolivia

The Bolivian Sub-Andean Zone (SAZ) corresponds to a Neogene thrust system that affects an about 10-km thick Palaeozoic to Neogene siliciclastic succession. The analysis of macro and microstructures and cement distribution in thrust fault zones shows that they are sealed by quartz at depths >3 km, due to local silica transfer by pressure-solution/precipitation activated at temperatures >70–90 °C. At shallower depths, faults have remained open and could be preferential drains for lateral flow of carbonate-bearing fluids, as shown by the occurrence of carbonate cements in fractures and their host-sandstone. Due to decreasing burial, resulting from foothill erosion during fault activity, critically buried fault segments can be affected by non-quartz-sealed structures that post-date initial quartz-sealed structures. The integration of textural, fluid inclusion and isotopic data shows that carbonates precipitated at shallow depth (<3 km), low temperature (<80 °C) and relatively late during the thrusting history. Isotopic data also show that precipitation occurred from the mixing of gravity-driven meteoric water with deeper formation water bearing carbonate carbon derived from the maturation of hydrocarbon source rocks (Silurian and Devonian shales). The combined microstructural and isotopic analyses indicate that: (i) fluid flow in fault zones often occurred with successive pulses derived from different or evolving sources and probably related to episodic fault activity, and (ii) at a large-scale, the faults have a low transverse permeability and they separate thrust sheets with different fluid histories.     

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.     

Reconceptualising local community: environment, identity and threat

Summary Economic 'development' driven by global economic forces produces specific expressions of 'community' in places where large new economic projects are to be located. This paper draws on contemporary geopolitical literature to theorise community identity as partly formulated in response to external 'threats'. A comparative study of community mobilisation in response to proposals to locate coastal superquarries on the Isle of Harris, Outer Hebrides, Scotland, and Cape Breton, Nova Scotia, Canada, suggests the applicability of this theoretical framework for extending geographical analysis of community identity and the politics of place.     

Use of magnetic and radiometric measurements to investigate erosion and sedimentation in a British upland catchment

In response to the potential shortcomings of single-technique strategies in the investigation of erosion and sedimentation, a combined magnetic and radiometric (¹³Cs and ²¹⁰Pb) approach has been undertaken in the upland, watershed-lake system of Howden Reservoir, Derbyshire. By combining these techniques, some assessment of sediment sources and the erosion status of the catchment has been achieved. Alone, each approach would have been unable to determine unequivocally sediment provenance. Furthermore, the parallel use of these measurements has highlighted limitations and/or uncertainties in both the magnetic and ¹³⁷Cs techniques. These problems reflect the particular soil characteristics and drainage conditions of this upland catchment. Despite the documented severity of peat erosion in the region, Howden Reservoir has a mixture of sediment sources and a relatively moderate rate of sedimentation. Sediment yields (total 127·7 t km^?2 yr^?1 including organic fraction 31·3 t km^?2 yr^?1) are, however, higher than in other British upland areas.