Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.     

Dynamics of a fringe mangrove forest detected by Landsat images in the Mekong River Delta,Vietnam

Mangrove forests dominate many tropical coastlines and are one of the most bio‐diverse and productive environments on Earth. However, little is known of the large‐scale dynamics of mangrove canopies and how they colonize intertidal areas. Here we focus on a fringe mangrove forest located in the Mekong River Delta, Vietnam; a fast prograding shoreline where mangroves are encroaching tidal flats. The spatial and temporal evolution of the mangrove canopy is studied using a time series of Landsat images spanning two decades as well as Shuttle Radar Topography Mission (SRTM) elevation data. Our results show that fast mangrove expansion is followed by an increase in Normalized Difference Vegetation Index (NDVI) in the newly established canopy. We observe three different dynamics of the mangrove fringe: in the southwest part of the fringe, near a deltaic distributary where the fringe boundary is linear, the canopy expands uniformly on the tidal flats with a high colonization rate and high NDVI values. In the northeast part of the fringe, near another distributary, the canopy expands at a much lower rate with low NDVI values. In the fringe center, far from the river mouths, the fringe boundary is highly irregular and mangroves expansion in characterized by sparse vegetated patches displaying low NDVI values. We ascribe these different dynamics to wave action and southwest longshore transport triggered by energetic northeasterly monsoons during winter. We further link the large‐scale dynamics of the fringe to small‐scale physical disturbances (waves, erosion and deposition) that might prevent the establishment of mangrove seedlings. Based on these results, we include mangrove encroachment in an already published conceptual model of progradation of the Mekong River Delta. We conclude that high NDVI values and a constantly linear vegetation–water interface are indicative of stable mangrove canopies undergoing fast expansion, probably triggered by sediment availability at the shore. Our results can be applied more generally to mangrove forests growing in minerogenic and high tidal range environments with high sediment inputs. Copyright © 2016 John Wiley & Sons, Ltd.     

Depositional environment of a Kimmeridgian carbonate 'black band' (Akkuyu Formation, south-western Turkey)

The Upper Jurassic Akkuyu Formation of south-western Turkey consists of pale-coloured carbonate facies, but includes a peculiar ‘black band’ at its base. In order to characterize the depositional environment of this level, a sedimentological, organic and inorganic geochemical study was performed on 30 samples. Three units are distinguished. Unit 1 consists of black marlstones, very rich in organic carbon (22–30%) with HI (hydrogen index) values around 600. The organic matter is an amorphous homogeneous material even at nanoscopic scale. This unit is also characterized by a very high concentration of V ( >1000 p.p.m.) and a δ¹³C_org value around ?26·5‰. Unit 2 shows thin-bedded black limestones with chert layers. Its organic content varies from 2% to 6%. As in unit 1, the HI values are uniformly high (600), and gas chromatography shows a high quantity of hopanes. The V concentration is also high (≈400 p.p.m.). The unit has a high Sr/Ca ratio, an organic carbon isotopic ratio close to ?28·7‰ and diffuse, nanoscopically amorphous organic material that is closely associated with pyrite. Unit 3 corresponds to the white limestones overlying the ‘black band’. This calcitic facies is almost devoid of organic carbon (<0·1%). The δ¹³C_org values are similar to those of unit 1 (?25·5‰ to ?26‰). Deposition occurred in a basinal environment surrounded by a carbonate platform. Primary productivity was high but not exceptional; terrestrial organic inputs were scarce. Bottom waters were probably euxinic during the deposition of unit 1. The presence of both hopane-rich and sulphur-rich nanoscopically amorphous organic matter may be the result of strong sulphate-reducing bacterial activity. Coupled with low amounts of iron, this led to intense vulcanization of the organic matter and thus good preservation. With the onset of unit 2 deposition, environmental conditions became less extreme, perhaps because of cooler water temperatures. Finally, the depositional conditions became oxic, leading to the accumulation of pale-coloured organic-poor limestones of unit 3.     

Tectono-sequence stratigraphy and U–Pb zircon ages of the Rincón Blanco Depocenter,northern Cuyo Rift,Argentina

Extensional processes that followed the Gondwanan Orogeny rise to the development of a series of rift basins along the continental margin over older accreted Eopaleozoic terranes. Stratigraphic, structural, paleontological, and isotopic studies are presented in this work in order to constrain the ages of the sedimentary infilling and to analyze the tectosedimentary evolution of one of the Cuyo basin depocenters, known as Rincón Blanco. This asymmetrical half-graben was filled by continental sediments under a strong tectonic control. The infilling was strongly controlled by tectonics which in term produced distinctive features along the whole sedimentary sequence. Using a combination of lithological and structural data the infilling was subdivided into packages of genetically linked units bounded by regional extended surfaces. Several tuffs and acid volcanic rocks have been collected across the whole section of the Rincon Blanco sub-basin for SHRIMP and LA-MC-ICPMS U–Pb zircon dating. The ages obtained range from 246.4 ± 1.1 Ma to 230.3 ± 1.5 Ma which is the time elapsed for the deposition of three tectono-sequence units separated by regional unconformities and mainly constrained to the Middle Triassic. They are interpreted as a result of a reactivation of the extensional system that has evolved along strike as segments of faults that linked together and/or as laterally propagating faults. Regional correlation with coeval rift basins permits to establish north-south propagation in the extensional regime along the western margin of SW Gondwana. This trending started in the lowermost Triassic and extended until the latest Triassic. Two of them were precisely correlated with Cerro Puntudo and Cacheuta half-graben systems. The new data indicate that the three sequences were mostly deposited during the Middle Triassic (246 to 230 Ma), with no evidence of sedimentation during Norian and Rhaetian, which is in conflict with some previous biostratigraphic studies.     

A software solution for point counting. Petrographic thin section analysis as a case study

In the field of geology, as in many other fields, a common problem is the analysis of 2D sections. An example of this is the petrographic study of rock samples, i.e., the quantification of its mineral components and the percentages of each phase present in it. Conventionally, this quantification has been determined by point counting performed on thin sections. Although point counting is very time consuming, it is of common use in several domains including geology, biology, medicine, and materials sciences, among others. Point counting in thin sections is normally conducted through mechanical or electromechanical devices attached to a microscope; such devices are very expensive, offer limited functionality, and are very time consuming. In this contribution, we introduce an interactive visualization application called Rock.AR that reduces the amount of time required to apply this technique and simplify its work flow. It provides visual tools like distortion techniques, overview + detail, and statistics to assist the technique. A comparison between this application and similar tools through users' experiences is provided. We compare the time it takes to complete a session of point counting and the tools' usability.     

Nickel, Copper, Zinc and Cadmium Cycling with Manganese in Lake Vanda (Wright Valley, Antarctica)

Lake Vanda is a closed-basin, permanently ice-covered lake located in the Wright Valley of Antarctica. The lakes more important geochemical features include the fact that it is fed by a single glacial melt water stream for only 6–8weeks out of the year; that it has remained stratified for more than a millennium; and that, like other lakes in the region, it is remote from anthropogenic influence. These, together with the fact that it is among the least biologically productive lakes in the world, make it an ideal system for examining the transport, cycling and fate of trace metals in the aquatic environment. Like others before us, we view this lake as a natural geochemical laboratory, a flask in the desert. This paper presents the first set of closely spaced, vertical, profiles for dissolved and particulate Mn, Fe, Ni, Cu, Zn and Cd in the water column. Despite the absence of an outflow, metals in the fresh upper waters of the lake have extremely low concentrations, in the pico-molar to nano-molar range, and are partitioned largely into dissolved rather than particulate phases. Efficient metal scavenging by particles from these oxygen-rich waters is indicated. Significant increases in metal concentrations begin to appear at depth, between 57 and 60m, and these increases coincide with the onset of manganese oxide dissolution in oxic, but lower pH waters. Vertical profiles suggest that the entire suite of trace metals (Ni, Cu, Zn, and Cd) is being released from manganese oxide carrier phases. Thermodynamic analysis indicates that Mn3O4 (i.e., the mineral hausmannite) may be important in metal sequestration and recycling in the deeper waters of Lake Vanda. Manganese-reducing organisms reported by Bratina etal. (1998) are active in the zone of metal release and these could also contribute to the observed cycling.     

Geomorphologic map of the 1<Superscript>st</Superscript> Mutnaya River,Southeastern Kamchatka,Russia

The Kamchatka Peninsula–situated in the Pacific “Ring of Fire”–has 29 active and over 400 extinct volcanoes. Since it is situated in the northeastern extremity of Russia, in subarctic climate, the volcanic landforms are overprinted by the 446 glaciers. This research focuses on the 1^stMutnaya catchment which drains the southern slopes of two active volcanoes: Avachinsky and Koryaksky. Those volcanoes are a permanent threat for the cities of Petropavlovsk and Elizovo, which are the 2 of 3 cities of the peninsula. Hence, most of the studies carried out in the area dealt with the natural hazards and only few focus on landscape evolution. Thus, the purpose of this study was to elaborate a cartographic approach which integrates classic geomorphology with state of the art GIS and remote sensing techniques. As result, different landforms and related processes have been analysed and included in the first general geomorphologic map of the 1^stMutnaya catchment.     

Effect of agrochemicals on macroinvertebrate assemblages in Pampasic streams,Buenos Aires,Argentina

Agricultural practices have been intensified in recent decades in Argentina. The Pampa plain is the main agricultural region of the country. The effect of increased application of agrochemicals on the invertebrate fauna of the Pampasic streams remains unreported. In the present study, we compared the abundance and composition of invertebrate assemblages in seven Pampasic streams with contrasting soil use in their basins. Two streams run through intensively cropped plots, two drain basins with livestock fields, while the other three are located within a biosphere Reserve. Higher nutrient and insecticide concentrations were measured in the streams draining cropped basins, related with pesticide applications and crop fertilization. The invertebrate assemblage composition of the cropped streams differed significantly from the others and between the two. Present evidence suggests that the impact of agrochemicals results in a change in composition with decreased abundance or absence of sensitive species such as Hyalellidae, Caenidae, Baetidae and Curculionidae and increased abundance of more tolerant taxa: Ostracoda, Glossiphoniidae (Hirudinea), Ancylidae (Gundlanchia), Ampullariidae (Pomacea canaliculata), Sphaeriidae and Dugesiidae. Available information suggests that macrophyte cover and composition also influence the invertebrate assemblages of the Pampasic streams.