On-chip earthquake simulation model using potentials

A two-dimensional (2-D) Cellular Automata (CA) dynamic system constituted of cells-charges has been proposed for the simulation of the earthquake process. The CA model has been calibrated with the use of real data. The calibration incorporates major seismic characteristics of the area under test. The simulation results are found in good quantitative and qualitative agreement with the recorded Gutenberg–Richter (GR) scaling relations. The model is enriched with a powerful multi-parameter interface that enables the user to load real data from different regions. This paper examines the on-chip realisation of the model and its instrumentation. The CA model hardware implementation is based on Field Programmable Gate Array (FPGA) logic. It utilises an array of 32 × 32 cells. Parameters that construct the local CA rule constitute the input data. The initial seed, which to some extent corresponds to the seismic features of the area under test, is loaded in a semi-parallel way and the process is completed in a certain number of time steps. The automatic response of the processor provides the corresponding GR scaling law of the area under study. The hardware implementation of the CA-based earthquake simulation model is advantageous in terms of low-cost, high-speed, compactness and portability features. It can operate as a preliminary data-acquisition filter that accelerates the evaluation of recorded data as far as its origin time, spatial and magnitude completeness and quality are concerned. Software that performs reliable automatic phase picking, as well as data elaboration, can be assembled next to the earthquake recording instruments (the whole network) output to assure a quick and reliable iteration of the focal parameters of a recorded earthquake (epicentre coordinates, focal depth and magnitude). The dedicated processor can be accommodated right after this stage (before any manual elaboration) focusing on the near real-time development of a reliable qualitative dynamical seismic record and a mapping of the seismic characteristics of the area.     

Shear banding in geomaterials under extensional plane strain conditions: Physical and analytical model

The shear band (SB) spacing phenomenon in geomaterials is addressed in this paper under plane strain extensional conditions. On the basis of sand box observations, a method is proposed for the prediction of the spacing between shear bands based on the so-called “bookshelf” deformation mechanism. The proposed method is based on the assumption that the material is softening inside the shear bands whereas outside the SB it undergoes elastic unloading. The underlying assumption for the prediction of SB spacing is that the material reaches the lowest possible energy rate. An analytical expression for the determination of the shear band spacing is presented taking into account the plane strain extensional deformation of the specimen. The friction due to the normal off-plane shear acting on the boundaries is then taken into account.     

Refining the timing of eclogite metamorphism: a geochemical,petrological, Sm-Nd and U-Pb case study from the Pohorje Mountains,Slovenia (Eastern Alps)

High-pressure metamorphism in the Pohorje Mountains of Slovenia (Austroalpine unit, Eastern Alps) affected N-MORB type metabasic and metapelitic lithologies. Thermodynamic calculations and equilibrium phase diagrams of kyanite–phengite-bearing eclogites reveal PT conditions of >2.1 GPa at T<750°C, but within the stability field of quartz. Metapelitic eclogite country rocks contain the assemblage garnet + phengite + kyanite + quartz, for which calculated peak pressure conditions are in good agreement with results obtained from eclogite samples. The eclogites contain a single population of spherical zircon with a low Th/U ratio. Combined constraints on the age of metamorphism come from U/Pb zircon as well as garnet–whole rock and mineral–mineral Sm-Nd analyses from eclogites. A coherent cluster of single zircon analyses yields a ²⁰⁶Pb/²³⁸U age of 90.7±1.0 Ma that is in good agreement with results from Sm-Nd garnet–whole rock regression of 90.7±3.9 and 90.1±2.0 Ma (εNd: +8) for two eclogite samples. The agreement between U-Pb and Sm-Nd age data strongly suggests an age of approximately 90 Ma for the pressure peak of the eclogites in the Pohorje Mountains. The presence of garnet, omphacite and quartz inclusions in unfractured zircon indicates high-pressure rather than ultrahigh pressure conditions. The analysed metapelite sample yields a Sm-Nd garnet–whole rock scatterchron age of 97±15 Ma. These data probably support a single P-T loop for mafic and pelitic lithologies of the Pohorje area and a late Cretaceous high-pressure event that affected the entire easternmost Austroalpine basement including the Koralpe and Saualpe eclogite type locality in the course of the complex collision of the Apulian microplate and Europe.     

ISA model: A constitutive model for soils with yield surface in the intergranular strain space

In this article, a new constitutive model for soils is proposed. It is formulated by means of plasticity, but in contrast to the precedent works, it presents a yield function describing a surface within the intergranular strain space. This latter is a state variable providing information of the recent strain history. An expression for the plastic strain rate has been proposed to guarantee the stress rate continuity. Under the application of medium or large strain amplitudes, the constitutive equation becomes independent of the intergranular strain and delivers a mathematical structure similar to some Karlsruhe hypoplastic models. Some simulations of monotonic and cyclic triaxial test are provided to evaluate and analyze the model performance. Copyright © 2015 John Wiley & Sons, Ltd.     

Crustal observations beneath the southern North Sea and their tectonic and geological implications

In 1991, a deep seismic reflection line, MPNI-9101, was acquired in the southern North Sea from the Mesozoic Broad Fourteens Basin, across the West Netherlands Basin onto the London-Brabant Massif (LBM). The resultant section shows a strongly reflective lower crust beneath the area of Mesozoic basin development. This lower crustal reflectivity continues to be strong beneath the LBM. The travel time to the base of the reflective zone increases from approximately 11.0 s beneath the Mesozoic basins to 12.5 s beneath the LBM, suggesting a southward thickening of the crust (Rijkers et al., 1993). Based on these travel times and information from deep wells and refraction surveys. Moho depth is estimated to increase from about 31 km beneath the Mesozoic basins to about 38 km beneath the LBM. This difference in depth to the Moho can partly be explained by coaxial stretching of the crust beneath the Mesozoic basins. In comparison with the Mesozoic basins, the crust beneath the LBM was thickened during the Caledonian and Variscan orogenies.     

Relations between metamorphism and orogeny in a typical section of the Indian Himalayas

Summary A comprehensive geological and petrological investigation has been undertaken in an area of about 10 000 km² in the Indian Himalaya (S-Lahul, Himachal Pradesh). The development of mineral assemblages in metamorphic rocks of medium grade is considered to be a dominant Alpine event, although almost exclusively Paleozoic and Precambrian rocks have been involved. The Barrowian type of this metamorphism, ranging from the anchi- to the sillimanite zone, took place under the elavated T-gradient of about 4°C/100 m. It is suggested that normal geothermal conditions prevailed only in the outermost zone of this orogenic belt. In the Late Tertiary this metamorphic series has been moved as a huge nappe upon the Lower Himalaya. During this process a unique feature of reverse metamorphism has been formed. It can be shown that this feature was caused by a combination of metamorphism and very rapid tectonic movements.

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Beziehungen zwischen Metamorphose und Orogenese in einem typischen Querschnitt des Indischen Himalaya

Zusammenfassung Ein etwa 10 000 km² großes Gebiet des Indischen Himalaya (S-Lahul, Himachal Pradesh) wurde einer umfassenden geologischen und petrographischen Bearbeitung unterzogen. Die Ausbildung der in den mittelgradig metamorphen Gesteinen vorliegenden Mineralparagenesen wird als ein dominant alpines Ereignis betrachtet, obwohl fast nur paläozoische und präkambrische Gesteine einbezogen wurden. Die Metamorphose selbst ist von Barrow-Typus und reicht von der Anchi- bis zur Sillimanitzone. Sie fand unter einem erhöhten Temperaturgradienten von etwa 4°C/100 m statt. Nur in der äußersten Zone des Orogens entsprach der Gradient etwa normalen geothermischen Verhältnissen. Im Spättertiär wurde diese alpin-metamorphe Serie in Form einer mächtigen Kristallindecke dem Niedrigen Himalaya aufgeschoben. Dabei wurde eine einzigartige Zone inverser Metamorphose ausgebildet. Es konnte gezeigt werden, daß diese inverse Metamorphose durch das Zusammenwirken von Metamorphose und sehr rasch ablaufender Tektonik entstand.

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With 13 Figures

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Dedicated to Prof. Dr. Dr. h. c.B. Sander on the occasion of his 90th birthday.     

Electrical resistivity and 57Fe Mössbauer spectra of Fe-bearing calcic amphiboles

Electrical resistivity and ⁵⁷Fe Mössbauer spectra are reported for three calcic amphiboles with different Fe concentrations. AC measurements (20?Hz–1?MHz) were performed, applying impedance spectroscopy between 100 and 785?°C in an N₂ gas atmosphere. It was found that up to three semiconducting charge transport processes can be distinguished, which in part changed slightly when several runs were carried out to higher temperatures. The extrapolated DC resistivity is much smaller for an amphibole with high Fe content than for the two with lower Fe concentrations. The derived activation energies are between ～0.48 and ～1.06?eV. For temperatures ≤600?°C the results are compatible with a charge transport mechanism due to electron hopping between Fe²⁺ and Fe³⁺. Above 600?°C, dehydrogenation and/or beginning amphibole decomposition obviously alter the conduction mechanism. From Mössbauer spectra it was established that in all amphibole samples Fe²⁺ and Fe³⁺ are simultaneously present. Mössbauer parameters were derived by fitting the observed spectra to models taking the occupation of various M sites into account.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Emissions of Volatile Organic Compounds from Sunflower and Beech: Dependence on Temperature and Light Intensity

Emissions of volatile organic compounds (VOCs) from sunflower (Helianthus annuus L. cv. giganteus) were measured in a continuously stirred tank reactor. The compounds predominantly emitted from sunflower were: isoprene, the monoterpenes -pinene, -pinene, sabinene, 3-carene and limonene, an oxygenated terpene, not positively identified so far and the sesquiterpene -caryophyllene. Emission rates ranged from 0.8 x 10^–16 to 4.3 x 10 ^–15 mol cm^–2 s^–1 at a temperature of 25°C and at a light intensity of 820 µEm^–2 s^–1. A dependence of the emission rates on temperature as well as on light intensity was observed. The emission rates of -pinene, sabinene and thujene from beech (Fagus sylvatica L.) were also affected by temperature as well as by light intensity. Our results suggest that an emission algorithm for all compounds emitted from sunflower and beech has to consider temperature and light intensity simultaneously. The observations strongly indicate that the emissions of VOCs from sunflower and beech are in part closely coupled to the rate of biosynthesis and in part originate from diffusion out of pools. The emission rates can be described by an algorithm that combines the model given by Tingey and coworkers with the algorithm given by Guenther and coworkers after slight modification.     

A laser-photolysis fragment-fluorescence (LPFF) method for the detection of gaseous nitric acid in ambient air

The development and first tests of a novel method for the direct, sensitive, selective, and fast detection of gaseous nitric acid in air are described. The detection method is based on the laser-photolysis fragment-fluorescence (LPFF) method using 193 nm (ArF) laser light. The photolysis process yielding OH fluorescence has been thoroughly investigated. Up to now, the method has been found to be practically free of interferences. The mixing ratio for nitric acid is measured on-line with a detection limit of about 0.1 ppbv for an accumulation time of the signal of 10–15 min. A number of tests and field measurements were performed to demonstrate the feasibility and limits of the described detection method.