Rice Husk Ash as a Low Cost Adsorbent for the Removal of Methylene Blue and Congo Red in Aqueous Phases

Adsorption is of significant importance for effluent treatment, especially for the treatment of colored effluent generated from the dyeing and bleaching industries. Low cost adsorbents have gained attention over the decades as a means of achieving very high removal efficiencies to meet effluent discharge standards. The present article reports on batch investigations for color removal from aqueous solutions of Methylene Blue (MB) and Congo Red (CR) using Rice Husk Ash (RHA) as an alternative low cost adsorbent. The performance analysis was carried out as a function of various operating parameters, such as initial concentration of dye, adsorbent dose, contact time, shaker speed, interruption of shaking and ionic concentration. Performance studies revealed that a very high percentage removal of color was achievable for both dyes. The maximum percentage removal of MB was 99.939%, while 98.835% removal was observed for CR. These percentage removals were better than existing systems. Detailed data analysis indicated that adsorption of MB followed the Temkin isotherm, while CR followed the Freundlich isotherm. These isotherms were feasible within the framework of experimentation. Batch kinetic data, on the other hand, indicated that pseudo second order kinetics governed adsorption in both cases. Sensitivity analysis further indicated that the effects of initial dye concentration, shaker speed, pH and ionic strength had no noticeable effect on the percentage dye removal at equilibrium. Batch desorption studies revealed that 50% acetone solution was optimum for CR, while desorption of MB varied directly with acetone concentration.     

Petrology,geochemistry and geochronology of the Chilka Lake igneous complex,Orissa state,India

The Chilka Lake igneous complex of Orissa, the largest known anortosite massif of the Indian Shield, occurs in a catazonal environment of high-grade metamorphics of the Eastern Ghats Precambrian Orogenic Province. The syntectonic massif consists of the anorthositic Balugaon dome, leuconoritic Rambha lobe and quartz-mangeritic Kallikota cover. A completely gradational suite comprising anorthosite-leuconorite-norite-minor jotunite (the anorthositic suite) constitutes most of the complex. The subordinate of suite of acid rocks spatially associated with this is of a broad quartz-mangeritic lithology with minor granitic rocks (the acidic suite). Geochemical evolution of the complex in the sequence anorthosite-leuconorite-norite-jotunite-acidic rocks shows moderate iron enrichment in the noritic-jotunitic stage and is marked by an overall decrease in Al₂O₃, CaO, MgO, Ni/Co, Sr/Ba, K/Rb and increase in SiO₂, K₂O, V/Ni, K/Ba and Rb/Sr. Such progressive variation in geochemical parameters appears (i) essentially gradual and frequently overlapping in rock members of the intergradational anorthositic suite and (ii) rather abrupt across transition zones between the anorthositic suite and the acidic suite due to near absence of intervening intermediate lithologies. RbSr whole rock isochron studies indicate that the complex was emplaced ca. 1400 Ma ago. The initial ⁸⁷Sr/⁶⁸Sr (0.70661) implies limited hybridisation of the parent magma prior to emplacement. A critical appraisal of all the available evidence suggests that (i) the anorthositic suite of rocks form a perfectly consanguinous and comagmatic assemblage and (ii) the spatially associated acidic suite emerged through a convergence of magmatic and metasomatic processes (the latter brought about by contact anatexis of the host rocks). The complex as well as the host metamorphics are intruded by an atectonic suite of noritic dykes emplaced ca 850 Ma ago.     

High-resolution profile of stable isotopes and iridium across a K/T boundary section from Koshak Hill, Mangyshlak, Kazakhstan

Oxygen and carbon isotopes were measured to a high depth resolution in a nannoplankton carbonate sequence spanning the Cretaceous-Tertiary boundary at Koshak Hill, Mangyshlak Peninsula, Kazakhstan. The boundary is characterized by the presence of a ∼ 1 cm thick clay layer having a sharp peak in iridium concentration with a maximum value of 3.7 ng g^-1. The δ¹⁸O data reveal rapid (∼10³ years) excursion of sea-surface temperature at the boundary where an initial cold pulse is followed by a persistent warm period. The δ¹³C data, in contrast, indicate only a gradual change in productivity across the boundary. The observations suggest a biogeochemical scenario for the boundary event pertaining to shallow epicontinental seas.     

Alteration of volcanic glass to well-crystallized ferrosaponite in the vesicles of the Deccan trap basalts at Bhuleshwar Ghat section,Pune district,Maharashtra

Clay minerals formed mainly by the alteration of volcanic glass are reported by many workers. The commonly formed minerals belonging to the smectite group especially nontronite and ferrosaponite are widely reported by many in basalts. However, most of the reports suggest the formation of ferrosaponite in marine conditions (Zhou et al., 1992; Chen et al., 1996) or by hydrothermal solutions (Shayan et. al., (1988)). Origin of ferrosaponite in continental flood basalts by a mechanism of alteration of volcanic glass to ferrosaponite is reported in the paper. The different stages involved in the alteration process are also highlighted.     

Early Eocene calcareous algae and benthic foraminifera from Meghalaya,NE India: A new record of microfacies and palaeoenvironment

Early Eocene carbonate sediments of the Umlatdoh Limestone (Meghalaya, N-E India) represent a shallow marine shelf environment. The major biotic components characterizing these carbonates are calcareous green algae and small to larger benthic foraminifera. Based on the biogenic associations and general sedimentological features, five major facies types (MFTs) are distinguished. They are dominated by poor to moderately sorted grainstones followed by packstones, rudstones and wackestones. Considerable abundance of Halimeda, scarcity of z-corals and poor to moderate occurrence of filter-feeding organisms imply mesotrophic to a slightly oligotrophic nutrient regime. Rare occurrence of geniculate coralline algae is probably due to the lack of suitable substrate and environmental conditions. High incidence of grainstones and packstones, fairly preserved microfossils and few reworked specimens indicate a parautochthonous mode of deposition. Preponderance of Alveolina and Nummulites indicate the possible advent of larger foraminiferal turnover (LFT) in the east Tethys during or even before early Eocene. A conceptual palaeoenvironmental model for the studied succession is provided to showcase various facies gradients, bathymetry levels and shelf zones pertinent to the Umlatdoh Limestone.     

Climate‐modulated sequence development in a tropical rift basin during the Late Palaeocene to Early Eocene super greenhouse Earth

Sequence developments in rift basins are considered to be influenced largely by tectonics and to a lesser extent by eustatic sea‐level and climate. Studies indicate that in passive margin basins, climate can mask the effects of tectonics and eustasy by modulating the sediment supply. It is, however, less understood how the sedimentary sequence in rift basins might respond to strong climatic fluctuations where tectonic pulses generate rapid accommodation space. Here a case study has been provided to assess the effect of climate vis à vis sea‐level and tectonics on sequence development in the Cambay rift basin, western India, during the Early Palaeogene (Late Palaeocene to Early Eocene) super greenhouse globe. Facies analysis of this shale–lignite sequence suggests deposition in a lagoon/bay, developed over the Deccan Trap basement. Detailed sequence stratigraphic analysis using basin‐wide representative composite sections, marker lignite seam, event bed and high‐resolution carbon isotope (δ¹³C) chemostratigraphy suggest an overall transgressive motif. Among the three prominent Early Eocene eustatic highstands, only the one at ca 53·7 Ma is expressed by the thickest coal accumulation throughout the basin. Expression of the other sequence stratigraphic surfaces is subdued and can be due to the overall finer grain size of the sediment or local variation in the subsidence rate at different fault‐controlled mini‐basins. Enigmatic presence of a maximum flooding surface coinciding with the 53·7 Ma climate event (Eocene Thermal Maximum 2), manifested by negative carbon isotope excursion, indicates possible influence of climate over and above tectonics in developing the rift sequence. Qualitative rainfall variation assessed using the magnitude of the carbon isotope excursion and pollen abundance show that a relatively dry/low precipitation climatic phase during the Eocene Thermal Maximum 2 hindered the siliclastic supply to the basin. Thus, it has been inferred that climate‐induced high siliciclastic supply possibly enhanced the autocyclic reorganization and hindered the development of the key sequence stratigraphic surfaces across the basin during climate extremes.     

Can an annual flood induce changes in channel geomorphology?

The present study has been a pioneering effort examining the role of an annual flood as a potent stimulus inducing changes in channel geomorphology of the Mayurakshi River, India. Twenty cross sections have been considered for the measurement of various hydro-geomorphic attributes of the river in both the pre- and post-flood conditions in 2018. The study sensed an escalating trend for channel width, width/depth ratio, and wetted perimeter while the reverse was also detected for average depth, maximum depth, cross-sectional area, and hydraulic radius. For example, the width/depth ratio recorded an increase of?~?11%, and the hydraulic radius depicted a decrease of?~?8%. Furthermore, channel asymmetry, bed asymmetry and bed relief index experienced a decrease after the flood. The sudden hydraulic impulse during monsoon flood as manifested in velocity, discharge, specific stream power, Reynolds number, Froude number increases the erosivity of the fluid. Besides the hydraulic factors, bank material (massive sandbank susceptible to hydraulic action and mixed bank constituted by alternate bands of sand and silt, and vulnerable to failure by piping action) brings substantial changes in channel morphology. Moreover, anthropogenic interventions such as sand mining are found to play a significant role in channel behaviour. The role of the multiple factors driving the morphological changes of the cross sections has been unpacked using canonical component analysis.

     

Analyzing Animal Movement Characteristics From Location Data

When individuals of a species utilize an environment, they generate movement patterns at a variety of spatial and temporal scales. Field observations coupled with location technologies (e.g. GPS tags) enable the capture of detailed spatio‐temporal data regarding these movement patterns. These patterns contain information about species‐specific preferences regarding individual decision‐making, locational choices and the characteristics of the habitat in which the animal resides. Spatial Data Mining approaches can be used to extract repeated spatio‐temporal patterns and additional habitat preferences hidden within large spatially explicit movement datasets. We describe a method to determine the periodicity and directionality in movement exhibited by a migratory bird species. Results using a High Arctic‐nesting Svalbard Barnacle Goose movement data yielded undetected patterns that were secondarily corroborated with expert field knowledge. Individual revisits by the geese to specific locations in the breeding and wintering grounds of Svalbard, Norway and Solway, Scotland, occurred with a periodicity of 334 days . Further, the orientation of this movement was detected to be mostly north‐south. During long‐range migration the geese use the north‐south oriented Norwegian islands as “stepping stones”, Short‐range movement between mudbank roosts to feeding fields in Solway also retained a north‐south orientation.