Assessing redox properties of standard humic substances

Redox properties of humic substances (HS) control important biogeochemical processes. Thus, accurate estimation of redox properties of HS is essential. However, there is no general consensus regarding the best available measurement method of HS redox properties. In this study, we compared several common HS redox property measurement methods using anthraquinone-2,6-disulfonate (AQDS) as model compound, and standard Elliot soil humic acid (1S102H, ESHA), reference Pahokee peat (1R103H, PPHA), and Suwannee River natural organic matter (1R101N, SRNOM) as representative HS. We found that the H₂/Pd reduction method followed by incubation with ferric citrate (FeCit) reagent was incomplete, and the H₂/Pd reduction method followed by incubation with potassium ferricyanide (K₃Fe(CN)₆) was insensitive. Stannous chloride (SnCl₂) reduction followed by titration of excess stannous (Sn²⁺) by potassium dichromate (K₂Cr₂O₇) was found to be most accurate. These findings will help in future investigations on detailed characterizations of functional groups of HS responsible for oxidation/reduction reactions.     

Trend analysis and ARIMA modelling of pre-monsoon rainfall data for western India

Spatial and temporal variability of rainfall over different seasons influence physical, social and economic parameters. Pre-monsoon (March, April and May – MAM) rainfall over the country is highly variable. Since heat lows and convective rainfall in MAM have an impact on the intensity of the ensuing monsoons, hence the pre-monsoon period was chosen for the study. The pre-whitened Mann Kendall test was used to explore presence of rainfall trend during MAM. The results indicate presence of significant (at 10% level) increasing trend in two stations (Ajmer, Bikaner). The practical significance of the change in rainfall was also explored as percentage changes over long term mean, using Theil and Sen's median slope estimator. Forecast using univariate ARIMA model for pre-monsoon months indicates that there is a significant rise in the pre-monsoon rainfall over the northwest part of the country.     

Estimation of causative fault parameters of the Rudbar earthquake of June 20, 1990 from near field SH-wave data

We analyze the strong motion accelerograms recorded for the large (M_S=7.7, M_W=7.3, m_b=6.4) Rudbar earthquake of June 20, 1990. The earthquake had a complex source process. We have identified the imprints of rupture of three localized asperities on the major causative fault on the accelerograms. These asperities are interpreted to correspond to (i) the main shock that initiated the rupture process and was located in the domino block between the Kabateh and Zard Goli faults, (ii) a foreshock that occurred about 10 s earlier in the Kabateh fault and (iii) a later shock, on the western end of the Baklor fault, which terminated the bilateral rupture process at the western end. We estimate the strike, dip and slip of these causative sub-event rupture planes using the SH spectral amplitudes, based on a point source representation of sub-events and a non-linear least square formulation for inversion of the amplitude data. The results of our inversion of the near field data are comparable to other studies based on teleseismic data.     

Deformation behavior of migmatites: insights from microstructural analysis of a garnet–sillimanite–mullite–quartz–feldspar-bearing anatectic migmatite at Rampura–Agucha,Aravalli–Delhi Fold Belt,NW India

International Journal of Earth Sciences - In the present study we investigate the microstructural development in mullite, quartz and garnet in an anatectic migmatite hosted within a Grenvillian-age...     

An analytical source function for a coupled hybrid wave model

An analytical form for the source function is formulated by comparing the fetch-limited approximation of the Ocean Wave Transport equation and the empirical equation for the fetch-dependent wave forecast nomograms. The source function thus generated has been utilised in the numerical model based on Toba’s formulation of wave transport equation and tested for the seas around the Indian subcontinent (5°S to 25°N latitude; 45°E to 100°E longitude). The grid averaged hindcast wave heights are found to be moderately matching with the GEOSAT altimeter measured significant wave heights of the 1987–1989 period, particularly for waves higher than 1 meter.     

Sharp depletion of atmospheric refractive index associated with Nor��wester over Gangetic West Bengal: a possible method of forecasting Nor��wester

The paper presents the nature of the variation of refractive index of atmospheric medium with time and altitude before, during and after the onset of thunderstorms over Gangetic West Bengal during the pre-monsoon period. A critical analysis shows that sharp depletion of the refractive index takes place before the onset of Nor??westers and possible explanations are also offered for the said occurrence.     

Mercury enrichments in core sediments in Hugli–Matla–Bidyadhari estuarine complex,north-eastern part of the Bay of Bengal and their ecotoxicological significance

Mercury concentrations (Hg_T) in fine-grained fraction (<63 μm) of core sediments of the Hugli–Matla–Bidyadhari estuarine complex, India were analyzed. Results revealed a wide range of spatial variations (<4–93 ng g⁻¹ dry weight) with a definite enhancement level at the lower stretch of the estuarine complex infested with mangrove plants, which might act as a sink to Hg_T. An elevated concentration of Hg was encountered in surface/subsurface layer of the core in majority of the cases resulting from physical, biogenic and postdepositional diagenetic processes that remobilized and resuspended the metal from deeper sediments. A strong positive correlation was observed between the Hg and clay fraction content of the sediments, while the correlations of Hg with Al, Fe and Mn were poor. Based on the index of geoaccumulation (I _geo) and effects range-low (ER-L) value, it is considered that the sediments are less polluted and thus there is less chance of ecotoxicological risk to organisms living in sediments.     

Derivations of coupled equations appropriate to the lower regions of the ionosphere

Coupled equations are derived for different ionospheric parameters through susceptibility dyadic appropriate to the medium. The nature of dispersion within the medium is studied.     

A multivariate statistical study of copper mineralization in the central section of Mosaboni Mine, Eastern Singhbhum, India

A multivariate statistical analysis was carried out with log-transformed values of Cu, Ni, Co, Pb, Zn, Ag, Cr, Mn, Ca, and Sr in several sets of samples collected across the mineralized base metal zone in sheared soda granite, feldspathic schist, and chlorite schist from the central section of Mosaboni Mine of the famous Singhbhum Copper Belt of eastern India. Linear correlation coefficient matrices of two sets of ore samples (>0.5% Cu)—one from levels 18 and 21 and the other from levels 25 and 28—indicate two well-defined and distinct clusters comprising Cu, Ni, Co, Pb, and Zn on one hand and Ca, Sr, and Mn on the other. Varimax-rotatedR-mode factor analysis of two above-noted sample sets, taken along with available geologic information, indicates that over 80% of the variability in data matrices for 9–10 elements can be accounted for by four distinct processes: (a) an early phase of copper mineralization which apparently replaced Mn, Ca, and Sr in the host rock; (b) a silicate-cum-oxide phase of crystallization/recrystallization of host rock; (c) remobilization of sulfide-forming ore elements (Cu, Ni, Co, Pb, and Zn); and (d) a phase of mineralization of Ag which appears to have replaced Cr, Ca and Cu. Process (c) was quantitatively most important. Factor score studies are suggestive of preferred introduction of Ni, Co, Pb, and Zn along central parts of preexisting copper-mineralized zones.     

Influence of plastic fines content on the liquefaction susceptibility of sands: monotonic loading

Acta Geotechnica - The paper presents an experimental study on the effect of plastic fines content on the undrained behavior and liquefaction susceptibility of sand–fines mixtures under...