Distribution and bioaccumulation of polychlorinated biphenyls and organochlorine pesticides residues in sediments and Manila clams (Ruditapes philippinarum) from along the Mid-Western coast of Korea

The distribution and bioaccumulation features of PCBs, DDTs, and HCHs were investigated in the sediments and Manila clams collected from along the Mid-Western coast of Korea. The measured concentrations of ΣPCBs, ΣDDTs and ΣHCHs were 1.08–3.5, 0.12–0.35 and 0.090–0.30 ng g⁻¹ dw in sediment, and 33–390, 7.4–46 and 6.3–27 ng g⁻¹ lipid in Manila clam, respectively. Their levels were found to be relatively lower than those of other contaminated areas and the consumption of Manila clam from these areas seems to be safe for human health according to calculated lifetime cancer risk and hazard indices. The ΣPCBs and ΣDDTs concentrations in sediments showed a significant relationship to those in clams. The significant correlation was observed between BSAF in clams and K_ow for each PCB congeners and DDT metabolites. These findings support that the PCBs and DDTs levels, which are highly hydrophobic chemicals, in clam reflect the sediment pollution through bioaccumulation.     

Suction force below plate anchors in soft clay

The results of a number of laboratory model tests for the short‐term ultimate uplift capacity of a circular plate anchor embedded in saturated soft kaolinite and montmorillonite are presented. The tests were conducted with and without venting the bottom of the plate anchor in order to determine the variation of the suction force with embedment ratio. The variation of the suction force is presented in terms of the undrained shear strength of the clay and also the net ultimate uplift capacity.     

Frequency‐domain acoustic‐elastic coupled waveform inversion using the Gauss‐Newton conjugate gradient method

We developed a frequency‐domain acoustic‐elastic coupled waveform inversion based on the Gauss‐Newton conjugate gradient method. Despite the use of a high‐performance computer system and a state‐of‐the‐art parallel computation algorithm, it remained computationally prohibitive to calculate the approximate Hessian explicitly for a large‐scale inverse problem. Therefore, we adopted the conjugate gradient least‐squares algorithm, which is frequently used for geophysical inverse problems, to implement the Gauss‐Newton method so that the approximate Hessian is calculated implicitly. Thus, there was no need to store the Hessian matrix. By simultaneously back‐propagating multi‐components consisting of the pressure and displacements, we could efficiently extract information on the subsurface structures. To verify our algorithm, we applied it to synthetic data sets generated from the Marmousi‐2 model and the modified SEG/EAGE salt model. We also extended our algorithm to the ocean‐bottom cable environment and verified it using ocean‐bottom cable data generated from the Marmousi‐2 model. With the assumption of a hard seafloor, we recovered both the P‐wave velocity of complicated subsurface structures as well as the S‐wave velocity. Although the inversion of the S‐wave velocity is not feasible for the high Poisson's ratios used to simulate a soft seafloor, several strategies exist to treat this problem. Our example using multi‐component data showed some promise in mitigating the soft seafloor effect. However, this issue still remains open.     

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.     

Evolution processes of Ordovician–Devonian arc system in the South‐Kitakami Massif and its relevance to the Ordovician ophiolite pulse

The South Kitakami Massif is one of the oldest geological domains in Japan having Silurian strata with acidic pyroclastic rocks and Ordovician–Silurian granodiorite–tonalite basement, suggesting that it was matured enough to develop acidic volcanisms in the Silurian period. On the northern and western margin of the South Kitakami Massif, an Ordovician arc ophiolite (Hayachine–Miyamori Ophiolite) and high‐pressure and low‐temperature metamorphic rocks (Motai metamorphic rocks) exhumed sometime in the Ordovician–Devonian periods are distributed. Chronological, geological, and petrochemical studies on the Hayachine–Miyamori Ophiolite, Motai metamorphic rocks, and other early Paleozoic geological units of the South Kitakami Massif are reviewed for reconstruction of the South Kitakami arc system during Ordovician to Devonian times with supplementary new data. The reconstruction suggests a change in the convergence polarity from eastward‐ to westward‐dipping subduction sometime before the Late Devonian period. The Hayachine–Miyamori Ophiolite was developed above the eastward‐dipping subduction through three distinctive stages. Two separate stages of overriding plate extension inducing decompressional melting with minor involvement of slab‐derived fluid occurred before and after a stage of melting under strong influence of slab‐derived fluids. The first overriding plate extension took place in the back‐arc side forming a back‐arc basin. The second one took place immediately before the ophiolite exhumation and near the fore‐arc region. We postulate that the second decompressional melting was triggered by slab breakoff, which was preceded by slab rollback inducing trench‐parallel wedge mantle flow and non‐steady fluid and heat transport leaving exceptionally hydrous residual mantle. The formation history of the Hayachine–Miyamori Ophiolite implies that weaker plate coupling may provide preferential conditions for exhumation of very hydrous mantle. Very hydrous peridotites involved in arc magmatism have not yet been discovered except for in the Cambrian–Ordovician periods, suggesting its implications for global geodynamics, such as the thermal state and water circulation in the mantle.     

Reduction of future disaster damages by learning from disaster experiences

This paper examines the effect of a country’s own past disaster experiences and nearby countries’ past experiences on subsequent disaster damage. We use global disaster data from 1990 to 2010, which include disaster-related death tolls for both natural and technological disasters that are further divided into sub-categories. Overall, we find evidence of a reduction effect of past disaster damage on future disaster damage. More detailed analyses show that an adaptation effect seems to be present for certain combinations of disaster types and levels of economic development. The results show that a country’s own experiences reduce future damage for natural disasters but that the marginal effect is larger for lower-income countries. On the other hand, for technological disasters, a robust impact of experiences was found only in higher-income countries. In terms of the disaster experiences of nearby countries, the adaptation effect was found only for natural disasters, and the marginal impact was relatively higher for higher-income countries.     

Acoustic full waveform inversion of synthetic land and marine data in the Laplace domain

Elastic waves, such as Rayleigh and mode‐converted waves, together with amplitude versus offset variations, serve as noise in full waveform inversion using the acoustic approximation. Heavy preprocessing must be applied to remove elastic effects to invert land or marine data using the acoustic inversion method in the time or frequency domains. Full waveform inversion using the elastic wave equation should be one alternative; however, multi‐parameter inversion is expensive and sensitive to the starting velocity model. We implement full acoustic waveform inversion of synthetic land and marine data in the Laplace domain with minimum preprocessing (i.e., muting) to remove elastic effects. The damping in the Laplace transform can be thought of as an automatic time windowing. Numerical examples show that Laplace‐domain acoustic inversion can yield correct smooth velocity models even with the noise originating from elastic waves. This offers the opportunity to develop an accurate smooth starting model for subsequent inversion in the frequency domain.     

Organohalogen compounds in deep-sea fishes from the western North Pacific, off-Tohoku, Japan: Contamination status and bioaccumulation profiles

Twelve species of deep-sea fishes collected in 2005 from the western North Pacific, off-Tohoku, Japan were analyzed for organohalogen compounds. Among the compounds analyzed, concentrations of DDTs and PCBs (up to 23,000 and 12,400 ng/g lipid wt, respectively) were the highest. The present study is the foremost to report the occurrence of brominated flame retardants such as PBDEs and HBCDs in deep-sea organisms from the North Pacific region. Significant positive correlations found between δ¹⁵N (‰) and PCBs, DDTs and PBDEs suggest the high biomagnification potential of these contaminants in food web. The large variation in δ¹³C (‰) values observed between the species indicate multiple sources of carbon in the food web and specific accumulation of hydrophobic organohalogen compounds in benthic dwelling carnivore species like snubnosed eel. The results obtained in this study highlight the usefulness of deep-sea fishes as sentinel species to monitor the deep-sea environment.     

Fatty acid profiles of benthic environment associated with artificial reefs in subtropical Hong Kong

Artificial reefs can enhance habitat heterogeneity, especially in seabed degraded by bottom-dredging and trawling. However, the trophodynamics of such reef systems are not well understood. This study provided baseline data on trophic relationships in the benthic environment associated with artificial reefs in late spring and mid summer of subtropical Hong Kong, using fatty acid profiles as an indicator. Data from sediments collected at the reef base, materials from sediment traps deployed on top and bottom of the reefs, total particulate matter from the water column and oyster tissues from reef surface were subjected to principal component analysis. Results showed variations of fatty acid profiles in the total particulate matter, upper sediment trap and oyster tissue samples collected in the two samplings, indicating seasonal, trophodynamic changes within the reef system. The wastes produced by fish aggregating at the reefs can also contribute a source of biodeposits to the nearby benthic environment.