Sulfur volcanism on Io

In February 2003, March 2003 and January 2004 Pele plume transmission spectra were obtained during Jupiter transit with Hubble's Space Telescope Imaging Spectrograph (STIS), using the 0.1″ wide slit and the G230LB grating. The STIS spectra covered the 2100-3100 Å wavelength regions and extended spatially along Io's limb encompassing the region directly above and northward of the vent of the Pele volcano. The S₂ and SO₂ absorption signatures evident in these data indicate that the gas signature at Pele was temporally variable, and that an S₂ absorption signature was present ∼12° from the Pele vent near 6±5 S and 264±15 W, suggesting the presence of another S₂ bearing plume on Io. Contemporaneous with the spectral data, UV and visible-wavelength images of the plume were obtained in reflected sunlight with the Advanced Camera for Surveys (ACS) prior to Jupiter transit. The dust scattering recorded in these data provide an additional qualitative measure of plume activity on Io, indicating that the degree of dust scattering over Pele varied as a function of the date of observation, and that there were several other dust bearing plumes active during the observations. We present constraints on the composition and variability of the gas abundances of the Pele plume as well as the plumes detected by ACS and recorded within the STIS data, as a function of time.     

Low-background gamma counting: applications for210Pb dating of sediments

Sediment cores from three lakes were dated with²¹⁰Pb using a constant rate of supply (CRS) model. We used low-background gamma counting to measure naturally occurring levels of²¹⁰Pb,²²⁶Ra, and¹³⁷Cs in sediment samples because sample preparation is simple and non-destructive,²²⁶Ra activity provides a direct measure of supported²¹⁰Pb activity for each sample analyzed, and¹³⁷Cs activity may provide an independent age marker for the 1962–1963 peak in atmospheric fallout of this radionuclide. In one core supported²¹⁰Pb activity was estimated equally well from²²⁶Ra activity of each sampling interval or from the mean total²¹⁰Pb activity of constant activity samples at depth. Supported²¹⁰Pb activity was constant with depth in this core. In a short freeze core, determining²²⁶Ra activity of every sample proved advantageous in estimating supported²¹⁰Pb activity because supported²¹⁰Pb activity could be estimated from²¹⁰Pb measurements only at the deepest sampling interval. Supported²¹⁰Pb activity estimated from²²⁶Ra activity also yielded more precise estimates of highly variable sedimentation rates. In the third core²²⁶Ra activity exceeded²¹⁰Pb activity at the top of the core and varied 20 fold with depth. This high input of²²⁶Ra in disequilibrium with²¹⁰Pb is attributed to recent erosion of radium-bearing materials in the drainage basin. These data invalidate the assumption that supported²¹⁰Pb activity is constant in sediment cores and can be estimated from the mean total²¹⁰Pb activity at depths where²¹⁰Pb activity is constant. We recommend using gamma counting or another independent assay of²²⁶Ra to validate the assumption of constant supported²¹⁰Pb activity in sediment cores if there is reason to expect that²²⁶Ra activity varies with depth.This is the fourth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr. P.G. Appleby is guest editing this series.     

210Pb/226Ra and 210Po/210Pb disequilibria in seawater and suspended particulate matter

The distribution of²¹⁰Po and²¹⁰Po in dissolved (<0.4 μm) and particulate (>0.4 μm) phases has been measured at ten stations in the tropical and eastern North Atlantic and at two stations in the Pacific. Both radionuclides occur principally in the dissolved phase. Unsupported²¹⁰Pb activities, maintained by flux from the atmosphere, are present in the surface mixed layer and penetrate into the thermocline to depths of about 500 m. Dissolved²¹⁰Po is ordinarily present in the mixed layer at less than equilibrium concentrations, suggesting rapid biological removal of this nuclide. Particulate matter is enriched in²¹⁰Po, with²¹⁰Po/²¹⁰Pb activity ratios greater than 1.0, similar to those reported for phytoplankton. Box-model calculations yield a 2.5-year residence time for²¹⁰Pb and a 0.6-year residence time for²¹⁰Po in the mixed layer. These residence times are considerably longer than the time calculated for turnover of particles in the mixed layer (about 0.1 year). At depths of 100–300 m,²¹⁰Po maxima occur and unsupported²¹⁰Po is frequently present. Calculations indicate that at least 50% of the²¹⁰Po removed from the mixed layer is recycled within the thermocline. Similar calculations for²¹⁰Pb suggest much lower recycling efficiencies.Comparison of the²¹⁰Pb distribution with the reported distribution of²²⁶Ra at nearby GEOSECS stations has confirmed the widespread existence of a²¹⁰Pb/²²⁶Ra disequilibrium in the deep sea. Vertical profiles of particulate²¹⁰Pb were used to test the hypothesis that²¹⁰Pb is removed from deep water by in-situ scavenging. With the exception of one profile taken near the Mid-Atlantic Ridge, significant vertical gradients in particulate²¹⁰Pb concentration were not observed, and it is necessary to invoke exceptionally high particle sinking velocities to account for the inferred²¹⁰Pb flux. It is proposed instead that an additional sink for²¹⁰Pb in the deep sea must be sought. Estimates of the dissolved²¹⁰Pb/²²⁶Ra activity ratio at depths greater than 1000 m range from 0.2 to 0.8 and reveal a systematic increase, in both vertical and horizontal directions, with increasing distance from the sea floor. This observation implies rapid scavenging of²¹⁰Pb at the sediment-water interface and is consistent with a horizontal eddy diffusivity of 3?6 × 10⁷ cm²/sec. The more reactive element Po, on the other hand, shows evidence of rapid in-situ scavenging. In filtered seawater,²¹⁰Po is deficient, on the average, by ca. 10% relative to²¹⁰Pb; a corresponding enrichment is found in the particulate phase. Total inventories of²¹⁰Pb and²¹⁰Po over the entire water column, however, show no significant departure from secular equilibrium.     

Coastal morphology and late quaternary history,Cayman Islands,West Indies

Instrumental surveys of coastal profiles in the Cayman Islands, western Caribbean, reveal the presence of a horizontal erosional bench at +1.9 m on Grand Cayman and a deep horizontal notch at +6.4 m on Cayman Brac, but no raised erosional features on Little Cayman. Each island is surrounded by a horizontal constructional raised reef, usually below +2 m, here dated by U-series methods as 124,000 ± 8000 yr old, and hence broadly contemporary with other western Atlantic raised reefs of similar elevations. The different raised erosional features indicate independent vertical tectonic movement of the three islands, predating the formation of the raised reef. The accordance and horizontality of the raised reef indicates stability of the islands since the last interglacial times. An erosional notch at present sea level has formed since the sea reached its present level less than 2100 B.P., and algal benches on exposed coasts are also in equilibrium with present conditions.     

Hybrid seismic protection of cable‐stayed bridges

This paper proposes a hybrid control strategy combining passive and semi‐active control systems for seismic protection of cable‐stayed bridges. The efficacy of this control strategy is verified by examining the ASCE first‐generation benchmark problem for a seismically excited cable‐stayed bridge, which employs a three‐dimensional linearized evaluation bridge model as a testbed structure. Herein, conventional lead–rubber bearings are introduced as base isolation devices, and semi‐active dampers (e.g., variable orifice damper, controllable fluid damper, etc.) are considered as supplemental damping devices. For the semi‐active dampers, a clipped‐optimal control algorithm, shown to perform well in previous studies involving controllable dampers, is considered. Because the semi‐active damper is a controllable energy‐dissipation device that cannot add mechanical energy to the structural system, the proposed hybrid control strategy is fail‐safe in that the bounded‐input, bounded‐output stability of the controlled structure is guaranteed. Numerical simulation results show that the performance of the proposed hybrid control strategy is quite effective in protecting seismically excited cable‐stayed bridges. Copyright © 2004 John Wiley & Sons, Ltd.     

Spatial variability of metals in the inter-tidal sediments of the Medway Estuary,Kent, UK

Concentrations of major and trace metals were determined in eight sediment cores collected from the inter-tidal zone of the Medway Estuary, Kent, UK. Metal associations and potential sources have been investigated using principal component analysis. These data provide the first detailed geochemical survey of recent sediments in the Medway Estuary. Metal concentrations in surface sediments lie in the mid to lower range for UK estuarine sediments indicating that the Medway receives low but appreciable contaminant inputs. Vertical metal distributions reveal variable redox zonation across the estuary and historically elevated anthropogenic inputs. Peak concentrations of Cu, Pb and Zn can be traced laterally across the estuary and their positions indicate periods of past erosion and/or non-deposition. However, low rates of sediment accumulation do not allow these sub surface maxima to be used as accurate geochemical marker horizons. The salt marshes and inter-tidal mud flats in the Medway Estuary are experiencing erosion, however the erosion of historically contaminated sediments is unlikely to re-release significant amounts of heavy metals to the estuarine system.