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Twentieth century environmental lead chronologies for the western North Atlantic, Pacific, and Indian Oceans have been reconstructed from annually-banded scleractinian corals. Measurements of lattice-bound Pb in sequential coral bands reveal temporal changes in surface water Pb concentrations and Pb isotopic distributions. Perturbations are observable in all specimens studied, attesting to global augmentation of environmental Pb by industrialization.In the western North Atlantic, Pb perturbations have occurred in direct response to the American industrial revolution and the subsequent introduction and phasing-out of alkyl Pb additives in gasoline. Surface ocean conditions near Bermuda may be reliably reconstructed from the coral data via a lead distribution coefficient of 2.3 for the species,Diploria strigosa. Based on210Pb measurements, a similar distribution coefficient may be characteristic of corals in general. Surface Pb concentrations in the pre-industrial Sargasso Sea were about 15–20 pM. Concentrations rose to near 90 pM by 1923 as a result of metals manufacture and fossil fuel combustion. Beginning in the late 1940's, increased utilization of leaded gasoline eventually led to a peak concentration of 240 pM in 1971, representing an approximate 15-fold increase over background. Surface ocean concentrations are presently declining rapidly (128 pM in 1984) as a result of curtailed alkyl Pb usage. Lead isotopic shifts parallel the concentration record indicating that characteristic industrial and alkyl Pb source signatures have not changed appreciably in time. Industrial releases recorded in the Florida Keys reflect a weaker source and evidence of recirculated Pb (5–6 years old) from the North Atlantic subtropical gyre. An inferred background concentration of 38 pM suggests influence of shelf and/or resuspended inputs of Pb to these coastal waters.In remote areas of the South Pacific and Indian Oceans, industrial signals are fainter and the corals studied much younger than their Atlantic counterparts. Contemporary Pb concentrations implied by coral measurements (assumingKD = 2.3) are 40–50 pM for surface waters near Tutuila and Galapagos in the South Pacific, and 25–29 pM near Mauritius in the Indian Ocean. A single coral band from Fiji (1920 ± 5yr) implies a pre-industrial surface water concentration of 16–19 pM Pb for the South Pacific. In view of reported surface water measurements and the North Atlantic coral data, the Pacific coral extrapolations may be slightly high. This could be a result of small variations inKD among different coral genera, or incorporation of diagenetic Pb by corals sampled in coastal environments. 相似文献
44.
On the radiation and diffraction of linear water waves by an infinitely long rectangular structure submerged in oblique seas 总被引:1,自引:0,他引:1
The radiation and diffraction of linear water waves by an infinitely long rectangular structure submerged in oblique seas of finite depth is investigated. The analytical expressions for the radiated and diffracted potentials are derived as infinite series by use of the method of separation of variables. The unknown coefficients in the series are determined by the eigenfunction expansion matching method. The expressions for wave forces, hydrodynamic coefficients and reflection and transmission coefficients are given and verified by the boundary element method. Using the present analytical solution, the hydrodynamic influences of the angle of incidence, the submergence, the width and the thickness of the structure on the wave forces, hydrodynamic coefficients, and reflection and transmission coefficients are discussed in detail. 相似文献
45.
长江河口径流与盐度的谱分析 总被引:9,自引:1,他引:9
根据大通水文站的流量和引水船站的盐度系列资料,应用谱分析方法研究长江口径流、盐度的变化规律及两者的相互关系.分析表明,长江口径流存在4~8a,2~3a,1.5a,1a,30~60d及20d的及化周期;盐度存在5~10a,2~3a,1.5a,1a,0.5a,40~50d,26~30d,14~15d7~8d及3.5d的变化周期.径流和盐度的谱结构在各水文年基本一致,均以1a周期变化占优势,但盐度谱结构在高频部分较径流的谱结构具有更大的振荡.盐度与流量的5~10a,2~3a,1.5a,1a的周期振动上存在高相关.径流对盐度变化的影响主要体现在低频部分.在低频变化中表现为盐度变化滞后于径流变化,在高频带呈同步变化. 相似文献
46.
溞对中国对虾早期幼体的循环系统及血液流向进行了活体观察 ,描述了中国对虾早期幼体发育阶段中幼体循环系统血管的走向与分布、血液的流向及循环路径等 ,比较各期幼体循环系统的形态 ,并探讨对虾早期幼体循环系统的发育过程。 相似文献
47.
作者以 Sm Cl3 与 (CH3 Cp) Na反应分离得到了三价稀土有机配合物 [(CH3 Cp) 2 Sm Cl·THF]2 的单晶 ,X-射线四圆衍射测定 ,该配合物属正交晶系 ,Pbna空间群 ,晶胞参数 a=9.6 6 2 (2 ) ,b=16 .4 76 (9) ,c=2 0 .582 (9) ;α=β=γ=90°,Z=4。并分析比较 [(CH3 Cp) 2 Sm Cl· THF]2 与其他三价稀土一氯化物的结构特点 相似文献
48.
A numerical modeling study of the influence of the lateral flow on the estuarine exchange flow was conducted in the north passage of the Changjiang estuary. The lateral flows show substantial variabilities within a flood-ebb tidal cycle. The strong lateral flow occurring during flood tide is caused primarily by the unique cross-shoal flow that induces a strong northward (looking upstream) barotropic force near the surface and advects saltier water toward the northern part of the channel, resulting in a southward baroclinic force caused by the lateral density gradient. Thus, a two-layer structure of lateral flows is produced during the flood tide. The lateral flows are vigorous near the flood slack and the magnitude can exceed that of the along-channel tidal flow during that period. The strong vertical shear of the lateral flows and the salinity gradient in lateral direction generate lateral tidal straining, which are out of phase with the along-channel tidal straining. Consequently, stratification is enhanced at the early stage of the ebb tide. In contrast, strong along-channel straining is apparent during the late ebb tide. The vertical mixing disrupts the vertical density gradient, thus suppressing stratification. The impact of lateral straining on stratification during spring tide is more pronounced than that of along-channel straining during late flood and early ebb tides. The momentum balance along the estuary suggests that lateral flow can augment the residual exchange flow. The advection of lateral flows brings low-energy water from the shoal to the deep channel during the flood tide, whereas the energetic water is moved to the shoal via lateral advection during the ebb tide. The impact of lateral flow on estuarine circulation of this multiple-channel estuary is different from single-channel estuary. A model simulation by blocking the cross-shoal flow shows that the magnitudes of lateral flows and tidal straining are reduced. Moreover, the reduced lateral tidal straining results in a decrease in vertical stratification from the late flood to early ebb tides during the spring tide. By contrast, the along-channel tidal straining becomes dominant. The model results illustrate the important dynamic linkage between lateral flows and estuarine dynamics in the Changjiang estuary. 相似文献
49.
核电厂的楼层反应谱分析是核电厂房主结构和设备子系统抗震设计的主要依据.楼层谱计算方法可分为2种类型,一种是通过地震动反应谱输入直接得到楼层谱的计算方法,简称直接法;另一种是通过地震波输入的时程分析计算方法,简称时程法,文中主要研究前者.首先简要评述了几种具代表性的直接法,例如Biggs方法、Kaput方法、Singh方法等,并对它们的优缺点进行了分析.然后总结了我们的工程经验,并在Biggs和Kapur方法的基础上,提出一种修正模态法,既考虑了结构-地基动力相互作用的影响,又计算简便易行,也可获得比较满意的精确度. 相似文献
50.