Significant photodegradation of chromophoric dissolved organic matter (CDOM) in rainwater was observed after exposure to simulated
sunlight. Fluorescence excitation emission spectra (EEMS) of precipitation revealed the presence of four major peaks all of
which degraded upon photolysis with the greatest loss in the region characteristic of marine CDOM. Photobleaching of absorbance
also occurred in the wavelength region between 250 and 375 nm with the greatest loss of absorbance in the upper end of the
UV-A region near 275 nm. There was a strong positive correlation between absorbance loss and total integrated fluorescence
loss suggesting these optical properties and the degree to which they are photobleached in rainwater are directly related.
The quantum yield of CDOM photodegradation in rainwater decreased dramatically with increasing wavelength and decreasing energy
of incoming radiation with the average quantum yield at 325 nm approximately an order of magnitude greater than at 460 nm.
The similarity of photolytic response between rainwater and Cape Fear estuarine CDOM indicates that some fraction of the compounds
that make up rainwater CDOM may be derived from surface sources and/or that the processes that produce or modify humic-like
substances in the atmosphere result in similar types of compounds as non-atmospheric processes. 相似文献
Many scholars study when climate change communication increases citizen engagement. Yet, past work has largely used public opinion-based measures of engagement to evaluate alternative frames. In this paper, we argue for a new approach to evaluation, which is premised on research on the policy-making process showing that space on the political agenda and, ultimately, policy change are more likely to arise in response to changes in both public opinion and collective political action. Thus, we argue that alternative frames should be evaluated based on their consequences for both. This is especially critical given that frames can have divergent effects on attitudes and behavior. Using a combination of field and survey experiments, we apply our approach to evaluate two frames related to climate change risks. We find that they heighten people’s concern about climate change yet decrease their rate of political action to express that concern. Our results suggest caution with regard to these frames in particular and that, more generally, frames that might seem advantageous when examining public opinion may not be when political behavior is analyzed.
In the first of four pieces arising from Gill Foulger's challenge to the mantle plume hypothesis (last issue), Carol Stein and Seth Stein join the debate with some data and comment on heat-flow around Iceland. 相似文献
Polycyclic aromatic hydrocarbons (PAHs) are widespread persistent pollutants that readily undergo biotic and abiotic conversion to numerous transformation products in rivers, lakes and estuarine sediments. Here we characterize the developmental toxicity of four PAH transformation products each structural isomers of hydroxynaphthoic acid: 1H2NA, 2H1NA, 2H3NA, and 6H2NA. Medaka fish (Oryzias latipes) embryos and eleutheroembryos were used to determine toxicity. A 96-well micro-plate format was used to establish a robust, statistically significant platform for assessment of early life stages. Individual naphthoic acid isomers demonstrated a rank order of toxicity with 1H2NA > 2H1NA > 2H3NA > 6H2NA being more toxic. Abnormalities of circulatory system were most pronounced including pericardial edema and tube heart. To determine if HNA isomers were AhR ligands, spatial-temporal expression and activity of CYP1A was measured via in vivo EROD assessments. qPCR measurement of CYP1A induction proved different between isomers dosed at respective concentrations affecting 50% of exposed individuals (EC50s). In vitro, all ANH isomers transactivated mouse AhR using a medaka CYP1A promoter specific reporter assay. Circulatory abnormalities followed P450 induction and response was consistent with PAH toxicity. A 96-well micro-plates proved suitable as exposure chambers and provided statistically sound evaluations as well as efficient toxicity screens. Our results demonstrate the use of medaka embryos for toxicity analysis thereby achieving REACH objectives for the reduction of adult animal testing in toxicity evaluations. 相似文献
Dense understory thickets of the native evergreen shrub Rhododendron maximum expanded initially following elimination of American chestnut by the chestnut blight, and later in response to loss of the eastern hemlock due to hemlock woolly adelgid invasion. Rhododendron thickets often blanket streams and their riparian zones, creating cool, low-light microclimates. To determine the effect of such understory thickets on summer stream temperatures, we removed riparian rhododendron understory on 300 m reaches of two southern Appalachian Mountain headwater streams, while leaving two 300 m reference reaches undisturbed. Overhead canopy was left intact in all four streams, but all streams were selected to have a significant component of dead or dying eastern hemlock in the overstory, creating time-varying canopy gaps throughout the reach. We continuously monitored temperatures upstream, within and downstream of treatment and reference reaches. Temperatures were monitored in all four streams in the summer before treatments were imposed (2014), and for two summers following treatment (2015, 2016). Temperatures varied significantly across and within streams prior to treatment and across years for the reference streams. After rhododendron removal, increases in summer stream temperatures were observed at some locations within the treatment reaches, but these increases did not persist downstream and varied by watershed, sensor, and year. Significant increases in daily maxima in treatment reaches ranged from 0.9 to 2.6°C. Overhead canopy provided enough shade to prevent rhododendron removal from increasing summer temperatures to levels deleterious to native cold-water fauna (average summer temperatures remained below 16°C), and local temperature effects were not persistent. 相似文献
This paper presents the analytic element modeling approach implemented in the software AnAqSim for simulating steady groundwater flow with a sharp fresh‐salt interface in multilayer (three‐dimensional) aquifer systems. Compared with numerical methods for variable‐density interface modeling, this approach allows quick model construction and can yield useful guidance about the three‐dimensional configuration of an interface even at a large scale. The approach employs subdomains and multiple layers as outlined by Fitts (2010) with the addition of discharge potentials for shallow interface flow (Strack 1989). The following simplifying assumptions are made: steady flow, a sharp interface between fresh‐ and salt water, static salt water, and no resistance to vertical flow and hydrostatic heads within each fresh water layer. A key component of this approach is a transition to a thin fixed minimum fresh water thickness mode when the fresh water thickness approaches zero. This allows the solution to converge and determine the steady interface position without a long transient simulation. The approach is checked against the widely used numerical codes SEAWAT and SWI/MODFLOW and a hypothetical application of the method to a coastal wellfield is presented. 相似文献
Stream water temperature plays a significant role in aquatic ecosystems where it controls many important biological and physical processes. Reliable estimates of water temperature at the daily time step are critical in managing water resources. We developed a parsimonious piecewise Bayesian model for estimating daily stream water temperatures that account for temporal autocorrelation and both linear and nonlinear relationships with air temperature and discharge. The model was tested at 8 climatically different basins of the USA and at 34 sites within the mountainous Boise River Basin (Idaho, USA). The results show that the proposed model is robust with an average root mean square error of 1.25 °C and Nash–Sutcliffe coefficient of 0.92 over a 2‐year period. Our approach can be used to predict historic daily stream water temperatures in any location using observed daily stream temperature and regional air temperature data. 相似文献
Three dating techniques for metamorphic minerals using the Sm–Nd, Lu–Hf and Pb isotope systems are combined and interpreted in context with detailed petrologic data from crustal segments in NW Namibia. The combination of isochron ages using these different approaches is a valuable tool to testify for the validity of metamorphic mineral dating. Here, PbSL, Lu–Hf and Sm–Nd garnet ages obtained on low- to medium-grade metasedimentary rocks from the Central Kaoko Zone of the Neoproterozoic Kaoko belt (NW Namibia) indicate that these samples were metamorphosed at around 550–560 Ma. On the other hand, granulite facies metasedimentary rocks from the Western Kaoko Zone underwent two phases of high-grade metamorphism, one at ca. 660–625 Ma and another at ca. 550 Ma providing substantial evidence that the 660–625 Ma-event was indeed a major tectonothermal episode in the Kaoko belt. Our age data suggest that interpreting metamorphic ages by applying a single dating method only is not reliable enough when studying complex metamorphic systems. However, a combination of all three dating techniques used here provides a reliable basis for geochronological age interpretation. 相似文献