Reactive Transport Modeling of Subaqueous Sediment Caps and Implications for the Long-Term Fate of Arsenic, Mercury, and Methylmercury

A 1-D biogeochemical reactive transport model with a full set of equilibrium and kinetic biogeochemical reactions was developed to simulate the fate and transport of arsenic and mercury in subaqueous sediment caps. Model simulations (50?years) were performed for freshwater and estuarine scenarios with an anaerobic porewater and either a diffusion-only or a diffusion plus 0.1-m/year upward advective flux through the cap. A biological habitat layer in the top 0.15?m of the cap was simulated with the addition of organic carbon. For arsenic, the generation of sulfate-reducing conditions limits the formation of iron oxide phases available for adsorption. As a result, subaqueous sediment caps may be relatively ineffective for mitigating contaminant arsenic migration when influent concentrations are high and sorption capacity is insufficient. For mercury, sulfate reduction promotes the precipitation of metacinnabar (HgS) below the habitat layer, and associated fluxes across the sediment–water interface are low. As such, cap thickness is a key design parameter that can be adjusted to control the depth below the sediment–water interface at which mercury sulfide precipitates. The highest dissolved methylmercury concentrations occur in the habitat layer in estuarine environments under conditions of advecting porewater, but the highest sediment concentrations are predicted to occur in freshwater environments due to sorption on sediment organic matter. Site-specific reactive transport simulations are a powerful tool for identifying the major controls on sediment- and porewater-contaminant arsenic and mercury concentrations that result from coupling between physical conditions and biologically mediated chemical reactions.     

Recent large fold nucleation in the upper crust: Insight from gravity,magnetic, magnetotelluric and seismicity data (Sierra de Los Filabres–Sierra de Las Estancias,Internal Zones,Betic Cordillera)

Rheological heterogeneities in the upper-crust have a close relationship with the fold position where rigid bodies could constitute initial perturbations that allow the nucleation of folds. Consequently, establish the position and geometry of anomalous rocks located in the upper-crust by geophysical studies help to understand the folded structure observed on surface. New geological observations in the field, along with gravity, magnetic, magnetotelluric and seismicity data, reveal the subsurface structure in the Sierra de Los Filabres–Sierra de Las Estancias folded region part of the Alpine belt in southern Spain. The geometry of the upper crust is determined by geological field data, 2D gravity models, 2D magnetic models and 2D MT resistivity model, while seismicity evidences the location of the deep active structures. These results allow us to propose that a basic rock body at 4 to 9 km depth has determined the nucleation and development of the Sierra de Los Filabres kilometric antiform. N-vergent large late folds are subjected to a variable present-day stress field. Earthquake focal mechanisms suggest the presence in depth of a regional NW–SE compressive stress field. However, most of the seismogenetic structures do not extend up to the surface, where NW–SE and WNW–ESE outcropping active normal faults are observed, thus indicating a NE–SW extension in the upper crust simultaneous to orthogonal NW–SE compression related to reverse faults and minor folds developed in the Eastern Almanzora Corridor and in the nearby Huércal–Overa Basin. The recent and active tectonic studies of cordilleras hinterland subjected to late folding greatly benefits from the integration of surface observations together with geophysical data.     

Prediction of groundwater‐induced flooding in a chalk aquifer for future climate change scenarios

Current climate change models for the southeast UK predict changing rainfall patterns, with increased incidence of extreme events. The chalk aquifer in the UK and northern France is susceptible to groundwater‐induced flooding under such conditions. In this methodological study we apply a frequency domain analysis approach to the chalk aquifer to derive a transfer function between effective rainfall and groundwater level from 7 years of monitoring data from the North Heath Barn site, near Brighton. The derived transfer function was calibrated and validated against monitoring data and then used to predict groundwater level for rainfall models for high, medium and low emission scenarios from the UKCP09 database. The derived transfer function is most closely comparable to the linear aquifer model, despite evidence for both matrix and fracture or karst water flow in the chalk, with transmissivity and unconfined storativity at the catchment scale of 1548 m² day^?1 and 1.6 × 10^?2. The application of the transfer function to UKCP09 rainfall data suggests that groundwater‐induced flooding may be about four times more frequent by 2040–2069 compared with 1961–1990 and seven times more frequent by 2070–2099. The model data also suggest an increase in the duration of groundwater minima relative to the reference period. Compared to deterministic modelling which requires detailed knowledge of aquifer heterogeneity and processes, the transfer function approach, although with limitations, is simpler, incorporating these factors into the analysis through frequency and phase coefficients, and thus may have the potential for groundwater risk assessment in other areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Pito Rift: How a large-offset rift propagates

The Pito Rift area is the site of actively deforming oceanic lithosphere that has been primarily under extension for at least the past million years, based on kinematic reconstructions. The major morphologic features, Pito Deep and Pito Seamount, are aligned toward the Euler pole for relative motion between the Easter and Nazca plates. SeaMARC II side-scan and bathymetry data indicate that there are two general modes of faulting currently active in the Pito Rift area. One is associated with incipient rifting of old (3 Ma) Nazca lithosphere by large NW-SE normal faults, and the other is associated with a broad area of right-lateral transform shear between the Nazca and Easter plates. This transform shear is distributed over a broad region because of the northward growth of the East Rift and parallel tectonic rifting within the Pito Rift area. The majority of the Pito Rift area is composed of preexisting blocks of Nazca plate that are back-tilted away from Pito Deep and strike perpendicular to present and previous relative plate motions. This observation suggests that block-faulting and back-tilting are the primary mechanisms responsible for the distributed lithospheric extension, in agreement with gravity and magnetic analyses (Martinez et al., this issue).The only recent volcanic flows observed in side-scan data are from the Pito Seamount area and to the outside of the outer pseudofault of the East Rift. The significance of the young flows near the outer pseudofault is not understood. We interpret the flows extending northwest from the Pito Seamount as representing a newly formed seafloor spreading axis within the Pito Rift area. Gravity and magnetic analyses (Martinez et al., this issue) together with SeaMARC II bathymetry and side-scan data support this interpretation.Based on the tectonic evolution of the Easter microplate, we propose an evolutionary model for the formation of the Pito Rift area, where new tectonic grabens form immediately west of the previous graben and with slightly more counterclockwise orientation. The duration and history of tectonic activity for each graben are not well constrained.     

Strategically Siting Urban Agriculture: A Socioeconomic Analysis of Roanoke,Virginia

Food insecurity is a major concern in the United States, particularly in high-poverty areas and among households with children. Urban agriculture helps address food insecurity and promote recreation, aesthetics, biodiversity, and other benefits. This article reports a socioeconomic evaluation of ten different variables, including in situ analysis of healthy, nutritious food options, of a small, intensely urbanized city to identify neighborhoods that would benefit from urban agriculture. We produced a hierarchy of locations (using census block groups), from least to greatest socioeconomic need, for new urban agriculture sites. Our results found that one block group qualified in all ten variables and two-thirds demonstrated a need in at least half of the variables. The majority of these block groups were distributed within the middle of the city.     

On the relation between radius,luminosity, surface brightness,and surface density in elliptical galaxies

We have analyzed luminosity profiles of E galaxies studied by Strom and Strom in six clusters of galaxies. We have found a relationship between radius, luminosity, and surface brightness for galaxies in each of the clusters. A dependence of the zero point of the relation with the local projected density of galaxies is likewise found:r _{e proj} ^–0.14 L ^0.445 I _e ^–0.413 . This relationship implies (i) that there is not a universal luminosity profile for elliptical galaxies, (ii) the environmental variation of radius is larger than that produced by mergers of galaxies, (iii) distance to a galaxy can be estimated from apparent magnitude, surface brightness, angular size, and apparent local projected density of galaxies.     

The role of ground reference data collection in the prediction of stem volume with LiDAR data in mountain areas

Ground reference data collection represents an important element in the prediction of stem volume with LiDAR-derived variables, and at present it is the most expensive part of such analyses. In this paper two aspects of ground reference data collection were analyzed: (1) the positioning error of the ground plots; and (2) the optimal number of training plots. A system for the prediction of stem volume at area-based level was adopted. LiDAR data were preprocessed and 13 variables describing both height and coverage were extracted. Models were defined using a stepwise ordinary least square (OLS) regression. Three experiments were conducted: (i) the role of the plots positioning error on prediction accuracy; (ii) the influence of random downsampling of plot numbers on prediction accuracy; and (iii) the influence of a stratified downsampling of plot numbers on prediction accuracy based on LiDAR-derived variables. A dataset comprising 799 ground plots was used. They were distributed throughout a mountainous area in the Southern Alps, where the presence of a complex landscape increases the uncertainty of the Global Positioning System (GPS) accuracy, and where a large variety of tree forest species and climatic environments make it necessary to have a large number of sample plots for accurate characterization of the study area. All the experiments provided important indications for LiDAR based forest inventories: the GPS error did not significantly influence the prediction accuracy and it was possible to reduce the number of training samples without compromising the generalization ability of the prediction model. Leading on from these findings, a new ground sampling protocol based on genetic algorithms was proposed. The new protocol allowed us to obtain promising results for the considered dataset: using only 53 training plots, instead of 534 in the original dataset, we obtained the same results for the validation set. These results, obtained in a complex mountainous area, are representative of Alpine environments and allow us to infer that similar (or better) results could also be obtained within non mountainous areas.     

Design and performance of the angle integrating erenkov array AIROBICC

An air-shower array consisting of 49 open huts with photomultiplier tubes viewing the night sky over a solid angle of about 1 steradian is described. The array is operating in conjunction with the HEGRA installation. The main objectives of the experiment are VHE to UHE γ-ray astronomy and a determination of the chemical composition of cosmic rays. The design principles, construction and performance in angular resolution, energy threshold and determination of shower parameters are discussed.     

Mid‐ and Large‐Scale Geodiversity Calculation in Fuentes Carrionas (NW Spain) and Serra do Cadeado (Paraná, Brazil): Methodology and Application for Land Management

A state‐of‐the‐art geodiversity concept, its use and scientific development are presented. Methodologies for geodiversity calculation are assessed, as well as their aim and problems. Geodiversity calculation methodology based on biodiversity richness index is explained and applied to two different areas: Fuentes Carrionas, a high mountain mid‐latitude environment in northern Spain, and Serra do Cadeado, a tropical mid‐mountain environment in southern Brasil. A geodiversity map of Fuentes Carrionas proves that glacial cirques over 2000 m a.s.l. keep a high geodiversity related to a periglacial and glacial environment, whereas a geodiversity map of Serra do Cadeado shows that high geodiversity areas are situated at its main structural scarp. Geodiversity calculation needs to take scale and hierarchy issues into account, which makes comparison only possible if the same scale is used. Geodiversity calculation is a useful tool for land management as it defines areas subject to protection due to the richness of abiotic elements. It is also useful in terms of environmental impact assessment and geotourism evaluation at remote areas.     

Quantifying the impact of watershed urbanization on a coral reef: Maunalua Bay,Hawaii

Human activities in the watersheds surrounding Maunalua Bay, Oahu, Hawaii, have lead to the degradation of coastal coral reefs affecting populations of marine organisms of ecological, economic and cultural value. Urbanization, stream channelization, breaching of a peninsula, seawalls, and dredging on the east side of the bay have resulted in increased volumes and residence time of polluted runoff waters, eutrophication, trapping of terrigenous sediments, and the formation of a permanent nepheloid layer. The ecosystem collapse on the east side of the bay and the prevailing westward longshore current have resulted in the collapse of the coral and coralline algae population on the west side of the bay. In turn this has lead to a decrease in carbonate sediment production through bio-erosion as well as a disintegration of the dead coral and coralline algae, leading to sediment starvation and increased wave breaking on the coast and thus increased coastal erosion. The field data and resulting coral reef ecohydrology model presented in this paper demonstrate and quantify the importance of biophysical processes leading to coral reef degradation as the result of urbanization. Coral restoration in Maunalua Bay will require an integrated ecosystem approach.