Seismic signature of a phreatic explosion: hydrofracturing damage at Karthala volcano, Grande Comore Island, Indian Ocean

Karthala volcano is a basaltic shield volcano with an active hydrothermal system that forms the southern two-thirds of the Grande Comore Island, off the east coat of Africa, northwest of Madagascar. Since the start of volcano monitoring by the local volcano observatory in 1988, the July 11th, 1991 phreatic eruption was the first volcanic event seismically recorded on this volcano, and a rare example of a monitored basaltic shield. From 1991 to 1995 the VT locations, 0.5<M_l<4.3, show a crack shaped pattern (3 km long, 1 km wide) within the summit caldera extending at depth from –2 km to +2 km relative to sea level. This N-S elongated pattern coincides with the direction of the regional maximum horizontal stress as deduced from regional focal mechanism solutions. This brittle signature of the damage associated with the 1991 phreatic eruption is a typical pattern of the seismicity induced by controlled fluid injections such as those applied at geothermal fields, in oil and gas recovery, or for stress measurements. It suggests the 1991 phreatic eruption was driven by hydraulic fracturing induced by forced fluid flow. We propose that the extremely high LP and VT seismicity rates, relative to other effusive volcanoes, during the climax of the 1991 phreatic explosion, are due to the activation of the whole hydrothermal system, as roughly sized by the distribution of VT hypocenters. The seismicity rate in 1995 was still higher than the pre-eruption seismicity rate, and disagrees with the time pattern of thermo-elastic stress readjustment induced by single magma intrusions at basaltic volcanoes. We propose that it corresponds to the still ongoing relaxation of pressure heterogeneity within the hydrothermal system as suggested by the few LP events that still occurred in 1995.Editorial responsibility: H Shinohara     

Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

Apport de la cathodoluminescence à haute résolution à l'étude de la diagenèse météorique dans les formations sédimentaires carbonatées

Different diagenetic transformations and their relative chronological sequence are studied in the meteoric diagenetic zone from the Upper Oligocene limestone at the North of the Aquitaine Basin (France), by combining high-resolution cathodoluminescence spectroscopy and electron-microprobe analyses. More than 128 spot analyses by electron microprobe and 60 analyses by cathodoluminescence spectroscopy are done on different meteoric cements firstly identified by classic optical microscopy. Three cement types are identified according to the relative intensity of the bands of their respective cathodoluminescence spectra (350, 380, 430, 500, and 620 nm). From these investigations, we could identify for each meteoric cement different phases of crystalline growth and crystalline dissolution. As a result, a better and more realistic meteoric diagenetic model is proposed. It illustrates the cyclic transformations from vadose zone (unsaturated) to meteoric zone (saturated). To cite this article: R. Chapoulie et al., C. R. Geoscience 337 (2005).     

Les laves du mont Bangou : une première manifestation volcanique éocène, à affinité transitionnelle,de la Ligne du Cameroun

Mount Bangou, an Eocene volcano (⁴⁰K–⁴⁰Ar ages between 44.7 and 43.1 ± 1 Ma) is the oldest dated volcano of the Cameroon Line. In this region, two magmatic series, evolving by fractional crystallization, show transitional affinities that are exceptionally known in this sector. Mineral compositions of basaltic rocks (scarce modal olivine and occurrence of normative hypersthene) as well as geochemical characteristics (low Ba, La, Ta contents and high Y/Nb ratios) are in agreement with this trend. The succession of magmas evolving in time from transitional to more typical alkaline compositions is evidenced in a continental setting. To cite this article: J. Fosso et al., C. R. Geoscience 337 (2005).     

Preliminary data on chemical changes in the Aral Sea during low-level periods from the last 9000 years

The withdrawal of the Aral Sea tributaries (Amu and Syr Daria) for cultures has led to significant falls of its level and an important increase in its salinity. During the Holocene, a succession of low and high water inputs occurred. Silty deposits correspond to the high levels and carbonates to the low levels. This study makes a distinction between the Syr Daria and the Amu Daria water inputs during low-level periods by using mineralogical and chemical compositions of the carbonates deposits. Waters from the Syr Daria are more sulphatic and have a low iron content in comparison with that of the Amu Daria. The Syr Daria was the major tributary around 7500, 4956 and 970 yr?BP, whereas around 6200 and 3610 yr?BP, inflow also from the Amu Daria is observed. To cite this article: L. Le Callonnec et al., C. R. Geoscience 337 (2005).     

Étude expérimentale de la réactivité du CO2 supercritique vis-à-vis de phases minérales pures. Implications pour la séquestration géologique de CO2

Carbon dioxide sequestration in deep aquifers and depleted oilfields is a potential technical solution for reducing green-house gas release to the atmosphere: the gas containment relies on several trapping mechanisms (supercritical CO₂, CO_2(sc), dissolution together with slow water flows, mineral trapping) and on a low permeability cap-rock to prevent CO_2(sc), which is less dense than the formation water, from leaking upwards. A leakproof cap-rock is thus essential to ensure the sequestration efficiency. It is also crucial for safety assessment to identify and assess potential alteration processes that may damage the cap-rock properties: chemical alteration, fracture reactivation, degradation of injection borehole seals, etc. The reactivity of the host-rock minerals with the supercritical CO₂ fluid is one of the potential mechanisms, but it is altogether unknown. Reactivity tests have been carried out under such conditions, consisting of batch reactions between pure minerals and anhydrous supercritical CO₂, or a two-phase CO₂/H₂O fluid at 200?°C and 105/160 bar. After 45 to 60 days, evidence of appreciable mineral-fluid reactivity was identified, including in the water-free experiments. For the mixed H₂O/CO₂ experiments, portlandite was totally transformed into calcite; anorthite displayed many dissolution patterns associated with calcite, aragonite, tridymite and smectite precipitations. For the anhydrous CO₂ experiments, portlandite was totally carbonated to form calcite and aragonite; anorthite also displayed surface alteration patterns with secondary precipitation of fibrous calcite. To cite this article: O. Regnault et al., C. R. Geoscience 337 (2005).     

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).     

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.