Removal of ammonia toxicity in marine sediment TIEs: a comparison of Ulva lactuca,zeolite and aeration methods

Toxicity Identification Evaluations (TIEs) can be used to determine the specific toxicant(s), including ammonia, causing toxicity observed in marine sediments. Two primary TIE manipulations are available for characterizing and identifying ammonia in marine sediments: Ulva lactuca addition and zeolite addition. In this study, we compared the efficacy of these methods to (1) remove NH(x) and NH(3) from overlying and interstitial waters and (2) reduce toxicity to the amphipod Ampelisca abdita and mysid Americamysis bahia using both spiked and environmentally contaminated sediments. The utility of aeration for removing NH(x) and NH(3) during a marine sediment TIE was also evaluated preliminarily. In general, the U. lactuca and zeolite addition methods performed similarly well at removing spiked NH(x) and NH(3) from overlying and interstitial waters compared to an unmanipulated sediment. Toxicity to the amphipod was reduced approximately the same by both methods. However, toxicity to the mysid was most effectively reduced by the U. lactuca addition indicating this method functions best with epibenthic species exposed to ammonia in the water column. Aeration removed NH(x) and NH(3) from seawater when the pH was adjusted to 10; however, very little ammonia was removed at ambient pHs ( approximately 8.0). This comparison demonstrates both U. lactuca and zeolite addition methods are effective TIE tools for reducing the concentrations and toxicity of ammonia in whole sediment toxicity tests.     

Simple models for estimating period‐shift and damping in soil

This study describes the development of a simple, heuristic manual calculation procedure for estimating the site period‐shift factor and soil damping ratio, with appropriate considerations for the level of shaking, impedance contrast between soil and bedrock interface and the plasticity of the soil layers. Essentially, the analogy of a building shear‐frame has been used to represent the seismic response behaviour of a soil column. The proposed procedure has been verified by comparing the predictions with results obtained directly from non‐linear shear wave analyses of soil column models. Copyright © 2006 John Wiley & Sons, Ltd.     

Barium uptake and adsorption in diatoms

Using trace metal-defined culture conditions, we measured the cellular barium concentration in cultures of the diatom Thalassiosira weissflogii. In cultures with low Fe concentration, at a typical surface seawater Ba concentration of 35 to 40 nmol/L, the cellular Ba was 0.5 μmol/mol P (∼0.04 μg/g dw), much below all previously published values for phytoplankton. When the Fe concentration in the growth medium was increased, the measured “cellular” Ba increased proportionally to the particulate Fe. Under conditions of ferric hydroxide precipitation, similar particulate Ba concentrations were measured in the absence and the presence of cells for a given concentration of particulate Fe. Thus, the bulk of the particulate Ba in such experiments was not truly intracellular but adsorbed on precipitated Fe hydroxides associated with the cell surface. A similar mechanism likely explains the high cellular Ba concentrations reported by previous investigators who utilized relatively high ratios of Fe to EDTA concentrations in the growth medium, resulting in Fe precipitation. On the basis of our results, it seems highly unlikely that intracellular uptake by living phytoplankton explains the vertical flux of Ba in oceanic waters. But the adsorption of Ba on Fe hydroxides that is seen in laboratory experiments must also occur in the oceans and contribute to Ba transport in the upper part of the water column. To be significant, however, such a mechanism would require that the particles that transport Ba out of the surface have a markedly lower Ba/Fe ratio than is measured in the average suspended material.     

Factors controlling carbon isotope ratios of dissolved inorganic carbon in two major tributaries of the Han River,Korea

Understanding the carbon cycle of the Han River system in Korea is of prime interest in managing and preserving this valuable water resource for more than 20 million residents in the area. As a part of a comprehensive carbon cycling study for the Han River system, this report focuses on the carbon isotope compositions of dissolved inorganic carbon (DIC) in its two major tributaries, the North and the South Han Rivers. The major difference in carbonate chemistry of the tributaries originates primarily from the lithology of the catchment areas. The South Han River, draining a carbonate‐dominant terrain, has much higher alkalinities and DIC concentrations, whereas the lower concentrations in the North Han River indicate little influence of carbonate weathering. Likewise, δ¹³C_DIC values in the South Han River indicate that the DIC input from the carbonate rocks is important in controlling carbon isotope ratios of DIC. For the North Han River, the oxidation of organic material influences the amount of riverine DIC and δ¹³C_DIC values to a greater extent. Overall, remarkable seasonal and spatial variations of river chemistry and carbon isotope compositions of DIC reflect the variability in geo‐hydrologic characteristics, in the water regime, and in metabolic activities in the river water and/or the drainage areas. Copyright © 2006 John Wiley & Sons, Ltd.     

Estimates of Tsunami Risk Zones on the Coasts Adjacent to the East (Japan) Sea based on the Synthetic Catalogue

Prognostic characteristics of tsunamis in the East (Japan) Sea based on numerical simulations are investigated by using linear long wave theory. Due to the lack of observed data, the concept of the synthetic catalogue is applied to generate possible tsunami scenarios. It includes four real events that occurred in the East (Japan) Sea during the 20th century, 24 hypothetical tsunamigenic earthquakes located in the gap zones of the seismic map, and 76 idealized model ‘hydrodynamic’ sources covering the eastern part of the East (Japan) Sea uniformly. The tsunami wave height distributions along the East (Japan) Sea coastline due to these hypothetical events are computed. From the geographical distributions of tsunami wave height for all possible events, it is found that there exist several coastal locations where the tsunami risk is relatively lower than in other zones. The relation between the maximal value of the tsunami height and its average value is analyzed. It is found that the maximal tsunami height does not exceed the mean wave height times a constant. The uniform bounded curve for all areas can be obtained if the mean wave height is replaced by the modified mean wave height (1/3 of largest waves). The problem of quantitative definition of the prognostic tsunami wave height for each location based on the data from the synthetic catalogue is discussed. The results of tsunami wave height analysis based on the synthetic catalogue can be used as a tool for coastal disaster mitigation planning.     

Distribution Functions of Tsunami Wave Heights

The problem of describing the distribution functions of tsunami wave heights is discussed. Data on runup heights obtained in field surveys of several tsunamis for the last decade are used to calculate the empirical distribution functions. It is shown that the log-normal distribution describes the observed data well. This means that the irregular topography and coastline are major factors which influence the height distribution. The power distribution related with the geometric decay of the propagated wave is a good approximation for one event (Sulawesi, January 1, 1996) only. Results of a numerical simulation of the tsunami event in the Japan (East) Sea on July 12, 1993 are presented. It is shown that the computed wave height distribution, obtained by using the runup correction in the framework of nonlinear shallow-water theory, is in good agreement with the observed height distribution. Simulations are used to study the transformation of the distribution function on different distances from the source.     

Petrology of lavas from episodes 2–47 of the Puu Oo eruption of Kilauea Volcano,Hawaii: Evaluation of magmatic processes

The Puu Oo eruption of Kilauea Volcano in Hawaii is one of its largest and most compositionally varied historical eruptions. The mineral and whole-rock compositions of the Puu Oo lavas indicate that there were three compositionally distinct magmas involved in the eruption. Two of these magmas were differentiated (<6.8 wt% MgO) and were apparently stored in the rift zone prior to the eruption. A third, more mafic magma (9–10 wt% MgO) was probably intruded as a dike from Kilauea's summit reservoir just before the start of the eruption. Its intrusion forced the other two magmas to mix, forming a hybrid that erupted during the first three eruptive episodes from a fissure system of vents. A new hybrid was erupted during episode 3 from the vent where Puu Oo later formed. The composition of the lava erupted from this vent became progressively more mafic over the next 21 months, although significant compositional variation occurred within some eruptive episodes. The intra-episode compositional variation was probably due to crystal fractionation in the shallow (0.0–2.9 km), dike-shaped (i.e. high surface area/volume ratio) and open-topped Puu Oo magma reservoir. The long-term compositional variation was controlled largely by mixing the early hybrid with the later, more mafic magma. The percentage of mafic magma in the erupted lava increased progressively to 100% by episode 30 (about two years after the eruption started). Three separate magma reservoirs were involved in the Puu Oo eruption. The two deeper reservoirs (3–4 km) recharged the shallow (0.4–2.9 km) Puu Oo reservoir. Recharge of the shallow reservoir occurred rapidly during an eruption indicating that these reservoirs were well connected. The connection with the early hybrid magma body was cut off before episode 30. Subsequently, only mafic magma from the summit reservoir has recharged the Puu Oo reservoir.     

柴达木盆地低频地震探测结晶基底的工作方法

根据地质资料,柴达木盆地的基岩（结晶基底）埋藏深度,可达十公里以上.勘探这样深的基岩,利用反射和一般折射方法是不容易得到良好的效果.1958年6月,在柴达木盆地开始试验低频地震的方法,来接收基岩面的折射波.所用检波器的谐振频率为13周/秒,放大器最低谐振频率为8周/秒.最大接收距离为100公里左右.