Can 234U–230Th dating be used to date large semi‐arid tufas? Challenges from a study in the Naukluft Mountains,Namibia

The large, extensive tufa deposits of the semi‐arid Naukluft Mountains, Namibia are potentially important palaeoenvironmental indicators in an area with few proxy records. Tufas are reliable indicators of increased moisture availability, and have been shown to be amenable to ²³⁴U–²³⁰Th dating, although two challenges are detrital contamination and open‐system behaviour. Densely cemented tufa facies are good candidates for dating, minimising these problems. We report attempts to date five densely‐cemented units, which are only found rarely within the Naukluft deposits. We applied a detailed methodology using multiple subsample analysis, measurement of insoluble residues, application of ‘isochron’ mixing lines, and attempted open‐systems modelling, alongside observations of micromorphology and cathodoluminescence in order to assess the validity of any obtained dates. Surprisingly, densely cemented tufas were found not always to be suitable for dating. Two units contained detrital contamination, which could not be corrected for using a single leachate correction or ‘isochron’ methods. Two units contained ‘excess ²³⁰Th’. This could result under a closed‐system if initial (²³⁴U/²³⁸U) was sufficiently high. Alternatively this may be the result of open‐system behaviour, and loss of uranium, or incorporation of initial unsupported ²³⁰Th, which render samples unsuitable for ²³⁴U–²³⁰Th dating. Micromorphological appearance and cathodoluminescence behaviour are used to explore these possibilities. This study exemplifies the need for careful sample selection, and highlights the importance of analysing multiple subsamples from any tufa sample. The detailed methodology applied proves to be a powerful tool for identifying the range of problems that can be encountered when selecting suitable candidate samples for successful dating. It also shows that semi‐arid tufa sequences may contain very little material suitable for dating. A reliable age of c 80 ka was obtained for a banded unit within a large fluvial barrage, with less reliable dates suggesting tufa deposition during times since >350 ka through to the late Holocene. Copyright © 2010 John Wiley & Sons, Ltd.     

Long-Term Variability of Volume and Heat Transport in the Nordic Seas: A Model Study

This article presents results from a model study of interannual and decadal variability in the Nordic Seas. Fifty years of simulations were conducted in an initial condition ensemble mode forced with the National Centers for Environmental Prediction (NCEP) reanalysis. We studied two major events in the interannual and interdecadal variability of the Nordic Seas during the past fifty years: the Great Salinity Anomaly in the 1960s and early 1970s and the warming of the Arctic and subarctic oceans in the late 1990s.

Previous studies demonstrated that the Great Salinity Anomaly observed in the subarctic ocean in 1960 was originally generated by intensified sea-ice and freshwater inflow from the Arctic Ocean. Our model results demonstrate that the increase in the transport of fresh and cold waters through Fram Strait in the 1960s was concurrent with a reduction in the meridional water exchange over the Greenland–Scotland Ridge. The resulting imbalance in salinity and heat fluxes through the strait and over the ridge also contributed to the freshening of the water masses of the Nordic Seas and intensified the Great Salinity Anomaly in the Nordic Seas.

The warming of the Atlantic Waters in the Nordic Seas and Arctic Ocean during the past two decades had an important impact on the variability of these two ocean basins. Some previous observational and model studies demonstrated that the warming of the subpolar Atlantic Ocean in the late 1990s and the meridional transport of the Atlantic Water mass (AW) into the Nordic Seas and Arctic Ocean contributed to this process. At the same time, observations show that the warming of the AW in the Nordic Seas started in the 1980s (i.e., earlier than the warming of the subpolar North Atlantic Ocean). Our model results suggest that this process was triggered by an imbalance in the lateral heat fluxes through Fram Strait and over the Greenland–Scotland Ridge. In the late 1980s the AW transport over the Greenland–Scotland Ridge was stronger than normal while the exchange through Fram Strait was close to normal. The related imbalance in the lateral heat fluxes through the strait and over the ridge warmed the Nordic Seas and caused an increase in the temperature of the AW inflow to the Arctic Ocean in the late 1980s (i.e., about a decade earlier than the warming of the source of the AW in the subpolar North Atlantic Ocean). Thus the model results suggest that the imbalance in lateral heat and salinity fluxes through the strait and over the ridge connecting the Nordic Seas to the North Atlantic and Arctic oceans could amplify the interannual variability in the subarctic ocean.

[Traduit par la rédaction] Cet article présente les résultats d'une étude par modèle de la variabilité interannuelle et décennale dans les mers nordiques. Nous avons effectué des simulations sur une période de cinquante ans en mode d'ensemble de conditions initiales forcé avec les réanalyses des NCEP (National Centers for Environmental Prediction). Nous avons étudié deux événements majeurs survenus dans la variabilité interannuelle et décennale des mers nordiques au cours des cinquante dernières années : la grande anomalie de salinité des années 1960 et du début des années 1970 et le réchauffement des océans Arctique et subarctique vers la fin des années 1990.

Des études précédentes ont démontrées que la grande anomalie de salinité observée dans l'océan subarctique en 1960 a été causée par une intensification de l'apport de glace de mer et d'eau douce depuis l'océan Arctique. Les résultats que nous avons obtenus du modèle montrent que l'accroissement du transport d'eau douce et froide à travers le détroit de Fram dans les années 1960 s'est produit en même temps qu'une réduction dans l’échange méridien d'eau au-dessus de la crête Groenland–Écosse. Le déséquilibre résultant dans les flux de salinité et de chaleur à travers le détroit et au-dessus de la crête a aussi contribué à l'adoucissement des masses d'eau des mers nordiques et a intensifié la grande anomalie de salinité dans les mers nordiques.

Le réchauffement des eaux atlantiques dans les mers nordiques et dans l'océan Arctique au cours des deux dernières décennies a eu un impact important sur la variabilité de ces deux bassins océaniques. Des études observationnelles et par modèle précédentes ont établi que le réchauffement de l'océan Atlantique subpolaire dans les années 1990 et le transport méridien de la masse d'eau atlantique dans les mers nordiques et dans l'océan Arctique ont contribué à ce processus. En même temps, les observations montrent que le réchauffement des eaux atlantiques dans les mers nordiques a commencé dans les années 1980 (c.–à–d. plus tôt que le réchauffement de l'océan Nord-Atlantique subpolaire). Les résultats du modèle suggèrent que ce processus a été déclenché par un déséquilibre dans les flux de chaleur latéraux à travers le détroit de Fram et au-dessus de la crête Groenland–Écosse. À la fin des années 1980, le transport des eaux atlantiques au-dessus de la crête Groenland–Écosse était plus fort que la normale alors que l’échange à travers le détroit de Fram était près de la normale. Le déséquilibre résultant dans les flux de chaleur latéraux à travers le détroit et au-dessus de la crête a réchauffé les mers nordiques et causé une augmentation de la température des eaux atlantiques parvenant à l'océan Arctique à la fin des années 1980 (c.-à-d. environ une décennie avant le réchauffement de la source d'eaux atlantiques dans l'océan Nord-Atlantique subpolaire). Donc, les résultats du modèle suggèrent que le déséquilibre dans les flux de chaleur et de salinité latéraux à travers le détroit et au-dessus de la crête reliant les mers nordiques à l'Atlantique Nord et à l'Arctique pourrait amplifier la variabilité interannuelle dans l'océan subarctique.     

Late Holocene vertical land motion and relative sea‐level changes: lessons from the British Isles

Vertical land motion caused by continuing glacial isostatic adjustment is one of several important components of sea‐level change and is not limited just to previously glaciated regions. A national‐scale analysis for the British Isles shows an ellipse of present‐day relative uplift (relative sea‐level fall), ～1.2 mm a^?1, broadly centred on the deglaciated mountains of Scotland. The pattern of three foci of relative subsidence, ～1 mm a^?1, results from the additional interactions of the deglacial meltwater load on the Atlantic basin and the continental shelf, and the signal due to far‐field ice sheets. At a local scale, sediment compaction can more than double the rate of relative land subsidence. Relative land‐level change (the negative of relative sea‐level change) is not the same as vertical land motion. There is a spatial pattern in the difference between relative land‐level change and vertical land motion, with differences at present of approximately ?0.1 to ?0.3 mm a^?1 around the British Isles and +2.5 to ?1.5 mm a^?1 globally. For the wider scientific and user community, whether or not the differences are considered significant will depend upon the location, time frame and spatial scale of the study that uses such information. Copyright © 2011 John Wiley & Sons, Ltd.     

Biogeography of the deep-sea galatheid squat lobsters of the Pacific Ocean

We analyzed the distribution patterns of the galatheid squat lobsters (Crustacea, Decapoda, Galatheidae) of the Pacific Ocean. We used the presence/absence data of 402 species along the continental slope and continental rise (200–2000 m) obtained from 54 cruises carried out in areas around the Philippines, Indonesia, Solomon, Vanuatu, New Caledonia, Fiji, Tonga, Wallis and Futuna and French Polynesia. The total number of stations was ca. 3200. We also used published data from other expeditions carried out in the Pacific waters, and from an exhaustive search of ca. 600 papers on the taxonomy and biogeography of Pacific species. We studied the existence of biogeographic provinces using multivariate analyses, and present data on latitudinal and longitudinal patterns of species richness, rate of endemism and the relationship between body sizes with the size of the geographic ranges. Latitudinal species richness along the Western and Eastern Pacific exhibited an increase from higher latitudes towards the Equator. Longitudinal species richness decreased considerably from the Western to the Central Pacific. Size frequency distribution for body size was strongly shifted toward small sizes and endemic species were significantly smaller than non-endemics. This study concludes that a clear separation exists between the moderately poor galatheid fauna of the Eastern Pacific and the rich Western and Central Pacific faunas. Our results also show that the highest numbers of squat lobsters are found in the Coral Sea (Solomon-Vanuatu-New Caledonia islands) and Indo-Malay-Philippines archipelago (IMPA). The distribution of endemism along the Pacific Ocean indicates that there are several major centres of diversity, e.g. Coral Sea, IMPA, New Zealand and French Polynesia. The high proportion of endemism in these areas suggests that they have evolved independently.     

Estimating impacts of warming temperatures on California's electricity system

Despite a clear need, little research has been carried out at the regional-level to quantify potential climate-related impacts to electricity production and delivery systems. This paper introduces a bottom-up study of climate change impacts on California's energy infrastructure, including high temperature effects on power plant capacity, transmission lines, substation capacity, and peak electricity demand. End-of-century impacts were projected using the A2 and B1 Intergovernmental Panel on Climate Change emission scenarios. The study quantifies the effect of high ambient temperatures on electricity generation, the capacity of substations and transmission lines, and the demand for peak power for a set of climate scenarios. Based on these scenarios, atmospheric warming and associated peak demand increases would necessitate up to 38% of additional peak generation capacity and up to 31% additional transmission capacity, assuming current infrastructure. These findings, although based on a limited number of scenarios, suggest that additional funding could be put to good use by supporting R&D into next generation cooling equipment technologies, diversifying the power generation mix without compromising the system's operational flexibility, and designing effective demand side management programs.     

The Effects of Ground Water Sampling Devices on Water Quality: A Literature Review

This paper reviews both field and laboratory studies that tested or compared the ability of various types of sampling devices to deliver representative ground water samples. Several types of grab samplers, positive displacement devices, and suction-lift devices were evaluated, Gas-lift and inertial-lift pumps were also evaluated. This study found that most of these devices can. under certain circumstances, alter the chemistry of ground water samples, das-lift pumps, older types of submersible centrifugal pumps, and suction-lift devices are not recommended when sampling for sensitive constituents such as volatile organics and inorganics, or inorganics that are subject to oxidation/precipitation reactions. In general, of the devices reviewed in this paper, bladder pumps gave the best recovery of sensitive constituents. However, better performance could be achieved for several devices if improved operational guidelines were developed by additional testing, especially at lower flow rates. Clearly, further research is warranted. Future studies should focus on pumping rate, flow control mechanisms, and dedication or decontamination of sampling devices.     

Effect of Concentration on Sorption of Dissolved Organics by PVC, PTFE, and Stainless Steel Well Casings

This report examines sorption of low ppb levels of organic solutions by polytetra- fluoroethylene (PTFE), rigid polyvinyl chloride (PVC), and stainless steel 304 and 316 well casings. Nineteen organics were selected, including several munitions and chlorinated solvents. Compounds were selected to offer a range of physical properties, such as solubility in water, octanol/water partition coefficient, and molecular structure. When these results were compared with the results from a similar study conducted at ppm levels, the rate and extent of sorption by PTFE and PVC were the same as seen previously for almost all analytes. There were no losses of any compounds associated with stainless steel. At these low levels (ppm and ppb), the rate of diffusion within the polymer (PVC and PTFE) is independent of concentration. Only with PTFE are the rates rapid enough to be of concern when monitoring for some contaminants in ground water. Tetrachloroethylene was the compound PTFE sorbed the most rapidly. The study showed that PVC well casings are suitable for monitoring low levels (ppm and ppb) of organics.