The deuterium enrichment of individual amino acids in carbonaceous meteorites: A case for the presolar distribution of biomolecule precursors

The δD values of over 40 amino acids and two pyridine carboxylic acids of the Murchison and Murray meteorites have been obtained by compound-specific isotopic analyses. For compounds with no known terrestrial distribution, these values range from approximately +330‰ (for cyclic leucine) to +3600‰ (for 2-amino-2,3-dimethylbutyric acid). The latter value is the highest ever recorded for a soluble organic compound in meteorites and nears deuterium to hydrogen ratios observed remotely in interstellar molecules. Deuterium content varies significantly between molecular species and is markedly higher for amino acids having a branched alkyl chain. The δD value of Murray l-isovaline, with an enantiomeric excess of ∼ 6% in the meteorite, was within experimental error of that determined for the combined dl-isovaline enantiomers. Overall, the hydrogen isotope composition of meteoritic amino acids is relatively simple and their δD values appear to vary more with the structure of their carbon chains than with the number and relative distribution of their functionalities or ¹³C content. The magnitude and extent of deuterium enrichment shared by many and varied amino acids in meteorites indicate that cosmic regimes such as those found in the interstellar medium were capable of producing, if not all the amino acids directly, at least a suite of their direct precursors that was abundant, varied, and considerably saturated.     

Channel avulsion and river metamorphosis: The case of the Thomson River,Victoria, Australia

Channel avulsion occurred on the Thomson River in Victoria, Australia, in 1952 along a 12 km length of the valley. A comparison of the old and new channels reveals considerable differences in channel characteristics. The old channel was perched above the floodplain on an alluvial ridge such that when bankfull capacity was exceeded, floodwaters concentrated on the lowest part of the floodplain some distance away. This is where the new channel formed. It is an incised channel with larger capacity and longer meander wavelength than the old channel and is also shorter and steeper. The new channel is subject to larger floodflows and a more variable flood regime than the old course because of the differences in the channel/floodplain relationship and channel capacity. The resulting concentration of stream power along the new course is responsible for the contrast in channel characteristics and for the more rapid meander migration. This example shows that river metamorphosis can occur without major environmental changes. Measures of channel geometry such as gradient, sinuosity, and meander wavelength therefore cannot be used in palaeohydrological work to infer climatic or other environmental changes without independent supporting evidence. Differences in channel geometry can arise simply from changes in the relationship between the channel and its loodplain.     

Medium and short-term channel planform changes on the Rivers Tay and Tummel, Scotland

Channel planform change was analysed using a variety of data-sources for the medium-term (>25 years and <250 years) and short-term (<25 years) on a reach of the Rivers Tay and Tummel, Scotland. Map data were input into a Geographic Information System (GIS) and used to determine planform characteristics and changes in width, braiding index and sinuosity for the study reach between 1755 and 1976. Aerial photographs were utilised to determine the more recent changes that had taken place between 1971 and 1994. The analysis showed that significant changes had occurred over the medium term with a mean reduction in channel width of 34% for this period. These changes are comparable to those found in studies of similar European rivers for this period. Changes determined for the short-term displayed a continuance of this trend at a comparable rate of change. An analysis of flood frequency and magnitude, precipitation and discharge records for both periods does not show an associated decrease and therefore does not reflect the changes in channel planform. Evidence points towards flood embankment construction in the mid-1800s as the initial cause of channel change for the study reach which was later exacerbated by flow regulation. Incision and the subsequent stabilisation of lateral and mid-channel gravel bars by vegetation succession has resulted in an overall increase in the stability of the study reach which has persisted even where the embankments have fallen into disrepair.     

Assessment of Potential Alkali Aggregate Reactivity for Siliceous and Carbonate Aggregates: A Case Study

Alkali-aggregate reactivity (AAR) involves a reaction between the pore solution of concrete and certain minerals found in some aggregates. To assess the potential AAR various physical and chemical tests are available and extensively used. The petrographic examination is the initial assessment that decides the further investigation for potential reactivity of an aggregate. A chemical approach is another option to assess the aggregate for potential AAR. The accelerated mortar bar method and concrete prism tests are other very important tests for determination of potential AAR of aggregates samples. However, a combination of the results of all the techniques provides most reliable results for potential AAR in aggregates. Moreover, each test represents the stepwise investigation and provides the decision for the test of next approach. Petrographic examination and chemical test methods are the quick decision-making methods for the estimation of potential AAR. In some cases, by these two methods, the aggregate can be selected and rejected confidently. However, for critical values or doubtful aggregates, further tests are necessary to develop a higher confidence level of the results. The present study comprises of the assessment of the alkali-reactivity of siliceous and carbonate aggregates using petrographic and chemical approaches. X-ray diffraction analysis was used as a complementary method to the petrographic evaluation. Moreover, under chemical approach, two separate test methods were used for siliceous and carbonate aggregates. The study also included a comparison between the petrographic examination and chemical analysis for the same aggregate samples and found significant results.     

An Evaluation of the Effects of Primary and Cross‐Contamination during the Preparation of Rock Powders for Chemical Determinations

Quartz crystals from the Batatal site, Minas Gerais, southern Brazil, were used to determine quantitatively primary contamination when submitting the samples to milling processes. Crushing devices used were a primary steel jaw crusher (br1), a secondary tungsten carbide (WC) crusher (br2) and a hydraulic press with stainless steel plates (pr). Fragments with suitable sizes were then ground in different Fritsch planetary mills, equipped with agate, WC and chromium‐steel rings for 7, 4 and 3 min, respectively. Solutions of the powders were analysed initially with the TotalQuant^? method in a quadrupole ICP‐MS instrument, providing semi‐quantitative results for seventy‐five elements. Contamination from crushers and mills was visible in major and minor elements such as Fe, Mn and Ti, and noticeable in trace elements such as Cr, Co, Ni, Cu and also V, Zr, Sc; significant contamination was observed from W, Mo, Co, Ta and Nb (mainly by use of the WC devices). Little or no contamination was observed for Pb, REE, Sr and Rb, elements that are important in routine isotopic determinations. Cross‐contamination was tested by grinding either a granite or a basalt sample, followed by conventional cleaning with mica‐free quartz sand, before the working quartz powder was prepared.     

The stable isotopic composition of coral skeletons: control by environmental variables

The reef corals Pocillopora damicornis and Montipora verrucosa were cultured under various controlled temperature and light conditions. The corals were analyzed for growth rate, tissue pigment content and skeletal ¹³C and ¹⁸O. Coral skeletal δ¹³C values varied with light dose and correlated with changes in zooxanthellar pigment. The δ¹³C values of skeletal aragonite seem to be modified by oxidation of photosynthetically produced organic matter.Functionally significant relationships between coral skeletal δ¹⁸O values and temperature have been determined. The temperature coefficients of the δ¹⁸O values [?4.4°C (%.)^?1] are similar to the first order coefficient in the equilibrium paleotemperature equation, but the δ¹⁸O values have taxonomically consistent offsets from equilibrium. The offsets may be attributed to the coral metabolism with slight but statistically significant differences between the two genera. Environmental and metabolic variables other than temperature have little or no effect on skeletal δ¹⁸O.     

Establishing the wave climate influence on the morphodynamics of a coastal lagoon inlet

The morphologic changes in estuaries and coastal lagoons are very complex and constitute a challenging task in coastal research. The bathymetric changes result from the combined action of tides, waves, rivers discharge and wind stress in the area of interest. Additionally, an accurate knowledge of the sediment transport is essential to achieve a good morphological characterization. This work establishes the influence of the wave climate on the morphodynamics of the Ria de Aveiro lagoon inlet by analysing the numerical results of the morphodynamic modelling system MORSYS2D. The numerical simulations considered a realistic coupled forcing of tidal currents and waves. The computed sediment fluxes and bathymetric changes are analysed and compared with the erosion and accretion trends obtained from the numerical simulations forced only by tidal currents, in order to establish the wave climate influence. The final bathymetry and the corresponding changes are compared with bathymetric data collected through surveys. It is concluded that: (a) the morphodynamics of the study area is dominated by the wave regime in the lagoon inlet and nearshore areas, while in the inner areas is tidally dominated; and (b) the inclusion of the wave regime forcing constitutes an improvement in order to accurately reproduce the local morphodynamics.     

Tintinnids and Other Microplankton from the Greenland Sea: Abundance and Distribution in the Marginal Ice Zone (MayJune 1989)

Abstract. Microplankton (silicoflagellates, dinoflagellates, tintinnids, pteropods, crustaceans, and fecal pellets) was analysed in 71 0–95 m samples from the Greenland Sea collected from May to June 1989. Abundances were clearly associated with the ice edge, highest concentrations occurring in ice-free waters. The 15 to 30 m stratum was generally richer in microplankton than deeper waters, with the exception of microcrustaceans, which often peaked below 30 m. Six tintinnid species were identified. The mean size of the tintinnid Parafavella denticulata from the Greenland Sea was consistently greater than that of Barents Sea specimens. It is suggested that colder waters and scarcer food are responsible for these morphometric differences.     

Abundance and size distribution of transparent exopolymer particles (TEP) in a coccolithophorid bloom in the northern Bay of Biscay

The distribution of transparent exopolymer particles (TEP) was investigated during a coccolithophorid bloom in the northern Bay of Biscay (North Atlantic Ocean) in early June 2006. MODIS chlorophyll-a (Chl-a) and reflectance images before and during the cruise were used to localize areas of important biological activity and high reflectance (HR). TEP profiles along the continental margin, determined using microscopic (TEP_micro) and colorimetric (TEP_color) methods, showed abundant (6.1×10⁶–4.4×10⁷ L^?1) and relatively small (0.5–20 μm) particles, leading to a low total volume fraction (0.05–2.2 ppm) of TEP_micro and similar vertical profiles of TEP_color. Estimates of carbon content in TEP (TEP-C) derived from the microscopic approach yielded surface concentration of 1.50 μmol C L^?1. The contribution of TEP-C to particulate organic carbon (POC) was estimated to be 12% (molar C ratio) during this survey. Our results suggest that TEP formation is a probable first step to rapid and efficient export of C during declining coccolithophorid blooms.