Cd, Pb, Cu, Ni and Co distribution in the German Bight

Cd, Pb and Cu concentrations, dissolved and total, have been determined in the German Bight. In 1975, 1977, 1978, 1980 and 1983 water samples were collected at 215 sampling stations. In the 1983 mission samples were also analysed for Ni and Co. The samples were filtered and acidified immediately after collection. Analysis was performed by voltammetry.The analytical data indicate that a net portion of the Cd, the Weser being a distinct source for it, will cross the estuarine zone. Open sea Cd levels in the German Bight are about a factor 10 higher than North Atlantic values. Pb, being transported mainly with the suspended particulate phase (up to 99.5%), is better eliminated by sedimentation in the estuaries. Ni and Cu occur mainly in the dissolved phase. Pollution by Co is distinct in the Elbe, but the output is rapidly diluted to background contents below 10 ng kg⁻¹. An interpretation of the results from the different years yields a rather steady state situation in the German Bight.     

A fish hepatocyte model for the investigation of the effects of environmental contaminants

An isolated fish hepatocyte culture system was developed as a models ystem to investigate the mechanisms of action of environmental contaminants. Hepatocytes were isolated from striped bass (Morone saxatilis) by an adaptation of the two stage perfusion technique of Seglen.¹ The system was used to evaluate metal binding protein (MBP) induction in response to cadmium, a primary inducer of metallothionein (MT) in rat hepatocytes. Striped bass hepatocytes appeared to be refractory to the induction of MBP by cadmium, since there was no significant increase in the synthesis of MBP for any of the doses at any of the time points investigated. However, when a similar experiment was performed using rat hepatocytes there was induction of MBP that was related to both dose and time. These comparative experiments indicate that although there are similarities between the hepatocytes of the two species in regard to ³⁵S incorporation into low molecular weight metal-binding proteins, there appear to be significant quantitative differences as well in regard to MBP kinetics. This in vitro model system could potentially be utilized to investigate the toxicological properties of other environmental contaminants.     

The Levant Slumps and the Phoenician Structures: collapse features along the continental margin of the southeastern Mediterranean Sea

Two distinct series of slumps deform the upper part of the sedimentary sequence along the continental margin of the Levant. One series is found along the base of the continental slope, where it overlies the disrupted eastern edge of the Messinian evaporites. The second series of slumps transects the continental margin from the shelf break to the Levant Basin. It seemed that the two series were triggered by two unrelated, though contemporaneous, processes. The shore-parallel slumps were initiated by basinwards flow of the Messinian salt, that carried along the overlying Plio-Quaternary sediments. Seawater that percolated along the detachment faults dissolved the underlying salt to form distinctly disrupted structures. The slope-normal slumps are located on top of large canyons that cut into the pre-Messinian sedimentary rocks. A layer of salt is found in the canyons, and the Plio-Quaternary sediments were deposited on that layer. The slumps are bounded by large, NW-trending faults where post-Messinian faulted offset was measured. We presume that the flow of the salt in the canyons also drives the slope-normal slumps. Thus thin-skinned halokynetic processes generated the composite post-Tortonian structural patterns of the Levant margin. The Phoenician Structures are a prime example of the collapse of a distal continental margin due to the dissolution of a massive salt layer.     

Faults at the proximal continental shelf off Atlit,central Israel,and their neotectonic significance

A seismic reflection survey was conducted in the proximal shelf off Atlit, western Mt. Carmel, Israel, to clarify the regional neotectonic regime. The Atlit promontory is built of late Pleistocene eolianite ridge, truncated by faults at its northern extension. The seismic survey encountered two series of faults, trending N—S and NW—SE, offsetting the upper strata by 1–5 m. Faulted escarpments of the N—S faults are barely covered by sediments, suggesting that they are tectonically active. The escarpments of the NW—SE faults are rarely exposed, suggesting their late Pleistocene age. A submerged undamaged Neolithic well near a major NW trending fault indicates that the structural stability of these faults during the last 8000 years can be presumed.     

A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.     

Onshore Neogene stratigraphy in the North of the Alboran Sea (Betic Internal Zones): Paleogeographic implications

The Neogene is the period in which the Betic Cordillera, the Rif, and the Alboran Sea acquired their present configuration. The Neogene sediments of the Betic Internal Zones (located directly to the North of the Alboran Sea) show the effects of important periods of deformation. Deposition was clearly controlled by tectonics. Therefore the generation, evolution, and total or partial destruction of basins and the formation of new, often superimposed, basins are common phenomena, according to the locations of the basins in the Betic Cordillera and to the different geodynamic situations.     

Palynological characterization of gassy sediments in the inner part of Ría de Vigo (NW Spain). New chronological and environmental data

Palynological characterization of the pollen assemblages from core ZV-01 offers a reliable age record of shallow ‘gas seal’ and ‘gas reservoir’ sediments from the Ría de Vigo (NW Spain). Gassy sediments show a direct correspondence with the palynological assemblage zones (LPAZ) 2, 3 and 4, which range in age from 950 to 1510 a.d. for the interval 81–176 cm where gas is found. The facies acting as a seal would correspond to the sedimentation in the ria starting from 1510 a.d. These assemblages also provide significant data which make it possible to reconstruct the palaeoenvironmental changes recorded in the sedimentary infill of the Ría de Vigo. The gassy horizon corresponds to the phase when riparian and mesophilous forest were better represented. This coincides with a relative high abundance of Lingulodinium machaerophorum, which indicates that the waters of the ria had been less renewed by oceanic waters and had a plentiful supply of continental nutrients. At that time, anoxic conditions resulted from restricted vertical circulation of seawater and/or high biological productivity. The dinocyst assemblages overlying and underlying the gassy horizon in core ZV-01 are clearly different from those concomitant with the accumulation of the gassy sediments. This suggests that oceanographic conditions in the Ría de Vigo may have changed several times during the time interval covered by our record. The weaker relationship between L. machaerophorum/Spiniferites spp., and simultaneous significant increases in Impagidinium spp. and Bitectatodinium tepikiense may indicate a greater intrusion of colder, more oceanic waters into the Ría de Vigo, which may have provoked intensification in upwelling during two periods, ca. 700–850 a.d. and ca. 1500–1750 a.d.     

The Huelva (Spain) Tsunami-Ready Station and Its Interaction with Storm Emma (March 2018)

Abstract

The sea level station operating since 1996 at Mazagón (Huelva, Spain) has been progressively upgraded to fit tsunami warning requirements, due to its location in one of the main regions at risk. Its radar water level sensor was complemented in 2017, with the addition of a pressure sensor. The performance of both sea level sensors and their response to sea level oscillations, at different frequencies, is assessed. Particular emphasis is put on the effect of extreme events, such as Storm Emma, when alternative methods to obtain 1-min data are tested, in contrast to the one based on arithmetic means. The overall differences are small, for the whole period of study (centered-root-mean-square-error below 1?cm, for 5-min, and hourly data; similar tidal parameters and sea level oscillations with periods between 30?s and 5?min). However, during Storm Emma, the pressure sensor presents sensibly lower readings than the radar, with the centered-root-mean-square-error rising to 80?mm on the March 2^nd 2018. A new method to compute 1-min data, based on medians, reduced this value to 10?mm for the same day.     

Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.     

Miocene extensional detachments in the outcropping basement of the northern Alboran Basin (Betics) and their tectonic implications

Whether or not there are extensional detachment faults in the Alboran basement can be tested directly because a part of the Alboran Basin is now emerged. These detachments, related to crustal thinning beneath the Alboran Basin, occurred from the Aquitanian to Tortonian. The resulting extensional geometries can be described in general terms. During the Serravalian a considerable southwest extension of the basin took place, accompanied by south-southeast extension in the northern Gibraltar Arc. Other detachments affected by Serravalian extension can be found. The spreading of the Alboran was nearly coeval with roughly westward migration of the Gibraltar mountain front.