U-Pb systematics of monazite and xenotime: case studies from the Paleoproterozoic of the Grand Canyon, Arizona

Monazite is accepted widely as an important U-Pb geochronometer in metamorphic terranes because it potentially preserves prograde crystallization ages. However, recent studies have shown that the U-Pb isotopic system in monazite can be influenced by a variety of processes that partially obscure the early growth history. In this paper, we attempt to interpret complex monazite and xenotime U-Pb data from three Paleoproterozoic granite dikes exposed in the Grand Canyon. Single-crystal monazite analyses from an unfoliated granite dike spread out along concordia from the crystallization age of the dike (defined by U-Pb zircon data to be 1685 ± 1 Ma) to 1659 ± 2 Ma, a span of 26 million years. Back-scattered electron (BSE) imaging reveals that magmatic domains within most crystals from this sample are truncated by secondary domains associated with prominent embayments at the grain margin. Fragments of a single crystal yield contrasting, concordant dates and fragments from the edges and tips of crystals yield the youngest dates. Based on these observations we suggest that the secondary domains formed at least 26 million years after the crystal formed. Monazite and xenotime dates from the second sample, a sheared dike that cross-cuts the previous dike, spread out along concordia over 16 million years and range up to 2.4% normally discordant. Again, BSE imaging reveals secondary domains that truncate both magmatic zoning and xenocrystic cores. Fragments sliced from specific domains of a previously imaged monazite crystal demonstrate that the secondary domain is 13 million years younger than the core domain. Textures revealed in BSE images suggest that the secondary domains formed by fluid-mineral interaction. Normal discordance appears to result from both radiation damage accumulated at temperatures below 300 °C and water-mineral interaction. Monazite data from the third sample exhibit dispersion in both the ²⁰⁷Pb/²⁰⁶Pb dates (1677–1690 Ma) and discordance (+ 1.6% to − 3.1%). Reverse discordance in these monazites cannot be explained by incomplete dissolution or excess (thorogenic) ²⁰⁶Pb. Sliced fragments from several crystals reveal dramatic intragrain U-Pb disequilibrium that does not correlate with either Th or U concentration or position within the crystal. We suggest that reverse discordance resulted from mechanisms that involve exchange or fractionation of elemental U or elemental Pb, and that neither the U-Pb dates nor the ²⁰⁷Pb/²⁰⁶Pb dates are reliable indicators of the rock's crystallization age. Given the large number of processes proposed in the recent literature to explain monazite U-Pb systematics from rocks of all ages, our results can be viewed as another cautionary note for single-crystal and multi-crystal monazite geochronometry. However, we suggest that because individual crystals can preserve a temporal record of primary and secondary monazite growth, micro-sampling of individual monazite crystals may provide precise absolute ages on a variety of processes that operate during the prograde, peak and/or retrograde history of metamorphic terranes. Received: 9 June 1996 / Accepted: 18 October 1996     

Climatic trends from isotopic records of tree rings: The past 100–200 years

There has been a great deal of discussion about global warming from accumulation of anthropogenic greenhouse gases in the atmosphere (Houghton et al., 1990). Relatively less attention has been paid to spatial and/or temporal climatic variations that may be associated with a warmer climate (Rind et al., 1989) or with anthropogenic activities (Schneider, 1994). In this article, we show that an increase in climatic variability may have started. Fourteen isotopic time series of tree rings are presented. These trees were randomly collected from world-wide locations and cover time periods of 120 to over 200 years. The isotopic records show increasing D values that suggest a consistent and progressive warming occurred in the 19th century in all locations where the trees were sampled. The rate of warming is greater at relatively cold locations than at warm locations with two exceptions. The records also suggest greater climatic variations both temporally and spatially in the 20th century than in the 19th century.     

The Uneven Landscape of California's Historical Landmarks

Historical markers help preserve and display history and communicate what a group deems important about a place's past. This paper analyzes the changing themes and landscape relevance of California's official historical landmarks. California's thousand‐plus markers are classified and mapped by themes, analyzed for changing topical emphasis over time, and evaluated for landscape presence. The thematic distribution and relative density of these landmarks is uneven. Gold Rush and Spanish themes have become less prevalent over time as culturally related landmarks have grown in importance. This paper illustrates how historical landmark programs help sustain and define the public's collective memory through designating dispersed geographical locations as particularly important points of reference to the past.     

Integrating variations in the soil chloride profile and evaporativity for in-situ estimation of evaporation in arid zones: an application in south-eastern Morocco

In arid regions, knowledge of the evaporation rate from the water table is essential for appropriate management of scarce resources and to prevent land degradation. Soil chloride profiles in the unsaturated zone of a bare soil in an arid area of south-eastern Morocco were used to assess the evaporation flux, using chloride inventories in conjunction with evaporative demand. Moisture fluxes were calculated from measured chloride concentrations on the basis of a steady-state flow model. The chloride profiles displayed large variations in concentrations and had (1) low chloride concentrations near the soil surface, (2) maximum chloride concentrations at depths of 11–14 cm beneath the soil surface, respectively in July and February, and (3) gradually decreasing chloride concentrations while depth increased below these peaks. Evaporative demands were found to be inversely proportional to the depth of evaporation fronts and proportional to evaporation fluxes. In addition, the evaporation along the profiles seems to be controlled by the soil composition and texture. The investigation of chloride profiles in February and July enabled the determination of a value for annual evaporation (～30 mm), which is in good agreement with the value estimated by the Allison-Barnes type model (～32 mm).     

It's not all about wealth and beauty: Changing perceptions of fatness among Makola market women of Accra,Ghana

Within the African context, body shape preferences may be influenced by culture without necessarily taking into consideration health implications. Thus, fatness is culturally associated with beauty, prosperity, and prestige while thinness is perceived as a sign of ill‐health or poverty. Using a cross section of Makola market women, who traditionally are perceived as fat and affluent, our findings revealed that the perception of fatness as a sign of richness and beauty is changing due to women's access to knowledge and information on the health implications of fatness. The challenge for these women however, is adhering to healthy lifestyles despite living sedentary lives in the market place which is a conducive environment for one to become fat. We recommend that qualified professionals should encourage these women through continuous programmes on regenerative health and nutrition aimed at healthy lifestyle behaviour at the market places. The social groups that women belong to should be targeted, trained and equipped with the right information on healthy living so that they can disseminate this information to other members of their networks.     

The sideband instability of electrostatic waves in an inhomogeneous medium

The work deals with the resonant particle excitation of two electrostatic waves with closely spaced wave numbers, when there is an inhomogeneity present in the form of a spatially dependent wave number. Resonant particle behaviour in such a field is investigated and the resonant particle current is computed for a variety of cases. If the inhomogeneity is such that resonant particles see the wave numbers of the waves increasing, then it turns out that the wave of greatest wave number is preferentially amplified. If the gradient is reversed it is the opposite wave which grows. Thus when a narrow band electrostatic wave is subject to beam excitation, only one of the sideband waves is unstable.The theory is applied to the closely analogous problem of sideband formation in the case of triggering of VLF emissions by magnetospheric whistler pulses, and seems to account for much of the observed behaviour.     

On hydraulic falls of two-layer flow

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A comparison of non-hydrolytic methods for extracting amino acids and proteins from coastal marine sediments

Advances in analytical techniques now allow for the potential analysis of intact peptides and proteins isolated from marine sediments. However, there is no established technique for the extraction of macromolecular materials from marine sediments. Six different methods for extracting the amino acid component from coastal marine sediments were compared to the standard hot acid hydrolysis technique for their percent recovery and amino acid composition. The standard hot acid hydrolysis on dried, whole sediments released the greatest concentration of total amino acids (PS-THAA; 3.52 mg gdwt^− 1 ± 10% (SMD)), yet this only accounted for 22% of the total nitrogen in Puget Sound sediments (Washington, USA). Repeated hydrolysis of the same samples did not improve the recovery of nitrogen by more than an additional 10%. Base extraction (0.5 N NaOH) was the second best method for recovering amino acid nitrogen, releasing 60% of the Puget Sound total hydrolyzable amino acids (PS-THAA) (corresponding to 13% of the total sedimentary nitrogen), and has the advantage that it does not rely on peptide hydrolysis to free the nitrogenous component from the sediment matrix. The amino acid distribution of the 0.5 N NaOH extract was not significantly different than the initial THAA. Other non-hydrolyzing methods released lower yields of amino acids (Triton X-100 ≥ hot water > 50 mM NH₄HCO₃ > HF), but might prove to be of use to investigators interested in specific fractions of sedimentary organic nitrogen because these four methods had distinctly different amino acid compositions (enrichments in basic amino acids and depletions in acidic amino acids). Treatments with HF both before and after traditional hydrolysis and/or extractions with base did not release any more of the sedimentary nitrogen. Our results are consistent with the hypothesis that a large fraction of the sedimentary nitrogen (TN) is protected within an organic matrix.