Magmatism in the eastern Aleutian Arc: temporal characteristic of igneous activity on Akutan Island

Lavas from Akutan Island, located in the eastern Aleutian arc at the transition between continental and oceanic crust, show a gradual change in their petrologic and chemical characteristics over the last 4 million years. The oldest lavas exposed on the island, the Hot Springs Bay Volcanics (HSBV), range from magnesian basalt to dacite (45%–62% SiO₂). The most mafic basalts contain salitic clinopyroxene, Cr- and Al-rich spinel, and pargasitic amphibole suggesting that they were derived from relatively hydrous magmas at greater pressures than lavas from the younger Akutan Volcanics (AKV) and the modern volcano (MOD). AKV lavas also range between basalt and dacite (46%–63% SiO₂), but contain no hydrous phenocrysts and seem to have fractionated within a shallow level magma chamber. Lavas from the modern volcano are andesitic (52%–57% SiO₂) and have a mineral assemblage similar to that of AKV lavas of similar composition. With the exception of clinopyroxene and spinel in the most mafic lavas, the compositions of plagioclase (An_92?45), olivine (Fo_88?51), orthopyroxene (En_69?56), and titanomagnetite (15%–21% TiO₂) phenocrysts found in these lavas are within the range observed in lavas from other Aleutian volcanoes. Variations in the major element chemistry of the older lavas can be reproduced by fractional crystallization of the observed mineral assemblages, however closed system crystal fractionation models are inadequate to explain the trace element variations. During the last 4 million years, La/Yb ratios have decreased (6.5–3.3 for HSBV lavas and 2.9–1.9 for MOD lavas) whereas Ba/La ratios appear to have increased slightly (37–43 for HSBV and AKV, and 41–45 of MOD). The lower La/Yb ratios of MOD lavas correspond with lower total abundances of the REE and slightly higher Sr and Pb isotopic ratios. The increased⁸⁷Sr/⁸⁶Sr ratios and Pb isotopic ratios in the MOD lavas, the less enriched LREE, and the higher Ba/La ratios may result from partial melting of an arc source which has experienced previous melting events but has continued to be contaminated by a component from the subducting slab. It may also indicate a change in the degree of partial melting of the underlying mantle, which corresponds to a different percentage of a slab derived component being incorporated into the overlying mantle.     

Velocity-space maps and transforms of tracking observations for orbital trajectory state analysis

The orbital state of a satellite in a central force field can be uniquely described by its velocity hodograph, a circle, rather than the Keplerian conic. Also, its coordinate-frame rotation about the attracting center is definable, without singularity, by the four-parameter set of Euler parameters. A unified state model of orbital trajectory and attitude dynamics has previously been developed by use of state variables of the orbital velocity hodograph and Euler parameters. The dynamical constraint equations of this orbital state model are especially effective in advanced techniques of state estimation, used for orbit determination and prediction. External observations of orbital vehicles, such as provided by optical and radar sensors of tracking systems, are transformable into corresponding velocity state maps, as presented in this paper. These transformations and the consequent state maps are essential for development of the orbit observation matrix used with the unified state matrix, in recursive estimators such as the Kalman filters. Line-of-sight rays and range spheres (or hemispheres) of observations map conformally into orthogonal spherical surfaces in velocity space, as the result of the point-contact transformations. In bispherical coordinates, the field of observation maps for a ground-based tracking system site is shown to be a reduced (or degenerate) form of the general field of observation maps for a satellite-based tracking site. These orbital state maps and transforms are directly useful in development of observation matrices for candidate observation sets, such as range only, angle only, or range plus range-rate tracking schemes. Also, surface coverage patterns can be generated for proposed new tracking systems, in mission analysis and system synthesis studies.     

Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite

Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.     

Do Spur-Throated Grasshoppers, <Emphasis Type="Italic">Melanoplus</Emphasis> spp. (Orthoptera: Acrididae), Exert Top-Down Control on Smooth Cordgrass <Emphasis Type="Italic">Spartina alterniflora</Emphasis> in Northern New England?

Recently, strong top-down (consumer) control of cordgrass (Spartina alterniflora) has been demonstrated. Here, we manipulated the densities of cordgrass consumers, acridid grasshoppers (Melanoplus bivittatus and Melanoplus femurrubrum), to examine their impact on cordgrass in the Plum Island Estuary (PIE), MA, USA. After 1 month, there was no detectable effect of grasshopper density on S. alterniflora biomass and grasshoppers at the highest densities (34 individuals per square meter) consumed only ~14% of the standing stock biomass. However, significant impacts of grasshopper density on grazing damage were seen. For example, plant damage and scarring length increased by 160% and 6,156%, respectively, at the highest grasshopper densities relative to exclusion (zero grasshoppers) densities. Plant height was significantly reduced with increasing grasshopper densities, although this may be a function of leaf tip removal instead of reduced plant growth. No other strong consumers of cordgrass (e.g., Littoraria irrorata, Prokelisia marginata) were observed in PIE and we suggest that consumer regulation of cordgrass is weak in this system.     

Processes controlling precipitation of carbonate cement and dissolution of silica in reef and near-reef settings

Carbonate cementation in the surface layer of reefs and beachrock eliminates porosity and partially replaces detrital quartz grains. The uptake and release of CO₂ by photosynthesis and respiration in reef communities cause a shift in the carbonate buffer system of seawater. Field studies and experimentation simulating the natural settings show minimum values of CO₂ (1.9 mmoles 1^?1) and HCO₃^? (2.4 meq 1^?1) in association with maximum values of pH (9.8) and O₂ (> 100% oxygen saturation) in waters covering corals and algae prior to sunset. The converse is true for these variables prior to sunrise, when minimum values of pH (7.6) and O₂ (<66% oxygen saturation) occur with maximum values of CO₂ (2.7 mmoles 1^?1) and HCO₃^? (2.7 meq 1^?1). Experimental tanks containing plain seawater showed almost no diurnal variability in pH (a constant 7.5–7.6) or O₂ (80–90% oxygen saturation) measurements. Seawater adjacent to reef biomass, with elevated pH and supersaturated with calcium carbonate, is periodically pumped into the underlying reef and beach sediments due to pressure-buildups between the reef framework or algal zones and open waters. Carbonate precipitation and quartz dissolution follow. As the system equilibrates, pH values progressively decrease.     

Constraints on the thermal evolution of continental lithosphere from U-Pb accessory mineral thermochronometry of lower crustal xenoliths,southern Africa

U-Pb isotopic thermochronometry of rutile, apatite and titanite from kimberlite-borne lower crustal granulite xenoliths has been used to constrain the thermal evolution of Archean cratonic and Proterozoic off-craton continental lithosphere beneath southern Africa. The relatively low closure temperature of the U-Pb rutile thermochronometer (~400-450 °C) allows its use as a particularly sensitive recorder of the establishment of "cratonic" lithospheric geotherms, as well as subsequent thermal perturbations to the lithosphere. Contrasting lower crustal thermal histories are revealed between intracratonic and craton margin regions. Discordant Proterozoic (1.8 to 1.0 Ga) rutile ages in Archean (2.9 to 2.7 Ga) granulites from within the craton are indicative of isotopic resetting by marginal orogenic thermal perturbations influencing the deep crust of the cratonic nucleus. In Proterozoic (1.1 to 1.0 Ga) granulite xenoliths from the craton-bounding orogenic belts, rutiles define discordia arrays with Neoproterozoic (0.8 to 0.6 Ga) upper intercepts and lower intercepts equivalent to Mesozoic exhumation upon kimberlite entrainment. In combination with coexisting titanite and apatite dates, these results are interpreted as a record of postorogenic cooling at an integrated rate of approximately 1 °C/Ma, and subsequent variable Pb loss in the apatite and rutile systems during a Mesozoic thermal perturbation to the deep lithosphere. Closure of the rutile thermochronometer signals temperatures of 𙠂 °C in the lower crust during attainment of cratonic lithospheric conductive geotherms, and such closure in the examined portions of the "off-craton" Proterozoic domains of southern Africa indicates that their lithospheric thermal profiles were essentially cratonic from the Neoproterozoic through to the Late Jurassic. These results suggest similar lithospheric thickness and potential for diamond stability beneath both Proterozoic and Archean domains of southern Africa. Subsequent partial resetting of U-Pb rutile and apatite systematics in the cratonic margin lower crust records a transient Mesozoic thermal modification of the lithosphere, and modeling of the diffusive Pb loss from lower crustal rutile constrains the temperature and duration of Mesozoic heating to 𙡦 °C for ₞ ka. This result indicates that the thermal perturbation is not simply a kimberlite-related magmatic phenomenon, but is rather a more protracted manifestation of lithospheric heating, likely related to mantle upwelling and rifting of Gondwana during the Late Jurassic to Cretaceous. The manifestation of this thermal pulse in the lower crust is spatially and temporally correlated with anomalously elevated and/or kinked Cretaceous mantle paleogeotherms, and evidence for metasomatic modification in cratonic mantle peridotite suites. It is argued that most of the geographic differences in lithospheric thermal structure inferred from mantle xenolith thermobarometry are likewise due to the heterogeneous propagation of this broad upper mantle thermal anomaly. The differential manifestation of heating between cratonic margin and cratonic interior indicates the importance of advective heat transport along pre-existing lithosphere-scale discontinuities. Within this model, kimberlite magmatism was a similarly complex, space- and time-dependent response to Late Mesozoic lithospheric thermal perturbation.     

Evidence for the depletion of ammonia in the Uranus atmosphere

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH₃ is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10^?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.     

Protecting small cetaceans from coastal development: Impact assessment and mitigation experience in Hong Kong

Since the early 1990s, there has been an active program in Hong Kong to manage and protect local populations of small cetaceans from the effects of massive development in the area. This paper reviews the progress that has been made. Only two species regularly occur there: the Indo-Pacific humpback dolphin and the finless porpoise. Because most development has occurred in the western waters of Hong Kong, where generally only the humpback dolphin occurs, most of the work has been conducted on that species. Development of large infrastructure projects (such as airports, bridges, expressways, power plants, fuel facilities, and container ports) in Hong Kong often results in land reclamation, dredging and dumping of spoils, pipe and cable laying, percussive and bored piling work, underwater blasting, large increases in vessel traffic, and other impacts. Several mitigation measures have been used with varying levels of success, including bubble curtains/jackets, exclusion zones, ramping up of piling hammers, acoustic decoupling of noisy equipment, vessel speed limits, no-dumping policies, and silt curtains. Baseline, construction-phase, and operational-phase cetacean monitoring is often conducted to evaluate the success of conservation measures put into place. The Environmental Impact Assessment process in Hong Kong has involved cetaceans to a degree perhaps higher than anywhere else in the world, and much can be learned from studying the successes and failures of this situation.     

New Methods to Estimate 2D Water Level Distributions of Dynamic Rivers

River restoration measures are becoming increasingly popular and are leading to dynamic river bed morphologies that in turn result in complex water level distributions in a river. Disconnected river branches, nonlinear longitudinal water level profiles and morphologically induced lateral water level gradients can evolve rapidly. The modeling of such river‐groundwater systems is of high practical relevance in order to assess the impact of restoration measures on the exchange flux between a river and groundwater or on the residence times between a river and a pumping well. However, the model input includes a proper definition of the river boundary condition, which requires a detailed spatial and temporal river water level distribution. In this study, we present two new methods to estimate river water level distributions that are based directly on measured data. Comparing generated time series of water levels with those obtained by a hydraulic model as a reference, the new methods proved to offer an accurate and faster alternative with a simpler implementation.     

Cytochrome P4501A biomarker indication of the timeline of chronic exposure of Barrow's goldeneyes to residual Exxon Valdez oil

We examined hepatic EROD activity, as an indicator of CYP1A induction, in Barrow’s goldeneyes captured in areas oiled during the 1989 Exxon Valdez spill and those from nearby unoiled areas. We found that average EROD activity differed between areas during 2005, although the magnitude of the difference was reduced relative to a previous study from 1996/1997, and we found that areas did not differ by 2009. Similarly, we found that the proportion of individuals captured from oiled areas with elevated EROD activity (?2 times unoiled average) declined from 41% in winter 1996/1997 to 10% in 2005 and 15% in 2009. This work adds to a body of literature describing the timelines over which vertebrates were exposed to residual Exxon Valdez oil and indicates that, for Barrow’s goldeneyes in Prince William Sound, exposure persisted for many years with evidence of substantially reduced exposure by 2 decades after the spill.