Thermobaric flow

Simple model flows demonstrating the combined effect of thermobaricity with either salinity variations or nonlinear temperature-dependence in the equation of state of water are investigated. An inviscid flow exhibits a three-layer behaviour, resulting in the formation of a mid-depth temperature maximum, such as is observed in some high-latitude oceans and deep lakes. This may be subsequently overtaken by nonlinear frontogenesis, which in the viscous case is shown to generate a thermal bar. Thermobaricity shifts the thermal bar towards the cold water, and initially produces a slope in the downwelling plume, but this transient feature disappears as the dominant frontogenesis tilts the plume back to the vertical.     

Recent variations in 700 hPa geopotential heights in summer over Europe and the Middle East,and their influence on other Meteorological factors

Summary Recent variations in atmospheric circulation in the eastern Mediterranean are analyzed and discussed. Interdecadal differences in mean monthly 700 hPa geopotential heights for June, July, and August in the period 1951–1980 show a trend of decreasing pressure of the subtropical high pressure belt over the Sahara Desert. The decrease is observed in the magnitude of the high pressure, in its areal extent, and in its northward position. Broader variations in other meteorological variables, such as rainfall regimes, temperature fields, wind variability, and evapotranspiration rates, are discussed in relation to variations in pressure fields and in indices of circulation such as the North Atlantic Oscillation. The trend from the 1950s through the 1970s was towards more temperate summer climate in the region.With 5 Figures     

Tectonics and volcanism along the Pacific Marginal Zone of Central America

The relation of volcanism to tectonics in the Central American region has been established by a review of the literature as well as by field and photogeological work of the authors. The association of a deep trench off the Pacific coast, a parallel seismic belt, and a similarly oriented chain of volcanic vents farther inland, has been recognized by numerous earlier workers. These features form a tectonic unit, and are here termed the Pacific marginal zone.Seismic foci on the northeastern edge of the southern part of the Middle American Trench define a fault zone which dips under the continent and suggests movement of the oceanic plate underneath the Central American continent.An impressive chain of volcanic cones and associated shallow seismic foci is aligned along a prominent graben, best developed in Nicaragua where it is known as the Nicaraguan Depression. This feature probably originated in late Tertiary time. The southeastern end of the graben terminates at the northern ranges of the Talamanca Cordillera in Costa Rica. At the Gulf of Fonseca the trend of the graben changes from NW to E-W; the graben continues as the Central Depression of El Salvador at a higher elevation. Only the fault of the seaward border of the graben is defined in Guatemala, where it is represented by a NW trending volcanic chain.In Nicaragua and El Salvador the oldest cones are situated on the north-eastern boundary fault zone of the graben. These include remnants of the largest volcanic structures of the region. All the active volcanoes are on the southwestern boundary fault belt. Cross fracturing of this fault system controlled later northerly trending cone alignments, often with the youngest cones on the south end.The main graben and associated faults are considered results of tensional stresses on the crest of geanticlinal arching on the landward side of the Middle American Trench. This arching is believed to be due to regional compression originated by the movement of the oceanic plate against the mainland.In northwestern Central America the youngest stresses produced N-S normal faults that are marked by well-defined scarps. These stresses may be the result of right-lateral motion along the underthrust fault zone. The complex Comayagua graben north of the Gulf of Fonseca, the Ipala graben and associated faults in southeastern Guatemala, and the Guatemala City graben are all north-south features illustrating the extent and youth of this structural trend.The distribution of volcanic vents along the Nicaraguan Depression and the N-S trends underscores the close tectonic control of volcanism.

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Zusammenfassung Der Zusammenhang zwischen Tektonik und Vulkanismus im mittelamerikanischen Raum wird aufgezeigt aufgrund einer Literaturdurchsicht und feldgeologischer Arbeiten der Verfasser. Die Beziehungen zwischen einem Tiefseegraben vor der pazifischen Küste, einem dem Festland parallelen seismischen Gürtel und einer ebenso orientierten Vulkankette weiter im Inland sind von früheren Bearbeitern bereits erkannt worden. Diese drei Einheiten werden hier zusammengefaßt und als pazifische Randzone bezeichnet.Erdbebenherde am Nordostrand des mittelamerikanischen Tiefseegrabens weisen auf eine Störungszone hin, die unter den Kontinent einfällt. Der Bewegungssinn spricht für ein Abtauchen der ozeanischen Platte unter das mittelamerikanische Festland.Eine eindrucksvolle Vulkankette und die mit ihr verbundenen Erdbebenherde sind längs eines bedeutenden Grabens aufgereiht, der in Nicaragua am deutlichsten ausgebildet ist und dort Nicaragua-Senke genannt wird. Diese tektonische Einheit entstand wahrscheinlich im Jung-Tertiär. Der Graben beginnt im Südosten an den nördlichen Ausläufern der Talamanca-Kordillere in Costa Rica.In Nicaragua verläuft er NW. Am Golf von Fonseca schwenkt er in eine E-W-Richtung und setzt sich in El Salvador in einem höheren Niveau als Zentral-Depression fort. In Guatemala ist nur der Südrand des Grabens erkennbar. Er ist gekennzeichnet durch eine in NW-Richtung aufgereihte Vulkankette. In Nicaragua und El Salvador liegen die ältesten Vulkane auf dem nordöstlichen Grenzbruch des Grabens. Zu dieser Gruppe zählen die größten Rumpfvulkane. Die meisten Kegel und alle tätigen Vulkane liegen hingegen auf dem südwestlichen Grenzbruchstreifen. Auf Querbrüchen haben sich jüngere, nördlich ausgerichtete Kegelreihen gebildet. Die jüngsten Kegel liegen meistens am südlichen Ende der Querbrüche.Es wird angenommen, daß der Hauptgraben und seine Störungen im Scheitel einer zum mittelamerikanischen Tiefseegraben parallel verlaufenden Aufwölbung entstanden sind. Die Aufwölbung kann auf Kompression der ozeanischen Platte gegen das Festland zurückgeführt werden.Im nordwestlichen Zentralamerika bewirkten jüngere Beanspruchungen die Bildung von N-S-Brüchen, die heute morphologisch als Steilkanten hervortreten. Diese Beanspruchungen können durch rechtslaterale Bewegungen entlang der pazifischen Störungszone ausgelöst worden sein. Beispiele dieser N-S-Struktur sind: Die Comayagua-Grabenzone, nördlich des Golfs von Fonseca, der Ipala-Graben und sein Störungssystem in Südost-Guatemala und der Guatemala-Stadt-Graben. Diese N-S-Störungen kennzeichnen das Ausmaß und das geringe Alter der Grabenbildung.Die Anordnung der Vulkane entlang der Nicaragua-Senke und der N-S-Brüche stellen die engen Beziehungen zwischen Tektonik und Vulkanismus in der pazifischen Randzone Mittelamerikas heraus.

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Resumen Mediante información tomada de la literatura, trabajos de campo e interpretation fotogeológica, se establece la relación entre el volcanismo y la tectónica en la región de América Central. Se usa la denominación de zona marginal del Pacífico para identificar, como una unidad, la asociación ya reconocida por otros autores de la profunda Fosa Mesoamericana frente a la costa del Pacífico de America Central y las franjas paralelas de actividad sísmica y de cadenas volcánicas.Los focos sísmicos en el borde nororiental de la Fosa Mesoamericana definen una gran zona de afallamiento inclinada hacia el continente, cuyos movimientos indican que un bloque de la corteza oceánica se sumerge bajo la porción continental de America Central.Una imponente serie de conos volcánicos, asociada a focos sísmicos poco profundos, está situada a lo largo de un gran graben conocido como Depresión de Nicaragua, por ser en ese país donde aparece más claramente definido. Este graben, que posiblemente se originó durante el Terciario tardío, termina en su extremo suroriental contra las estribaciones de la parte norte de la Cordillera de Talamanca, en Costa Rica. En Nicaragua el graben está orientado hacia el NW hasta el Golfo de Fonseca donde toma un rumbo E-W a través de El Salvador, donde se encuentra a mayor elevación. En Guatemala se conoce únicamente una línea de fallas, la más próxima al mar, definida por una cadena de volcanes que tiene nuevamente dirección NW.En Nicaragua y El Salvador los conos volcánicos más antiguos están situados a lo largo de las fallas que limitan al graben en su lado nororiental. Allí se encuentran las ruinas de los edificos volcánicos más grandes de la región. La mayoría de los conos que incluye todos los actualmente activos, se localizan a lo largo de las fallas del borde suroccidental del graben. Fracturas transversales controlan la localization de varios grupos de conos alineados de N-S. Los volcanes más jóvenes se encuentran frecuentemente en el extremo sur.Se postula que el graben principal y otras fallas del mismo sistema han sido formados como resultado de esfuerzos de tensión, en la cresta de un geanticlinal que resultó del arqueamiento del lado terrestre de la zona marginal del Pacífico. Dicho arqueamiento se cree que resulta de la compresión regional debida al movimiento del bloque oceánico contra el continente.En la parte noroccidental de América Central los esfuerzos más recientes produjeron fallas orientadas N-S, fácilmente identificables por sus bien marcadas escarpas. Estos esfuerzos pueden haber resultado del desplazamiento dextromóvil a lo largo de las zonas de afallamiento paralelas a la Fosa Mesoamericana.El complejo graben de Comayagua, al norte del Golfo de Fonseca, y los graben de Ipala y de la Ciudad de Guatemala, orientados también de norte a sur, ilustran la extension y la joven edad de las fracturas.La distribución de los focos volcánicos a lo largo de la Depresión de Nicaragua y de las fracturas N-S muestran de manera evidente, la estrecha relación que existe entre la tectónica y la localización del volcanismo en la zona marginal del Pacifico de America Central.

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, - . - , . . , , . , , - . - Talamanca Kordillere -. - - . Fanseca . . , , . - . . . , . . - N-S , . . : Comayagua, Fanseca, Ipala - . - . , .

     

Further studies of ozone and sunspots

Pure and Applied Geophysics -     

An overview of toxicant identification in sediments and dredged materials

The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected.     

Determining accurate temperature-time paths from U-Pb thermochronology: An example from the Kaapvaal craton, southern Africa

Thermochronology has revolutionized our understanding of the establishment and evolution of lithospheric thermal structure. However, many potential benefits provided by the application of diffusion theory to thermochronology have yet to be fully exploited. This study uses apatite (T_c = 450-550 °C) and titanite (T_c = 550-650 °C) U-Pb ID-TIMS thermochronology at the single- to sub-grain scale to separate the variable effects of volume diffusion of Pb from metamorphic (over)growth above and below the T_c of a mineral. Data are presented from two ca. 3227 Ma tonalite samples from north and south of the Barberton Greenstone Belt (BGB), southern Africa. Two distinct populations of apatite from a sample north of the BGB record fast cooling followed by metamorphic growth ∼10 Myr later. Both apatite and titanite dates from south of the BGB show a strong correlation with the grain size and record 100 Myr of post-emplacement cooling. Complex core-rim zoning observed in cathodoluminescence images of apatite is interpreted to reflect metamorphic overgrowth above the T_c. The age and topology of grain size versus date curves from titanite and apatite are used in combination with a finite-difference numerical model to show that slow, non-linear, cooling and not thermal resetting is responsible for the observed distribution. The thermal histories from either side of the BGB are very different and provide unique insight into the BGB’s tectonic evolution: a ∼70 Myr period of apparent stability after ca. 3.2 Ga terrane assembly was followed by fast exhumation south of the BGB that led to lower-crustal melting and intrusion of granitic batholiths ca. 3.14-3.10 Ga.     

Spatio-temporal changes in the abundance of the populations of the gastrotrich community in a shallow lake of tropical Africa

Studies on the biodiversity and population dynamics of freshwater planktonic Gastrotricha have been carried out in conjunction with a physical–chemical analysis of the water in the Yaounde Municipal Lake (Cameroon, Central Africa) over a 14 months period (November 1996–December 1997). The results obtained allow to consider the Yaounde Municipal Lake as an eutrophic lake. It harbours eight species of Gastrotricha belonging to four genera (Chaetonotus, Dasydytes, Neogossea and Polymerurus) of the order Chaetonotida. This community was characterized by high abundances of populations, and was dominated by the genus Neogossea and Chaetonotusreaching up to 2000 ind. L⁻¹. Polymerurus was mostly abundant at the almost anoxic bottom layers. The highest abundances were found mostly during the rainy season, when there is an important sedimentation process of organic matter, and were influenced by several different environmental factors such as dissolved oxygen, temperature and pH of the water.

Finally this community which may play an important role in the water bodies, is a potential water quality indicator.     

Hydrogen and carbon isotopic ratios of the cellulose nitrate and saponifiable lipid fractions prepared from annual growth rings of a California redwood

The $\text{D}\text{H}$ and ${}^{13}\text{C}{}^{12}$C ratios of the cellulose nitrate and saponifiable lipid fractions prepared from eleven annual growth rings of a California redwood were determined. The $\text{D}\text{H}$ ratios of the two fractions are related to one another for the annual rings in the sapwood portion of the tree, but not for those in the heartwood or in the wood undergoing the transition from sapwood to heartwood. No relationship was observed between the ${}^{13}\text{C}{}^{12}$ ratios of the two fractions. These results suggest that analysis of the hydrogen isotopic composition of the saponifiable lipid fractions in plants will provide information useful for climatic reconstruction provided the initial isotopic record has not been changed by subsequent physiological or diagenetic processes.     

Trace elements in ocean ridge basalts

A correlary of sea floor spreading is that the production rate of ocean ridge basalts exceeds that of all other volcanic rocks on the earth combined. Basalts of the ocean ridges bring with them a continuous record in space and time of the chemical characteristics of the underlying mantle. The chemical record is once removed, due to chemical fractionation during partial melting. Chemical fractionations can be evaluated by assuming that peridotite melting has proceeded to an olivine-orthopyroxene stage, in which case the ratios of a number of magmaphile elements in the extracted melt closely match the ratios in the mantle. Comparison of ocean ridge basalts and chondritic meteorites reveals systematic patterns of element fractionation, and what is probably a double depletion in some elements. The first depletion is in volatile elements and is due to high accretion temperatures of a large percentage of the earth from the solar nebula. The second depletion is in the largest, most highly charged lithophile elements (“incompatible elements”), probably because the mantle source of the basalts was melted previously, and the melt, enriched in these elements, was removed. Migration of melt relative to solid under ocean ridges and oceanic plates, element fractionation at subduction zones, and fractional melting of amphibolite in the Precambrian are possible mechanisms for depleting the mantle in incompatible elements. Ratios of transition metals in the mantle source of ocean ridge basalts are close to chondritic, and contrast to the extreme depletion of refractory siderophile elements, the reason for which remains uncertain. Variation of ocean ridge basalt chemistry along the length of the ridge has been correlated with ridge elevation. Thus chemically anomalous ridge segments up to 1000 km long appear to broadly coincide with regions of high magma production (plumes, hot spots). Basalt heterogeneity at a single location indicates mantle heterogeneity on a smaller scale. Variation of ocean ridge basalt chemistry with time has not been established, in fact, criteria for recognizing old oceanic crust in ophiolite terrains are currently under debate. The similarity of rare earth element patterns in basalt from ocean ridges, back-arc basins, some young island arcs, and some continental flood basalts illustrates the dangers of tectonic labeling by rare earth element pattern.     

Atmospheric noble gases in volcanic glasses from the southern Lau Basin: origin from the subducting slab?

Noble gas concentrations and isotopic compositions have been determined for four submarine volcanic glasses from the Valu Fa Ridge (VFR) in the southern Lau Basin. The samples are the least differentiated ones from this area, and they display enrichments in fluid-mobile elements similar to the nearby island arc. ³He/⁴He ratios are slightly below average MORB (6.8–7.8 times atmospheric), whereas Ne, Ar, Kr, and Xe have isotopic compositions very similar to air. Together with previously published data from the Valu Fa Ridge and other spreading segments in the Lau Basin, our data show a systematic latitudinal variation of increasing Ne, Ar, Kr, and Xe abundances from north to south as well as Ne and Ar isotopic compositions changing from MORB-like to atmosphere-like in the same direction. Moreover, isotopic compositions and noble gas abundances of the lavas correlate strongly with Ba/Nb ratios and H₂O concentrations. Based on these observations and mass balance arguments, we propose that the atmospheric noble gases come from the subducting oceanic crust and are not due to shallow contamination with air dissolved in seawater or assimilation of old crust. Our data suggest that the noble gases released from the subducting slab are atmospheric and thus contain little or no solar He and Ne. In addition to the fact that ratios of He to heavy noble gases are small in aged ocean crust, He has possibly fractionated from the other noble gases due to its higher diffusivity, and thus He transport from the subducting slab into the mantle wedge is probably insignificant. We propose that the ³He/⁴He ratios lower than MORB observed in the VFR lavas result from radiogenic ingrowth of He in a highly depleted, and hence degassed, mantle wedge after the enrichment of U and Th released from the downgoing slab.