Spatial and temporal patterns of iceberg rafting (IRD) along the East Greenland margin,ca. 68°N,over the last 14 cal.ka

Twelve 1–2 m, 10-cm-diameter gravity cores collected in 1988 and 1991, from the continental shelf and fjords of East Greenland near Kangerlussuaq Fjord/Trough (ca. 68°N, 32°W), have distinct changes in lithofacies and in the quantity of iceberg rafted (IRD) sediments. These changes are readily observed in X-radiographs of the split cores. We quantify the IRD contribution through grain-size analyses and counting the number of clasts >2 mm from the X-radiographs. Chronological control is provided by acclerated mass spectroscopy ¹⁴C dates on foraminifera. During deglaciation, after 14 cal.ka there was one interval of IRD accumulation ca. 12–13 cal.ka, followed by a brief return to IRD conditions centred at 9 cal.ka. Thereafter, a prominent feature of most cores on the shelf is an increase in IRD accumulation that started ca. 5–6 cal.ka, and which has increased toward the present. Indicators of iceberg rafting, such as the net sand flux and numbers of clasts >2 mm ka⁻¹, follow a power law distribution when graphed against distance from the present East Greenland coast, a measure of the position of the glacier margins. The form of the relationship indicates that there is a dramatic decrease in the supply of sediment from the fjords to the shelf. These relationships are used to estimate changes in the location of the ice margin during the late Quaternary based on a site on the East Greenland slope, Denmark Strait, and to discuss factors that can negate such a simple transfer function. © 1997 by John Wiley & Sons Ltd.     

Redistriution of Major Elements in the Alteration of Some Basic Lavas during Burial Metamorphism

An Ordovician geanticlinal marine sequence is exposed in theCentral West of New South Wales, Australia. The sequence containingbasic lavas, labile sedimentary, and proclastic rocks, has undergoneextensive adjustment during regional burial metamorphism. Thebasic lavas have a patchy coloration due to the formation ofalternation minerals of the prehnite-pumpellyite facies whichapperar to have formed during the metamorphism. The hererogeneousappearance of the basic lavas reflects a pronouced chemicaland mineralogical departure from the original composition. Twodiverging trends result. One leads to the production of a Ca-enrichedlithology, the other, which by far dominates in area at eachouterop, leads to a ‘spilitic’ lithology. The alterationdomains in many cases cross–cut all primary textural featureand their chemical variation does not correspond to likely variationsin the original lava composition.     

Trace Element and Isotope Geochemistry of the Volcanic Rocks of Bequia, Grenadine Islands, Lesser Antilles Arc: a Study of Subduction Enrichment and Intra-crustal Contamination

Pliocene volcanics on the island of Bequia comprise two interbeddedsuites of basalts and andesites. The isotopically homogeneoussuite (IHS) has a limited range of Sr—Nd—Pb isotopes(⁸⁷Sr/⁸⁶Sr 0.7040–0.7046, ¹⁴³ Nd/¹⁴⁴ Nd 0.5130 and ²⁰⁶Pb/²⁰⁴Pb 19.36–19.51), and mantle-like ¹⁸O values (5.5in clinopyroxene). The isotopically diverse suite (IDS) is characterizedby much wider ranges of radiogenic isotopes (⁸⁷ Sr/⁸⁶Sr 0.7048–0.7077,¹⁴³ Nd/¹⁴⁴ Nd 0.5128–0.5123 and ²⁰⁶ Pb/²⁰⁴ Pb 19.7–20.2),in which all of the Sr and Pb ratios are higher and Nd ratiosare lower than those of the IHS. The IDS is also characterizedby high ¹⁸ O values, up to 7.6 in clinopyroxene. The Sr andPb isotope ratios are too high, and the Nd isotope ratios aretoo low in the IDS for any of these lavas to be derived fromunmodified depleted mantle. Both suites are petrologically very similar and their majorelement compositions and phenocryst contents suggest that theywere formed largely by fractional crystallization of a hydroustholeiitic melt at pressures <3 kbar. The isotopic ratiosand enrichments in large ion lithophile elements (LILE), andto some extent light rare earth elements (LREE), as comparedwith mid-ocean ridge basalts (MORB), of the IHS lavas suggestthat they were derived from a depleted mantle source which hadbeen re-enriched by the addition of 1–4% of a subductioncomponent. This component probably comprised a mixture of dehydrationfluids, and perhaps minor siliceous melts, released from subductingsediments and mafic crust. The extreme isotopic ranges, largeenrichments in incompatible elements, more fractionated LREEpatterns and higher ¹⁸ O values of the IDS lavas are interpretedas resulting from 10–55% assimilation—fractionalcrystallization of sediments, derived from the Guyana Shield,which are present in the arc crust, by IHS type melts. KEY WORDS: trace elements; radiogenic isotopes; arc lavas; Lesser Antilles ^*Corresponding author.     

Petrogenetic Evolution of the Torfaj?kull Volcanic Complex, Iceland I. Relationship Between the Magma Types

The Torfaj?kull volcano, Iceland's largest silicic centre, issituated close to the junction of the active, southerly propagatingEastern Rift Zone and the South Eastern Zone, an older crustalsegment. This paper provides major, trace, and some Sr isotopedata on postglacial (<10000 y) rocks, i.e., tholeiitic magmasof the Eastern Rift Zone and transitional basalts, icelandites,and rhyolites of the Torfaj?kull centre, and assesses the relationshipsbetween the magma types in terms of the development of the Icelandiccrust. Tholeiitic magmas from the Eastern Rift Zone are LILE-enrichedrelative to MORB. They have undergone extensive olivine-plagioclase-clinopyroxenefractionation at low pressures. Compared with the tholeiites,Torfaj?kull transitional basalts show LILE/HFS enrichment andhigher (⁸⁷Sr/⁸⁶Sr)₁ ratios. They define several magmatic lineagesand have equilibrated over a wide range of pressures. Both basalttypes were derived by very small degrees of partial meltingof compositionally similar mantle sources, the main differencebeing that the tholeiites were generated in the spinel Iherzolite,and the transitional basalts in the garnet lherzolite, stabilityfields, a conclusion previously reached by Meyer et al. (1985).The mantle sources may have contained LILE-enriched streaks. Low-pressure differentiation of Torfaj?kull transitional basaltproduced an iceiandite to sub-alkaline rhyolite sequence bycrystal fractionation, the rhyolites representing >90% crystallizationof parental basalts. The rhyolites were emplaced as nine separatelava fields, formed during 11 eruptive episodes. The compositionalrange within each field is limited, and, although similar, theranges define several magmatic lineages. Continued fractionationof plagioclase-alkali feldspar-clinopyroxene-magnetite-apatite-zirconassemblages generated peralkaline rhyolites in certain post-glacialeruptions. Chemical variations in the deposits from the Hrafntinnuskerperalkaline eruption were related predominantly to alkali feldsparfractionation, and the melts were erupted from a zoned magmachamber. All postglacial volcanic rocks at Torfajokull havebeen mantle derived and thus represent new additions to theIcelandic crust.     

Compositional Zoning in Pyroxenes from Lunar Rock 12021, Oceanus Procellarum

Electron probe study of the pyroxene phenocrysts in rock 12021of the Apollo 12 sample reveals an extraordinary variety ofzoning phenomena. These phenocrysts have cores of relativelyhomogeneous pigeonite which are mantled by Ca-rich pyroxenes;the mantles are zoned outward from about 20 mol per cent FeSiO₃at the core-mantle boundaries to 70 mol per cent FeSiO₃ at themargins of the phenocrysts. The character of the normal zoningdiffers in each growth sector. Four different trends characterizinggrowth on (110), (100), (010), and parallel to c are described.Pronounced but erratic oscillatory effects are impressed onthe normal zoning in all sectors. Normal zoning in lunar pyroxenes is generally more extensivethan in terrestrial pyroxenes, probably because the lunar lavaswere an order of magnitude more fluid than terrestrial basalts.Turbulent flow in lunar lavas may have caused some of the oscillatoryeffects. The cyclic nature of augite and pigeonite crystallizationin these pyroxenes is probably kinetic in origin; conceivablyit could reflect the presence of an augite-pigeonite peritectic.It is likely that further knowledge of the crystal structureof pigeonite at high temperatures will be required before astructural model can be formulated that will satisfactorilyexplain the details of the sector zoning. Coarse-grained pyroxferroite and subcalcic ferroaugite havecrystallized in apparent ‘equilibrium’ in the finalstages of formation of the groundmass in rock 12021. Nevertheless,the crystallization of the pyroxferroite was probably metastablerelative to the assemblage ferroaugite+ fayalite+ tridymite.Data on the effect of Mg substitution on the stability of pyroxferroitewill be needed to establish this point. We suggest that the pigeonite cores of the phenocrysts in rock12021 crystallized under quiescent conditions, probably in amagma chamber below the lunar surface, and that the stronglyzoned augite mantles crystallized during emplacement of thelava on the surface.     

THE INFLUENCE OF PERMEABILITY ON COMPRESSIONAL WAVE VELOCITY IN MARINE SEDIMENTS*

To investigate the effect of permeability on the propagation of seismo-acoustic waves through marine sediments, a theoretical model based on Biot's equations is established which relates the compressional wave velocity measured at a fixed frequency to computed velocities at zero and infinite frequencies in terms of sediment porosity and permeability. The model is examined experimentally in a standard soil mechanics consolidation test (itself dependent, among other things, on sediment porosity and permeability) which has been modified to include measurements of compressional wave velocity at 1 MHz and shear-wave velocity at 5 kHz. This test allows the elastic modulus of the sediment frame to be assessed under different load conditions simultaneous with the velocity determinations. From a number of tests on different samples, five samples are chosen to typify the range of sediment sizes. The results show that the difference between the measured velocity at 1 MHz and the model-derived velocity at zero frequency increases with increasing particle size (from clays to fine sand), with decreasing porosity, and with increasing permeability. For sediments coarser than fine sand the simple model breaks down, possibly because of the dominance of scattering/diffraction effects at the high frequency of the experiment. Within this limitation the model seems satisfactory to offer a capability of predicting the permeability of a sea floor sediment to an order of magnitude by the in situ measurement of seismic velocities over a wide range of frequencies; the prediction process requires a good in situ determination of sediment porosity such as that offered by electrical formation factor measurements.     

The place of rural, remote and least-wealthy small islands in international water development: the nexus of geography–technology sustainability in Chuuk State, Federated States of Micronesia

Many least-wealthy, rural, remote and resource-poor small island communities are unlikely to benefit from high-profile global water improvement initiatives. Their small landmasses, geologic composition, geography, social and technological isolation, colonial history, and weak educational and financial resources constitute significant barriers to improving access to safe drinking water. This paper discusses the relatively unique position of such island societies in the international community, providing a case study of the Federated States of Micronesia that integrates data and information pertaining to water resources management and governance, spanning from the island village to national scale. A vision is offered regarding the interaction between small island human and biophysical water systems, manifesting ways to pursue water resource development to improve public health which are constructed to be economically, physically and culturally sustainable.