Seismic anisotropy in the core–mantle transition zone

Split S waves observed at Hockley, Texas from events in the Tonga–Fiji region of the southwest Pacific show predominantly vertically polarized shear-wave ( SV  ) energy arriving earlier than horizontally polarized ( SH ) energy for rays propagating horizontally through D" . After corrections are made for the effects of upper-mantle anisotropy beneath Hockley, a time lag of 1.5 to 2.0  s remains for the furthest events (93.9°–100.6° ), while the time lags of the nearer observations (90.5°–92.9° ) nearly disappear. At closer distances, the S waves from these same events do not penetrate as deeply into the lower mantle, and are not split. These observations suggest that a patch of D" beneath the central Pacific is anisotropic, while the mantle immediately above the patch is isotropic. The thickness of the anisotropic zone appears to be of the order of 100–200  km.
  Observations of shear-wave splitting have previously been made for paths that traverse D" under the Caribbean and under Alaska. SH leads SV , the reverse of the Hockley observations, but in these areas the fact that SV  leads SH in the HKT data shown here suggests a different sort of anisotropy under the central Pacific from that under Alaska and the Caribbean. The case of SH travelling faster than SV  is consistent with transverse isotropy with a vertical axis of symmetry (VTI) and does not require variations with azimuth. The case of SV  leading SH is consistent with transverse isotropy with a horizontal axis of symmetry (HTI), an azimuthally anisotropic medium, and with a VTI medium formed by a hexagonal crystal. Given that (Mg,Fe)SiO₃ perovskite appears unlikely to form anisotropic fabrics on a large scale, the presence of anisotropy may point to chemical heterogeneity in the lowermost mantle, possibly due to mantle–core interactions.     

Interpretations of self potential anomalies due to localised causative bodies

Summary Some direct methods of interpretation of SP anomalies that may arise from localised causative bodies have been developed in this paper. The models of the current sources that have been considered here are the cases of 1. single vertical dipole, 2. a pair of similar and similarly situated vertical dipoles and 3. an inclined dipole. A set of three master curves has been prepared in terms of which the interpretation in the first and the third case is complete. With an additional assumption that the distance between the dipoles is small, the second case also is completely solved with the help of the same set of master curves.Published under the kind permission of the Director General, Geological Survey of India, Calcutta.     

Numerical modeling of wave equation by a truncated high-order finite-difference method

Finite-difference methods with high-order accuracy have been utilized to improve the precision of numerical solution for partial differential equations.However, the computation cost generally increases linearly with increased order of accuracy.Upon examination of the finite-difference formulas for the first-order and second-order derivatives, and the staggered finite-difference formulas for the first-order derivative, we examine the variation of finite-difference coefficients with accuracy order and note th...     

Kirchhoff–Helmholtz reflection seismograms in a laterally inhomogeneous multi-layered elastic medium – II. Computations

Summary. High-frequency reflection and refraction seismograms for laterally variable multi-layered elastic media are computed by using the frequency domain elastic Kirchhoff–Helmholtz (KH) theory of Frazer and Sen. Both source and receiver wavefields are expanded in series of generalized rays and then elastic (KH) theory is applied to determine the coupling between each source ray and each receiver ray at each interface. The motion at the receiver is given as a series of integrals, one for each generalized ray. We use geometrical optics and plane wave reflection and transmission coefficients for rapid evaluation of the integrand. When the source or the receiver ray field has caustics on the surface of integration geometrical ray theory breaks down and this gives rise to singularities in the KH integrand. We repair this using methods suggested by Frazer and Sen.
Examples of reflection seismograms for 2-D structures computed by elastic KH theory are shown. Those for a vertical fault scarp structure are compared with the seismograms obtained by physical modelling. Then OBS data obtained from the mid-America trench offshore Guatemala area are analysed by computing KH synthetics for a velocity model that has been proposed for that area. Our analysis indicates the existence of a small low-velocity zone off the trench axis.
No head wave arrivals are obtained in our KH synthetics since we do not consider multiple interactions of a ray with an interface. The nearly discontinuous behaviour of elastic R/T coefficients near the critical angle causes small spurious phases which arrive later than the correct arrivals.     

Carbonate Alkalinity Enhances Triclosan Photolysis

Triclosan (TCS) is an antimicrobial compound found in many household products used across the world. TCS is not completely removed in wastewater systems, resulting in trace-level concentrations present ubiquitously in surface waters. The direct photodegradation of TCS has been widely studied, with results indicating that TCS breaks down to chlorophenols and dioxins. To date, no studies have specifically investigated the effects of alkalinity on the photolysis of the acidic form of TCS. This study assessed the effect of carbonate/bicarbonate alkalinity, which is ubiquitous in natural waters, on the photolysis rate of TCS. Results indicate that bicarbonate enhances the photodegradation of TCS at pH values well below the pK_a of TCS (7.9), with direct photolysis reaction kinetics that are very slow in the absence of buffers, but significant in the presence of bicarbonate (0.711 h^?1 at pH 6.55). At pH values well above its pK_a, both unbuffered- and buffered-mediated photolysis increased dramatically (1.92 h^?1 for direct photolysis and 2.86 h^?1 in buffered water) and is attributable to the increased photoreactivity of TCS by its conjugate base. Photolysis of methyl triclosan (MeTCS), a non-acidic analog of TCS, demonstrated the importance of TCS’s acidic functionality as MeTCS did not degrade at any pH. The observed influence of alkalinity on the acidic form of TCS photolysis was attributed to both a decrease in its excited state pK_a, coupled with TCS deprotonation through an excited state proton transfer to a base (bicarbonate and to a lesser degree hydrogen phosphate) resulting in the more photo-labile conjugate base form of TCS.

     

Spatiotemporal pattern of the dynamics in area,production, and yield of Aus rice in Bangladesh and its response to droughts from 1980 to 2018

Bangladesh is one of the most vulnerable countries to natural disasters such as droughts in the world. The pre-monsoon Aus rice in Bangladesh depends on rainfall and is threatened by increasing droughts. However, limited information on the changes in Aus rice as well as droughts hamper our understanding of the country’s agricultural resilience and adaption to droughts. Here, we collected all the official statistical data of Aus rice at the district level from 1980 to 2018, and examined the inter...